公开(公告)号：EP2428524A4

公开(公告)日：2018-01-03

申请号：EP11732341

申请日：2011-04-19

申请人： DAELIM IND CO LTD

发明人： KANG SUNG-WOO ,  KIM NAM-KYU ,  JUN YOUNG-JAE ,  KIM MAN-JUNG ,  KIM KIL-SU

IPC分类号： C08F2/34 ,  B01J8/18 ,  B01J19/24 ,  C08F10/00 ,  C08F210/16

CPC分类号： B01J8/44 ,  B01J8/1827 ,  B01J8/1854 ,  B01J8/1863 ,  B01J2208/00274 ,  B01J2208/0092 ,  B01J2208/00929 ,  C08F210/16 ,  C08F2/34 ,  C08F210/14 ,  C08F2500/07 ,  C08F2500/18 ,  C08F2500/08

摘要： A method for preparing polyolefin from alpha-olefin with high productivity using an internal circulating fluidized bed polymerization reactor is disclosed. The method for gas-phase polymerization of alpha-olefin comprising the steps of: supplying circulation gas including one or more alpha-olefins and inert gas into a polymerization reactor; polymerizing the alpha-olefin to polyolefin in two separated polymerisation areas in the polymerization reactor; and discharging produced polyolefin from the polymerization reactor. The polymerization reactor is divided into the two polymerization areas by a draft tube, and an inside of the draft tube forms a riser where growing polyolefin polymers move up in fast fluidization, and an outside of the draft tube forms an annulus where the polyolefin polymers passing the riser move down by gravity, and the polyolefin polymers passing the annulus are introduced to a lower part of the riser again, so that the polyolefin polymers are polymerized during circulating between the riser and the annulus.

公开(公告)号：EP3006469A4

公开(公告)日：2017-05-31

申请号：EP14807017

申请日：2014-06-03

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG SEOK ,  PARK MIN SUP ,  SEO HYUNG JAE ,  LEE SE HYUN

IPC分类号： C08F2/01 ,  C08F4/12 ,  C08F10/08

CPC分类号： C08F110/10 ,  B01J19/24 ,  B01J2219/00168 ,  B01J2219/24

摘要： Disclosed are an apparatus and method for preparing polybutene having various molecular weights by using complex catalysts of different molar ratios. The apparatus for preparing polybutene having various molecular weights, comprises: a complex catalyst preparing device for preparing a high-activity complex catalyst and a low-activity complex catalyst to form highly reactive polybutene through polymerization; a high-molar ratio complex catalyst system for controlling the storage and supply of the high-activity complex catalyst; a low-molar ratio complex catalyst system for controlling the storage and supply of the low-activity complex catalyst; and a reactor to which reaction raw materials including the high-activity complex catalyst, the low-activity complex catalyst, and isobutene are supplied to be polymerized into highly reactive polybutene.

摘要翻译： 公开了通过使用不同摩尔比的配合物催化剂来制备具有不同分子量的聚丁烯的装置和方法。 用于制备具有不同分子量的聚丁烯的设备包括：用于制备高活性络合催化剂和低活性络合催化剂以通过聚合形成高活性聚丁烯的络合催化剂制备装置; 用于控制高活性络合催化剂的储存和供应的高摩尔比络合催化剂体系; 用于控制低活性络合物催化剂的储存和供应的低摩尔比络合催化剂体系; 以及供给包含高活性络合物催化剂，低活性络合物催化剂和异丁烯的反应原料以聚合成高反应性聚丁烯的反应器。

公开(公告)号：EP3040349A4

公开(公告)日：2017-05-03

申请号：EP14841020

申请日：2014-08-28

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG SEOK ,  PARK MIN SUP ,  SEO HYUNG JAE ,  LEE SE HYUN

