are provided. In Formula I, M is Pd or Pt; each of X 1 to X 14 is C or N; one of Z 1 and Z 2 is C and the other is N; Y is selected from O, S, Se, N ∗ R, CRR', SiRR', or GeRR'; K 1 is a direct bond, O, or S; each R, R', R A , R B , R C , and R D is independently hydrogen or a substituent; at least one of R, R', R A , R B , R C , or R D is a substituent R ∗ ; and (i) R ∗ comprises a 5-membered or 6-membered heterocyclic ring, or (ii) R ∗ comprises Formula Ia:
wherein each of R Y and R Z independently represents mono to the maximum allowable substitution, or no substitution; R 1 , R 2 , R 3 , R 4 , R Y and R Z is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, germyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, selenyl, and combinations thereof; wherein at least one of R 1 , R 2 , R 3 , and R 4 is not hydrogen. Formulations, OLEDs, and consumer products including the compound are also provided.
摘要:
A compound including a first ligand L A of Formula I
is disclosed. In the structure of Formula I, one of L 1 and L 2 is C, and the other is N; Y 1 to Y 14 are each C or N; at least two adjacent Y 7 , Y 8 , Y 9 , and Y 10 are carbon atoms that are fused to a structure of Formula II
Z 1 and Z 2 are each O, S, Se, NR, CRR', or SiRR'; and each R, R', R A , R B , R C , and R D is hydrogen or a substituent; and any two substituents may be joined or fused together to form a ring. In the compound, L A is complexed to a metal M by L 1 and L 2 , and M has an atomic weight greater than 40. Organic light emitting devices and consumer products containing the compounds are also disclosed.
摘要:
The present invention relates to organic light emitting devices (OLEDs), and more specifically to phosphorescent organic materials used in such devices. More specifically, the present invention relates to emissive phosphorescent material which comprise at least one tridentate ligand bound to a metal center, wherein at least one of the bonds to the tridentate ligand is a carbon-metal bond.
摘要:
New organometallic complexes having bis- or tris- heteroleptic ligands and large aspect ratio in one direction and their use in OLEDs to enhance the efficiency is disclosed.
摘要:
Compounds having a particular molecular shape that makes transition dipole moments (TDM) of the compounds in an EML align within the plane of the EML and produce the maximum light extraction effect are disclosed.