摘要:
Provided is a technology that sufficiently suppresses dimensional change in the usage environment even without applying heat treatment in advance to a resin-molded article constituted of a crystalline thermoplastic resin. A resin composition constituted of a crystalline thermoplastic resin is injection-molded using a mold on the inner surface of which a heat-insulating layer is formed. It is preferable, in the present invention, to use a mold on which a heat-insulating layer is formed, the layer being constituted of porous zirconia formed by spraying method and having a thermal conductivity of 2W/(m·K) or less and a thickness of no less than 200 µ m. The injection-molded article obtained by the manufacturing method of the present invention has a dimensional change rate of 0.2% or less when left for 2 hours in an environment of a mold temperature + 20°C where the mold temperature is that at the time of injection molding and is Tg+30°C or more and Tg+80°C or less, in which Tg is a glass transition temperature of the crystalline thermoplastic resin.
摘要:
Provided is a method for manufacturing a mold for manufacturing a molded article, by which not only is the occurrence of flash suppressed but also the crystallization of the surface is sufficiently accelerated when the mold temperature during the molding of a crystalline thermoplastic resin is set at T c2 -100°C or less. Based on a relationship between crystallization rate and resin temperature of the crystalline thermoplastic resin, a temperature at which the crystalline thermoplastic resin filled into a mold has a sufficiently fast crystallization rate near a cavity surface and a retention time during which the crystalline thermoplastic resin in the mold is retained at a temperature equal to at least at a temperature at which the resin has the sufficiently fast crystallization rate are derived, such that the derived temperature and the derived retention time allow the molded article to have a surface whose crystallinity falls within a desired range, and a heat-insulating layer which, when mold temperature is T c2 -100°C or less, allows a time, during which temperature near surface of the mold cavity is retained at no less than the derived temperature, to fulfill the derived retention time is provided.