NORBORNENE OPEN-RING POLYMERS, PRODUCTS OF HYDROGENATION THEREOF AND PROCESSES FOR THE PRODUCTION OF BOTH
    3.
    发明公开
    NORBORNENE OPEN-RING POLYMERS, PRODUCTS OF HYDROGENATION THEREOF AND PROCESSES FOR THE PRODUCTION OF BOTH 有权
    OPEN NORBORNENRINGPOLYMERE,其加氢及其制备方法这两个产品

    公开(公告)号:EP1238996A4

    公开(公告)日:2003-03-12

    申请号:EP00955005

    申请日:2000-08-25

    申请人: ZEON CORP

    IPC分类号: C08G61/08 C08G63/82

    CPC分类号: C08G61/08

    摘要: A norbornene open-ring polymer having a weight-average molecular weight of 500 to 1,000,000 in terms of polystyrene and a melting point of 140 DEG C or above is produced by polymerizing a norbornene monomer mixture comprising a polycyclic norbornene monomer by using a polymerization catalyst containing as the main component a compound of a Group 6 transition metal of the periodic table bearing at least one imido group and at least two substituents (A) selected from the group consisting of alkoxy, aryloxy, alkylamido and arylamido; and hydrogenation of this polymer gives a product of hydrogenation thereof having a melting point of 140 DEG C or above.

    COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, PRODUCT OF HYDROGENATION OF COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, AND PROCESSES FOR PRODUCING THESE
    7.
    发明公开
    COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, PRODUCT OF HYDROGENATION OF COPOLYMER FORMED BY RING-OPENING POLYMERIZATION, AND PROCESSES FOR PRODUCING THESE 有权
    通过开环聚合生产的共聚物,氢化通过开环POLYERISATION生产的共聚物和其制造方法SAME

    公开(公告)号:EP1275675A4

    公开(公告)日:2004-11-17

    申请号:EP00979975

    申请日:2000-12-07

    申请人: ZEON CORP

    IPC分类号: C08G61/06

    CPC分类号: C08G61/06

    摘要: A copolymer formed by the ring-opening metathesis polymerization of a cycloolefinic monomer having a carboxylic anhydride group selected among cycloheptene derivatives, tetracyclododecene derivatives, and hexacycloheptadecene derivatives with a cycloolefinic monomer selected among bicycloheptene derivatives, bicycloheptene derivatives, tetracyclododecene derivatives, and hexacycloheptadecene derivatives; and a product of hydrogenation of the copolymer. In producing the copolymer, a polymerization catalyst is used which comprises an organoruthenium compound having a heterocyclic carbene compound as a ligand. The copolymer and the hydrogenated copolymer are reduced in permittivity and water absorption, have high adhesion to metals, and have excellent heat resistance.