Catalyst and process for producing conjugated diene polymer
    2.
    发明公开
    Catalyst and process for producing conjugated diene polymer 失效
    Katalysator和Verfahren zur Herstellung von Polymeren konjugierten Diene

    公开(公告)号:EP0778291A1

    公开(公告)日:1997-06-11

    申请号:EP96308873.7

    申请日:1996-12-06

    IPC分类号: C08F4/68 C08F36/04 C07F17/00

    摘要: A catalyst obtained by contacting (A) a compound of a transition metal of the group V of the Periodic Table represented by formula (I): R n M(O) m X p ·L a wherein M represents a transition metal of the group V of the Periodic Table; R represents a cyclopentadienyl group, a substituted cyclopentadienyl group, an indenyl group, a substituted indenyl group, a fluorenyl group or a substituted fluorenyl group; O represents an oxygen atom; X represents a hydrogen atom, a halogen atom, a hydrocarbon group having 1 to 20 carbon atoms, an alkoxy group, an aryloxy group or an amido group; L represents a Lewis basic compound; n, m, and p each represent an integer selected to make a combination of (n=1, m=1, p=2), (n=1, m=0, p=3), (n=2, m=0, p=1) or (n=1, m=0, p=2); and a represents 0, 1 or 2, and (B) at least one of (B1) an ionic compound comprising a non-coordinating anion and a cation and (B2) an aluminoxane, provided that the component (B) is an ionic compound comprising a non-coordinating anion and a cation (B1) when the combination of n, m, and p of the component (A) is (n=2, m=0, p=1) or (n=1, m=0, p=2).

    摘要翻译: 通过使(A)式(I)表示的元素周期表的第V族的过渡金属的化合物与式(I)化合物进行接触得到的催化剂:其中M表示周期表第Ⅴ族的过渡金属; R表示环戊二烯基,取代的环戊二烯基,茚基,取代的茚基,芴基或取代的芴基; O表示氧原子; X表示氢原子,卤素原子,碳原子数1〜20的烃基,烷氧基,芳氧基或酰胺基; L表示路易斯碱性化合物; n,m和p各自表示选择以使(n = 1,m = 1,p = 2),(n = 1,m = 0,p = 3),(n = = 0,p = 1)或(n = 1,m = 0,p = 2); 和(B)包含非配位阴离子和阳离子的离子化合物和(B2)铝氧烷中的至少一种,(B)组分(B)是离子化合物 当组分(A)的n,m和p的组合为(n = 2,m = 0,p = 1)或(n = 1,m = 1)时,包含非配位阴离子和阳离子(B1) 0,p = 2)。