IPC分类号： C08F6/00 ,  B01D3/00 ,  B01J19/18 ,  C08F2/01 ,  C08F6/10 ,  C08F10/08 ,  C08F110/08

CPC分类号： C08F110/08 ,  B01D3/009 ,  B01J19/18 ,  B01J2219/24 ,  C08F6/00 ,  C08F10/08 ,  C08F2/01

摘要： Disclosed are an apparatus and a method for removing halogens generated during the preparation of polybutene, which are capable of improving the utilization of polybutene and light polymers by removing halogen components contained in the polybutene and the light polymers. The method for removing halogens generated during the preparation of polybutene comprises the steps of: preparing a reaction product by supplying a catalyst and a reaction raw material to a reactor and polymerizing; removing a catalyst component from the reaction product and neutralizing; separating the reaction product into an organic compound and impurities comprising the catalyst component; heating the organic compound to distill an unreacted material; and removing a halogen component in a remaining polymerization mixture after the distillation using a halogen removing catalyst, or removing a halogen component in polybutene and light polymers obtained from the polymerization mixture using the halogen removing catalyst.

摘要翻译： 本发明公开了装置和用于除去的聚丁烯的制备过程中生成的卤素，其能够通过除去包含在聚丁烯与光聚合物的卤素组分提高聚丁烯和光聚合物的利用率的方法。 除去聚丁烯的制备过程中生成的卤素化合物的方法包括以下步骤：通过提供催化剂和反应原料到反应器中并聚合制备的反应产物; 除去反应产物和中和的催化剂组分; 将反应产物分离成有机化合物和杂质包括催化剂组分; 加热该有机化合物以蒸馏未反应的材料; 并且在使用卤素移除催化剂，或在除去从使用卤素移除催化剂聚合混合物获得的聚丁烯和光聚合物卤素组分的蒸馏后剩余的聚合混合物中除去卤素组分。

公开(公告)号：EP3029075A4

公开(公告)日：2017-04-12

申请号：EP14832215

申请日：2014-07-29

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG SEOK ,  PARK MIN SUP ,  MIN KYOUNG TAE

IPC分类号： C08F2/01 ,  B01J8/04 ,  B01J19/00 ,  B01J19/18 ,  C08F10/08

CPC分类号： C08F110/08 ,  B01J8/0457 ,  B01J19/1862 ,  B01J19/24 ,  B01J2219/24 ,  C08F6/003 ,  C08F6/02 ,  C08J11/02 ,  C08F2/01 ,  C08F4/14 ,  C08L23/20

公开(公告)号：EP2998324A4

公开(公告)日：2017-02-15

申请号：EP14797177

申请日：2014-05-15

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG SEOK ,  PARK MIN SUP ,  SEO HYUNG JAE ,  LEE SE HYUN

IPC分类号： C08F2/01 ,  C08F4/12 ,  C08F10/08

CPC分类号： C08F210/10 ,  B01J19/24 ,  B01J2219/24 ,  C08F10/08 ,  C08F110/08 ,  C08F2/01 ,  C08F4/14

摘要： There are disclosed an apparatus and a method for selectively preparing a high reactivity polybutene, a midrange reactivity polybutene and a non-reactive polybutene in a single plant. The apparatus for selectively preparing a reactive polybutene and a non-reactive polybutene, comprises: a reactive polybutene polymerization catalyst feeder for polymerization of the reactive polybutene; a non-reactive polybutene polymerization catalyst feeder for polymerization of the non-reactive polybutene; and a reactor for polymerizing a reactant including isobutene into polybutene, wherein the reactive polybutene polymerization catalyst feeder provides a catalyst to yield the reactive polybutene; and the non-reactive polybutene polymerization catalyst feeder provides a catalyst to yield the non-reactive polybutene.

