摘要:
A disclosed method of forming a ceramic article includes forming a pre-ceramic polymer article within a mold tool, and performing a first pyrolizing step on the initial pre-ceramic polymer article to form a ceramic article. The method further includes performing at least one pre-heat treatment polymer infiltration and pyrolizing (PIP) cycle on the ceramic article and an initial heat treatment cycle of the ceramic article after the at least one pre-heat treatment PIP cycle. Subsequent PIP cycles and heat treatment cycles are performed in combination to form a ceramic article including a desired density.
摘要:
Disclosed is a method for providing a crystalline ceramic material. In an example, the method includes providing a silicon-containing preceramic polymer material that can be thermally converted to one or more crystalline polymorphs. The silicon-containing preceramic polymer material includes dispersed therein an effective amount of dopant particles. The silicon-containing preceramic polymer material is then thermally converted to the silicon-containing ceramic material. The effective amount of dopant particles enhance the formation of at least one of the one or more crystalline polymorphs, relative to the silicon-containing preceramic polymer without the dopant particles, with respect to at least one of formation of a selected polymorph of the one or more crystalline polymorphs formed, an amount formed of a selected polymorph of the one or more crystalline polymorphs formed, and a temperature of formation of the one or more crystalline polymorphs.