METAL-ORGANIC POLYHEDRA
    2.
    发明公开
    METAL-ORGANIC POLYHEDRA 审中-公开
    METALLORGANISCHE POLYHEDRA

    公开(公告)号:EP1689762A4

    公开(公告)日:2009-08-05

    申请号:EP04822221

    申请日:2004-12-03

    申请人: UNIV MICHIGAN

    IPC分类号: C07F15/02

    CPC分类号: C07F15/025

    摘要: The present invention provides porous metal-organic polyhedra. The porous metal-organic polyhedra of the present invention comprises a plurality of metal clusters each of which have two or more metal ions, and a sufficient number of capping ligands to inhibit polymerization of the metal organic polyhedra. The porous metal-organic polyhedra further includes a plurality of multidentate linking ligands that connect adjacent metal clusters into a geometrical shape describable as a polyhedral with metal clusters positioned at one or more vertices of the polyhedron. The present invention also provides a method of making the porous metal-organic polyhedra in which a solution comprising a solvent, one or more ions, and a counterions that complexes to the porous metal-organic polyhedra as a capping ligand to inhibit polymerization of the metal organic polyhedra, with a multidentate linking ligand.