摘要翻译： 有游离缺失盘计划的装置和用于制备选择性地高反应性聚丁烯，中频反应性聚丁烯，并在单个的非反应性聚丁烯的方法。 用于选择性地制备反应性聚丁烯和一个非反应性聚丁烯，所述设备包括：用于反应性聚丁烯的聚合反应性聚丁烯聚合的催化剂进料器; 非反应性聚丁烯的聚合催化剂进料装置用于非反应性聚丁烯的聚合; 和用于聚合反应物包含异丁烯成聚丁烯，worin反应性聚丁烯聚合的催化剂进料器的反应器提供一种催化剂，以产生反应性聚丁烯; 和所述非反应性聚丁烯聚合的催化剂进料器提供一种催化剂，以产生非反应性聚丁烯。

公开(公告)号：EP2927245A4

公开(公告)日：2016-08-17

申请号：EP13859834

申请日：2013-12-03

申请人： DAELIM IND CO LTD

发明人： SOHN BYUNG-KEEL ,  YU SEUNG-TACK ,  HONG SAH-MUN ,  JUN YONG-JAE ,  KIM DA-JUNG ,  KIM YONG

IPC分类号： C08F4/6592 ,  C08F210/16

CPC分类号： C08F210/16 ,  C08F2/00 ,  C08F4/65912 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/12 ,  C08F4/65904

公开(公告)号：EP2173481A4

公开(公告)日：2011-06-29

申请号：EP08705005

申请日：2008-01-30

申请人： KOREA RESERACH INST OF CHEMICAL TECHNOLOGY ,  DAELIM IND CO LTD ,  KOREA GAS CORP ,  KOREA NAT OIL CORP ,  HYUNDAI ENGINEERING CO LTD ,  SK ENERGY CO LTD

发明人： JUN KI-WON ,  BAE JONG-WOOK ,  KIM SEUNG-MOON ,  LEE YUN-JO

IPC分类号： B01J27/185 ,  B01J23/75 ,  C07C1/04

CPC分类号： B01J23/75 ,  B01J27/16 ,  B01J27/1853 ,  B01J35/10 ,  B01J35/1019 ,  B01J35/1023 ,  B01J35/109 ,  B01J37/0201 ,  B01J37/0207 ,  B01J37/033 ,  B01J37/18 ,  B01J37/28

公开(公告)号：EP2947102A4

公开(公告)日：2016-08-17

申请号：EP14740608

申请日：2014-01-14

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG SEOK ,  PARK MIN SUP ,  SEO HYUNG JAE ,  LEE SE HYUN

IPC分类号： C08F10/10 ,  B01D3/14 ,  C10G7/02

CPC分类号： C08F110/10 ,  C07C5/13 ,  C08F10/10 ,  C10G45/32 ,  C10G45/58 ,  C10G50/00 ,  C10G69/00 ,  C10G69/126 ,  C08F4/14

摘要： Disclosed is a method for preparing a highly reactive polybutene of high quality having low fluorine content and high vinylidene content at high mileage of catalyst with economy. The method for preparing a polybutene includes: performing a selective hydrogenation reaction of diolefin among C4 hydrocarbon components produced from petroleum refineries or naphtha cracking centers, which involve cracking of crude oils, and simultaneously an isomerization reaction of 1-butene to 2-butene and then isolating an isobutene feedstock through fractional distillation; and polymerizing the isobutene feedstock obtained by the fractional distillation.

公开(公告)号：EP2832753A4

公开(公告)日：2015-11-25

申请号：EP13767447

申请日：2013-03-29

申请人： DAELIM IND CO LTD

发明人： SOHN BYUNG-KEEL ,  YU SEUNG-TACK ,  YOO SANG-WON ,  JUN YOUNG-JAE ,  HONG SAH-MUN

IPC分类号： C08F10/00 ,  C08J5/00 ,  C08L23/04 ,  C08L23/06 ,  C08L23/08

CPC分类号： C08F210/16 ,  C08F4/65916 ,  C08F4/65925 ,  C08F4/65927 ,  C08F10/02 ,  C08L23/04 ,  C08L23/06 ,  C08L23/0807 ,  C08L23/0815 ,  C08L2205/025 ,  C08L2207/068 ,  C08L2308/00 ,  C08L2314/06 ,  Y10T428/139 ,  Y10T442/60 ,  C08F4/65904 ,  C08F110/02 ,  C08F2500/04 ,  C08F2500/05 ,  C08F2500/07 ,  C08F2500/12 ,  C08F2500/11 ,  C08F2500/19 ,  C08F2500/20 ,  C08F210/14 ,  C08F4/65912

