摘要:
The invention relates to mixtures that comprise at least one polyester precursor and at least one alkali metal salt and/or alkaline earth metal salt, said mixture comprising at least one phosphonic ester of formula (I) (RO)OC-R'-PO(OR)2, wherein R independently represents a group having 1 to 60 carbon atoms and R' represents a linking group having 1 to 20 carbon atoms. The invention also relates to polyester compositions obtained from the aforementioned mixtures and to polyester films.
摘要:
The invention relates to a method for increasing the molecular weight of a polymer granulate from a polycondenstion system. Said polymer granulate is at least partially crystallised and is brought into direct contact with nitrogen-containing treatment gas which is guided in a circuit in a post condensation stage . The temperature of the polymer granulate in the post condensation stage is increased to between 175 250 °C with respect to the granulate from the polymer condensation system. A nitrogen rich unburnt gas which is obtained from air by means of physical methods and which has a residual oxygen content of between 0.1 5 vol. % and which also contains hydrocarbons is added to the treatment gas before it is directed via an oxidation stage and subsequently, to the post condensation stage.
摘要:
Die Erfindung betrifft ein Verfahren zur Analyse von polymerhaltigen Abfallgegenständen (2) , insbesondere von Teppichen, in einer Recycling-Anlage (1) sowie einen Analyseautomaten (7). Um die Polymerbestandteile des Abfallgegenstandes (2) zu bestimmen, wird erfindungsgemäß ein Teil des Abfallgegenstandes (2) verdampft und mittels eines Massenspektrometers (18) untersucht. Durch das erfindungsgemäße Verfahren und den erfindungsgemäßen Analyseautomaten lassen sich die Abfallgegenstände (2) für die weitere Verarbeitung (9, 10, 11) genauer und zuverlässiger während des Transports auf einer Fördereinrichtung (6) klassifizieren.
摘要:
The invention relates to small pieces of carpet which are introduced into a first impeller type mixer together with an aqueous solution containing a separating salt in order to obtain a first suspension which is guided to a first mechanical separating step. A high-solid phase is extracted therefrom, as is a second high-solid phase which contains a polymer fibre material, and a liquid phase. The second high-solid phase is mixed with a separating solution containing water in an impeller type mixer and a second suspension is produced which is guided to a second mechanical separating step. A third high-solid phase is extracted therefrom, along with a phase rich in polymer fibre material and a liquid phase. An acid is introduced into the impeller-type mixer along with the separating solution containing water, said acid being stronger than H2 CO3, and the pH value of the liquid phase in the impeller type mixer is adjusted to 2-6.
摘要:
The present invention refers to a process for the production and for the winding of at least one polyester multi-filament yam which consists of at least 90 weight %, in relation to the total weight of the polyester multi-filament yarn, of polybutylene terephthalate (PBT) and/or polytrimethylene terephthalate (PTMT), preferably of PTMT, to provide at least one yam package with long-term stability during storage and which is insensitive against elevated temperatures during storage and transport wherein polyester comprises an infrared absorbing pigment and/or a catalyst having infrared absorbing properties and that the polyester multi-filament yam is heat-treated by the use of infrared radiation during winding to a yarn package. In addition the present invention relates to said polyester multi-filament yam obtainable by said process wherein its elongation at break is in the range of > 60 % to 145 % and its boil-off shrinkage is in the range of 0 to 10 %. The present invention also claims a device for the winding of one or more multi-filament yams (3) comprising a commercial winder and at least one infrared radiant heater (9) arranged in a defined distance from the winder shaft (4) thereby irradiating a yarn package (5) which is placed on said winder shaft (4).
摘要:
According to a method for producing polyesters, the esterification of dicarboxylic acids and diols ensues in at least one reaction stage, the pre-polycondensation of the esterification product ensues in at least one reaction stage, and the polycondensation of the pre-polycondensation product ensues in at least one reaction stage. In order to increase the capacity of a system composed of one or more reaction stages and provided for producing polyesters, the supplied product flow, in at least one of the reaction stages, is split into at least two partial flows before or inside the reaction stage, and the partial flows are guided through the reaction stage while being entirely or partially separated from one another.
摘要:
Es wird ein Verfahren zur Herstellung von stabilisiertem Polyamid 6 beschrieben, bei dem man die Amino-Endgruppen von getrocknetem und entmonomerisiertem Polyamid 6 in schmelzflüssiger Phase durch Umsetzung mit einem Lacton oder einem Säureanhydrid blockiert. Das so erhaltene stabilisierte Polyamid 6 weist einen Gesamtgehalt an Oligomeren und Monomeren unter 1 Gewichtsprozent auf.