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公开(公告)号：EP1537913A1
公开(公告)日：2005-06-08
申请号：EP03795271.0
申请日：2003-09-01
发明人： KOBAYASHI, Shu , SANO, Atsunori , OONO, Keiji
IPC分类号： B01J31/28 , C07C45/62 , C07C49/213 , C07C67/343 , C07C69/618 , C07C69/757 , C07C41/16 , C07C43/215 , C07C45/29 , C07C47/232 , C07C205/34 , C07C201/12 , C07B61/00
CPC分类号： B01J31/06 , B01J2231/44 , B01J2231/645 , B01J2231/70 , C07B2200/11 , C07C17/16 , C07C41/16 , C07C45/29 , C07C45/62 , C07C67/343 , C07D303/16 , C07F15/006 , C07F15/0066 , C07C22/04 , C07C47/232 , C07C49/213 , C07C69/618 , C07C43/215
摘要： The present invention discloses 1) a catalyst composition consisting of a crosslinked organic polymer compound and a palladium catalyst, wherein said catalyst is physically carried on said crosslinked organic polymer compound, 2) a manufacturing method of the above catalyst composition 1), characterized by homogenizing a straight chain organic polymer compound, having a crosslinkable functional group, and a palladium catalyst in a solvent dissolving said straight chain organic polymer compound, then depositing a composition thus formed and subjecting the crosslinkable functional group in said deposit to a crosslinking reaction, 3) a method for substitution reaction at an allyl position, characterized by reacting an allyl carbonate and a neucleophilic agent in the presence of the above catalyst composition 1), and 4) a method for oxidizing an alcohol, characterized by subjecting the above catalyst composition 1) to reaction with an alcohol. The catalyst composition of the present invention can be safely and easily handled without danger of spontaneous ignition, and the like, and is extremely useful as a catalyst for various chemical reactions, and further activity thereof is not decreased by repeated use thereof and a metal catalyst does not leak from a polymer compound which is a carrier thereof.
摘要翻译： 本发明公开了1）由交联的有机高分子化合物和钯催化剂组成的催化剂组合物，其中所述催化剂在所述交联的有机高分子化合物上物理运载，2）上述催化剂组合物1）的制备方法， 具有可交联官能团的直链有机高分子化合物和溶解所述直链有机高分子化合物的溶剂中的钯催化剂，然后沉积由此形成的组合物，并对所述沉积物中的交联性官能团进行交联反应; 3） 在烯丙基位置进行取代反应的方法，其特征在于在上述催化剂组合物1）的存在下使碳酸烯丙酯和亲核试剂反应，和4）一种氧化醇的方法，其特征在于将上述催化剂组合物1） 与酒精反应。 本发明的催化剂组合物可以安全，容易地处理而没有自发点火的危险等，并且作为各种化学反应的催化剂是非常有用的，并且通过反复使用和金属催化剂不会降低其进一步的活性 不会从作为其载体的高分子化合物泄漏。
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公开(公告)号：EP1537913B1
公开(公告)日：2009-07-01
申请号：EP03795271.0
申请日：2003-09-01
发明人： KOBAYASHI, Shu , SANO, Atsunori , OONO, Keiji
IPC分类号： B01J31/28 , C07C45/62 , C07C49/213 , C07C67/343 , C07C69/618 , C07C69/757 , C07C41/16 , C07C43/215 , C07C45/29 , C07C47/232 , C07C205/34 , B01J23/44
CPC分类号： B01J31/06 , B01J2231/44 , B01J2231/645 , B01J2231/70 , C07B2200/11 , C07C17/16 , C07C41/16 , C07C45/29 , C07C45/62 , C07C67/343 , C07D303/16 , C07F15/006 , C07F15/0066 , C07C22/04 , C07C47/232 , C07C49/213 , C07C69/618 , C07C43/215
摘要： (1) A catalyst composition comprising a crosslinked organic polymer and a palladium catalyst, wherein the catalyst is physically supported on the crosslinked organic polymer; (2) a process for producing the catalyst composition (1), characterized by evenly mixing a linear organic polymer having crosslinkable functional groups with a palladium catalyst in a solvent in which the linear organic polymer is soluble, subsequently precipitating the resultant composition, and causing the crosslinkable functional groups contained in the precipitate to undergo a crosslinking reaction; (3) a method of allyl-position-shifting reaction, characterized by causing a nucleophilic agent to act on an allylcarbonic ester in the presence of the catalyst composition (1); and (4) a method of alcohol oxidation, characterized by causing the catalyst composition (1) to act on an alcohol. The catalyst composition has no fear of spontaneous ignition and can be handled safely and easily. It is extremely useful as a catalyst for various chemical reactions. It undergoes no decrease in activity even when used repeatedly. The metal catalyst is not released from the polymer support.
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