摘要： Multimodal polyolefin resin having excellent characteristics such as moldability, mechanical strength, external appearance and a polyolefin resin molded product are disclosed. The polyolefin resin satisfies all requirements of following (1) to (5), (1) density (d): 0.934 to 0.963 g/cm3, (2) melt flow index(MIE, 190°C, 2.16 kg load condition): 0.01 to 1.0 g/10 minutes, (3) ratio of weight-average molecular weight (Mw) and number-average molecular weight (Mn) measured by Gel Permeation Chromatography (GPC) (Mw/Mn, Molecular weight distribution (MWD)): 12 to 60, (4) at least two peaks appear when the molecular weight of the polyolefin resin is measured with GPC, and (5) amount of polyolefin having Mw of 10,000 or less exceeds 15 weight% and amount of polyolefin having Mw of 1,000,000 or more exceeds 1.5 weight%, when the molecular weight of the polyolefin resin is measured with GPC.

摘要翻译： 公开了具有成型性，机械强度，外观和聚烯烃树脂成型品等特性优异的多峰聚烯烃树脂。 聚烯烃树脂满足以下（1）〜（5），（1）密度（d）：0.934〜0.963g / cm 3，（2）熔体流动指数（MIE，190℃，2.16kg负载条件）的所有要求： 0.01〜1.0g / 10分钟，（3）通过凝胶渗透色谱法（GPC）（Mw / Mn，分子量分布（MWD））测定的重均分子量（Mw）和数均分子量 ：12〜60，（4）当用GPC测定聚烯烃树脂的分子量时，出现至少两个峰，（5）Mw为10,000以下的聚烯烃的量超过15重量％，Mw的Mw为 当用GPC测量聚烯烃树脂的分子量时，其100万以上超过1.5重量％。

公开(公告)号：EP2684858A4

公开(公告)日：2015-11-11

申请号：EP12746570

申请日：2012-02-17

申请人： DAELIM IND CO LTD

发明人： KIM MYEONG-SEOK ,  UHM JAE-HOON ,  PARK MIN-SUP ,  SEO HYOUNG-JAE ,  MIN KYOUNG-TAE

IPC分类号： C07C11/09 ,  C07B37/06 ,  C07C43/03

CPC分类号： C07C1/22 ,  C07B37/06 ,  C07C1/20 ,  C07C41/06 ,  C07C2531/10 ,  Y02P20/582 ,  C07C11/09 ,  C07C43/10

摘要： Disclosed is a method of preparing isobutene in which high-purity isobutene is separated (prepared) from a C 4 mixture by cracking glycol ether prepared from a C 4 mixture (in particular, C 4 raffinate-1) containing isobutene and a glycol. The method includes cracking glycol ether into isobutene and glycol at a temperature between 50°C and 300°C in the presence of a strongly acidic catalyst. The glycol ether may be prepared by reaction between a C 4 mixture containing isobutene and glycol in the presence of an acid catalyst.

摘要翻译： 公开了一种制备异丁烯的方法，其中通过由含有异丁烯和二醇的C 4混合物（特别是C 4萃余液-1）制备的二醇醚裂化，从C 4混合物中分离（制备）高纯度异丁烯。 该方法包括在强酸性催化剂存在下，在50℃至300℃的温度下将乙二醇醚裂化成异丁烯和二醇。 乙二醇醚可以通过在酸催化剂存在下在含有异丁烯和二醇的C 4混合物之间进行反应来制备。