公开(公告)号：EP2906345A1

公开(公告)日：2015-08-19

申请号：EP13803243.8

申请日：2013-10-08

申请人： Versalis S.p.A.

发明人： MASI, Francesco ,  SOMMAZZI, Anna ,  BENCINI, Elena ,  RONCHIN, Lucio ,  TONIOLO, Luigi ,  VAVASORI, Andrea

IPC分类号： B01J37/03 ,  B01J37/10 ,  B01J21/06 ,  B01J23/89 ,  B01J37/08 ,  C07C5/11 ,  C07C13/20

CPC分类号： B01J21/066 ,  B01J23/8906 ,  B01J23/8926 ,  B01J23/8953 ,  B01J23/896 ,  B01J23/898 ,  B01J31/2295 ,  B01J37/0209 ,  B01J37/033 ,  B01J37/086 ,  B01J37/10 ,  B01J2531/46 ,  B01J2531/48 ,  B01J2531/49 ,  B01J2531/56 ,  C07C5/11 ,  C07C2521/06 ,  C07C2523/08 ,  C07C2523/46 ,  C07C2523/745 ,  C07C2523/89 ,  C07C2601/16 ,  C07C13/20

摘要： An object of the present invention relates to a catalyst suitable for the selective hydrogenation of aromatic or polyunsaturated compounds, comprising: - a zirconia carrier (ZrO
2 ) - ruthenium - iron oxide (Fe
2 O
3 ) - at least one promoter (A) selected from the oxides of metals of groups IB, IIB and IIIA - at least one promoter (B) containing V, Ti, Hf, Zr or a mixture thereof, obtained by hydrolysis of at least one precursor P-B selected from the following metal arenes: V°(arene)
2 (I) V(arene)
2 AlCl
4 (II) M (η
6 -arene)
p Al
q X
r (III) M(η6-arene)
p' Al
q' X
r' R
s (IV) wherein : - V represents vanadium, - Al represents aluminium, - M represents zirconium (Zr), hafnium (Hf), titanium (Ti) or mixtures thereof, preferably titanium or zirconium; - arene represents a benzene, or a benzene substituted by from 1 to 6 linear or branched C
1 -C
6 alkyl groups, or mixtures thereof; - X represents a halogen atom, selected from chlorine, bromine, fluorine, iodine, preferably chlorine; - R represents a linear or branched C
1 -C
15 alkyl group; - p represents a number ranging from 1 to 2; - q is a number ranging from 2 to 6, preferably from 2 to 3; - r is a number ranging from 8 to 20, preferably from 8 to 11; - p represents a number ranging from 1 to 2; - q' is a number ranging from 2 to 6, preferably from 2 to 3; - r' is a number ranging from 2 to 20, preferably from 6 to 9; - s is a number ranging from 1 to 6, preferably 2. The catalyst of the invention is used in a process for the selective hydrogenation of aromatic or polyunsaturated compounds, particularly in the selective hydrogenation of benzene or cyclohexene.

摘要翻译： 本发明的一个目的涉及一种催化剂适合于芳族或多不饱和化合物的选择性加氢，包括： - 从所述氧化物中的至少一种助催化剂（A） - 氧化锆载体（氧化锆） - 钌 - 铁氧化物（Fe2O3的） 基团的金属IB，IIB和IIIA族的 - 含钒的至少一种助催化剂（B），钛，铪，锆或它们的混合物，获得由从下列金属芳烃中选择的至少一种前体PB的水解：V°（芳烃 ）2（I）V（芳烃）2 AlCl4（II）M（ETA-6芳烃）pAlqXr（III）M（ETA-6芳烃）p'Alq'Xr'Rs（IV）其中： - V darstellt钒 - 铝darstellt铝， - 中号darstellt锆（Zr），铪（Hf），钛（Ti）或它们的混合物，优选为钛或锆; - 芳烃darstellt苯，或由1至6的直链苯substituiertem或支链C1-C6烷基基团，或它们的混合物; - X表示卤素原子，选自氯，溴，氟，碘，优选氯选择; - R表示直链或支链C1-C15烷基; - p代表数字范围从1到2; - q是一个数从2到3，从2至6，优选; - r是数从8至11范围从8至20，优选; - p代表数字范围从1到2; - Q“是一个数为2〜3的范围为2至6，优选; - R“是一个数字6至9范围为2至20，优选; - s是数字从1至6，优选2。本发明的催化剂在一个方法用于芳族或多不饱和化合物的选择性加氢，特别是在苯或环己烯的选择性氢化。