ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:EP4212539A1

    公开(公告)日:2023-07-19

    申请号:EP22213964.4

    申请日:2022-12-15

    IPC分类号: C07F15/00 C09K11/06 H10K85/60

    摘要: Compounds of Formula I,

    are provided. In Formula I, M is Pd or Pt; each of X 1 to X 14 is C or N; one of Z 1 and Z 2 is C and the other is N; Y is selected from O, S, Se, N ∗ R, CRR', SiRR', or GeRR'; K 1 is a direct bond, O, or S; each R, R', R A , R B , R C , and R D is independently hydrogen or a substituent; at least one of R, R', R A , R B , R C , or R D is a substituent R ∗ ; and (i) R ∗ comprises a 5-membered or 6-membered heterocyclic ring, or (ii) R ∗ comprises Formula Ia:

    wherein each of R Y and R Z independently represents mono to the maximum allowable substitution, or no substitution;
    R 1 , R 2 , R 3 , R 4 , R Y and R Z is independently hydrogen or a substituent selected from the group consisting of deuterium, halogen, alkyl, cycloalkyl, heteroalkyl, heterocycloalkyl, arylalkyl, alkoxy, aryloxy, amino, silyl, germyl, boryl, alkenyl, cycloalkenyl, heteroalkenyl, alkynyl, aryl, heteroaryl, acyl, carboxylic acid, ether, ester, nitrile, isonitrile, sulfanyl, sulfinyl, sulfonyl, phosphino, boryl, selenyl, and combinations thereof; wherein at least one of R 1 , R 2 , R 3 , and R 4 is not hydrogen. Formulations, OLEDs, and consumer products including the compound are also provided.

    ORGANIC ELECTROLUMINESCENT MATERIALS AND DEVICES

    公开(公告)号:EP4019526A1

    公开(公告)日:2022-06-29

    申请号:EP22157219.1

    申请日:2019-01-25

    IPC分类号: C07F15/00 C09K11/06 H01L51/00

    摘要: A compound including a first ligand L A of Formula I

    is disclosed. In the structure of Formula I, one of L 1 and L 2 is C, and the other is N; Y 1 to Y 14 are each C or N; at least two adjacent Y 7 , Y 8 , Y 9 , and Y 10 are carbon atoms that are fused to a structure of Formula II

    Z 1 and Z 2 are each O, S, Se, NR, CRR', or SiRR'; and each R, R', R A , R B , R C , and R D is hydrogen or a substituent; and any two substituents may be joined or fused together to form a ring. In the compound, L A is complexed to a metal M by L 1 and L 2 , and M has an atomic weight greater than 40. Organic light emitting devices and consumer products containing the compounds are also disclosed.