Process for the preparation of 2,4-dichlorophenoxyacetic acid
    1.
    发明公开
    Process for the preparation of 2,4-dichlorophenoxyacetic acid 失效
    Verfahren zur Herstellung von 2,4-Dichlorphenoxyessigsäure。

    公开(公告)号:EP0509518A1

    公开(公告)日:1992-10-21

    申请号:EP92106647.8

    申请日:1992-04-16

    发明人: Abbruzzese, Luigi

    IPC分类号: C07C51/363

    CPC分类号: C07C51/363 C07C59/70

    摘要: A process is described for the preparation of 2,4-dichlorophenoxyacetic acid consisting of the chlorination of phenoxyacetic acid with chlorine, at temperatures from 0°C to the boiling point of the reaction mixture, in a reaction medium composed of acetic acid.

    摘要翻译: 描述了在由乙酸组成的反应介质中,在0℃至反应混合物的沸点的温度下,由苯氧基乙酸与氯氯化反应制备2,4-二氯苯氧基乙酸的方法。

    Process for producing calcium urea-nitrate
    5.
    发明公开
    Process for producing calcium urea-nitrate 失效
    生产尿素 - 硝酸钙的方法

    公开(公告)号:EP0278562A3

    公开(公告)日:1990-03-28

    申请号:EP88200178.7

    申请日:1988-02-03

    IPC分类号: C07C275/02

    CPC分类号: C07C273/02 C05C5/04 C05C9/00

    摘要: Calcium-urea nitrate [Ca(NO₃)₂.4CO(NH₂)₂] is produced by means of a process, according to which:
    - a liquid composition is prepared, at a temperature not higher than 170°C, which contains urea and calcium nitrate, in a molar ratio to each other equal to, or approximately equal to, 4/1, and having a water content comprised within the range of from 0 to 15% by weight;
    - said liquid composition is sprayed, through a spray nozzle, on previously formed solid particles of calcium-urea nitrate, kept moving at a temperature comprised within the range of from 40 to approximately 100°C, and under a stream of an inert gas;
    - calcium-urea nitrate is recovered from said solid products from the spray. The so obtained calcium-urea nitrate is in the form of a granular and free-flowing solid, free from the tendency to form dusts, and is useful in agriculture as a nitrogenous fertilizer. Also the suitable equipment for carrying out the process of calcium-urea nitrate preparation as a continuous process is disclosed.

    Process for the production of water soluble ammonium phosphates
    6.
    发明公开
    Process for the production of water soluble ammonium phosphates 失效
    生产水溶性磷酸铵的方法

    公开(公告)号:EP0161704A3

    公开(公告)日:1988-06-22

    申请号:EP85200559

    申请日:1985-04-12

    IPC分类号: C01B25/28

    CPC分类号: C01B25/28

    摘要: A process is disclosed for the production of water soluble ammonium phosphates, comprising the following steps:
    a) to react in a reaction step ammonia and untreated phosphoric acid with P 2 0 5 concentration, comprised within the range of from 30 to 54% outcoming from wet processes; b) to filter under high temperature conditions the reaction suspension, separating the impurity-containing sludges from an aqueous solution of ammonium phosphate; c) to cool and crystallize the aqueous solution of ammonium phosphate; d) to separate the formed ammonium phosphate crystals from the mother liquors.

    Process for producing calcium urea-nitrate
    9.
    发明公开
    Process for producing calcium urea-nitrate 失效
    Verfahren zur Herstellung von Calciumnitrat-Harnstoff。

    公开(公告)号:EP0278562A2

    公开(公告)日:1988-08-17

    申请号:EP88200178.7

    申请日:1988-02-03

    IPC分类号: C07C275/02

    CPC分类号: C07C273/02 C05C5/04 C05C9/00

    摘要: Calcium-urea nitrate [Ca(NO₃)₂.4CO(NH₂)₂] is produced by means of a process, according to which:
    - a liquid composition is prepared, at a temperature not higher than 170°C, which contains urea and calcium nitrate, in a molar ratio to each other equal to, or approximately equal to, 4/1, and having a water content comprised within the range of from 0 to 15% by weight;
    - said liquid composition is sprayed, through a spray nozzle, on previously formed solid particles of calcium-urea nitrate, kept moving at a temperature comprised within the range of from 40 to approximately 100°C, and under a stream of an inert gas;
    - calcium-urea nitrate is recovered from said solid products from the spray.
    The so obtained calcium-urea nitrate is in the form of a granular and free-flowing solid, free from the tendency to form dusts, and is useful in agriculture as a nitrogenous fertilizer.
    Also the suitable equipment for carrying out the process of calcium-urea nitrate preparation as a continuous process is disclosed.

    摘要翻译: 通过以下方法制备硝酸钙/硝酸钙[Ca(NO 3)2.4 CO(NH 2)2],其中: - 在不高于170℃的温度下制备液体组合物,其含有尿素和钙 硝酸盐,以相互摩尔比等于或约等于4/1,并且水含量在0至15重量%的范围内; - 所述液体组合物通过喷嘴喷雾在预先形成的硝酸钙的固体颗粒上,并保持在约40至约100℃的范围内并在惰性气体流下移动; - 从喷雾的所述固体产物中回收硝酸钙。 如此得到的尿素 - 硝酸铵是颗粒状和自由流动的固体的形式,没有形成粉尘的倾向,并且在作为氮肥的农业中是有用的。 还公开了用于进行硝酸钙 - 尿素制备工艺的合适设备作为连续方法。

    Process for the production of silicon tetrafluoride
    10.
    发明公开
    Process for the production of silicon tetrafluoride 失效
    Verfahren zur Herstellung von Silizium-Tetrafluorid。

    公开(公告)号:EP0254349A2

    公开(公告)日:1988-01-27

    申请号:EP87201303.2

    申请日:1987-07-08

    IPC分类号: C01B33/107

    CPC分类号: C01B33/10705

    摘要: A continuous process is disclosed for the production, with a high yield, of high purity silicon tetrafluoride, by starting from an aqueous solution of fluosilicic acid, which comprises:

    a) the reaction of an aqueous solution of fluosilicic acid with concentrated sulphuric acid, carried out with a short residence time and preferably under fluido-dynamic conditions of turbulence, inside a reaction zone;
    b) the separation of a gaseous stream containing silicon tetrafluoride from a liquid stream of aqueous sulphuric acid, carried out inside a separation zone, directly connected with the reaction zone;
    c) the washing, with concentrated and cold sulphuric acid, of said gaseous stream, carried out inside a washing zone, for the purpose of separating a gaseous stream of purified silicon tetrafluoride; and, possibly
    d) the further purification of said gaseous stream of purified silicon tetrafluoride, by means of techniques of adsorption on an adsorbent solid material.

    摘要翻译: 公开了通过从氟硅酸的水溶液开始以高产率生产高纯度四氟化硅的连续方法,其包括:a)将氟硅酸水溶液与浓硫酸反应,携带 在反应区内,停留时间短,优选在流动动力条件下的湍流; b)从与反应区直接连接的分离区内部进行含有四氟化硅的气态物流与硫酸水溶液的分离; c)用浓缩和冷的硫酸洗涤在洗涤区内进行的所述气流,以分离纯化的四氟化硅的气流; 并且可能d)通过在吸附剂固体材料上的吸附技术进一步纯化所述纯化四氟化硅的气流。 Ø