公开(公告)号：EP2660907B1

公开(公告)日：2018-09-26

申请号：EP11852696.1

申请日：2011-12-27

申请人： GS Yuasa International Ltd.

发明人： ENDO, Daisuke ,  KATAYAMA , Yoshihiro ,  MURAI , Tetsuya ,  SHIBATA, Masafumi

IPC分类号： H01M4/525 ,  H01M4/505 ,  H01M10/44 ,  H01B1/08 ,  C01G53/00 ,  H01M10/052

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1228 ,  C01G51/44 ,  C01G51/50 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/77 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01B1/08 ,  H01M4/0471 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028 ,  Y02E60/122 ,  Y02P70/54 ,  Y02T10/7011

摘要： An object of the present invention is to provide a positive active material for a nonaqueous electrolyte secondary battery which has a large discharge capacity and is superior in charge-discharge cycle performance, initial efficiency and high rate discharge performance, and a nonaqueous electrolyte secondary battery using the positive active material. The present invention pertains to a positive active material for a nonaqueous electrolyte secondary battery containing a lithium transition metal composite oxide which has a crystal structure of an ±-NaFeO 2 type, is represented by a compositional formula Li 1+± Me 1-± O 2 (Me is a transition metal element including Co, Ni and Mn, ± > 0), and has a molar ratio Li/Me of Li to the transition metal element Me of 1.2 to 1.6, wherein a molar ratio Co/Me of Co in the transition metal element Me is 0.02 to 0.23, a molar ratio Mn/Me of Mn in the transition metal element Me is 0.62 to 0.72, and the lithium transition metal composite oxide is observed as a single phase attributed to a space group R3-m on an X-ray diffraction chart when it is electrochemically oxidized up to a potential of 5.0 V (vs. Li/Li + ).

公开(公告)号：EP1137598B2

公开(公告)日：2016-03-16

申请号：EP99960299.8

申请日：1999-11-12

申请人： UMICORE

发明人： GAO, Yuan ,  YAKOVLEVA, Marina ,  WANG, Hugh, H. ,  ENGEL, John, F.

IPC分类号： C01G45/12 ,  C01G53/00 ,  C01G51/00 ,  C01G1/02 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M4/525 ,  H01M10/052 ,  H01M10/0525

CPC分类号： H01M4/525 ,  C01G1/02 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2002/88 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

公开(公告)号：EP2724397A4

公开(公告)日：2015-11-25

申请号：EP12802556

申请日：2012-06-21

申请人： BASF CORP

发明人： PETROVIC IVAN ,  THURSTON ANTHONY ,  SHEARGOLD STEPHEN

IPC分类号： H01M4/1391 ,  C04B35/64 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525

CPC分类号： C01G45/1221 ,  C01G45/1228 ,  C01G51/44 ,  C01G51/50 ,  C01G53/44 ,  C01G53/50 ,  C01P2002/72 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/505 ,  H01M4/525 ,  Y02E60/122

摘要： A method for preparing a layered oxide cathode using a two step calcination procedure, wherein the first step includes pre-calcination utilizing a rotary calciner.

公开(公告)号：EP2492243A1

公开(公告)日：2012-08-29

申请号：EP10825034.1

申请日：2010-10-21

申请人： Toda Kogyo Corporation

发明人： KOBINO, Masashi ,  FUJITA, Katsuhiro ,  FUJINO, Shoichi ,  KAJIYAMA, Akihisa ,  MASAKI, Ryuta ,  MORITA, Daisuke ,  YAMAMURA, Takayuki ,  KODAIRA, Tetsuya ,  YAMASAKI, Minoru ,  OKAZAKI, Seiji ,  HIRAMOTO, Toshiaki ,  ITO, Akino ,  ODA, Wataru ,  OKINAKA, Kenji

IPC分类号： C01G53/00 ,  H01M4/505 ,  H01M4/525

CPC分类号： C01G45/006 ,  C01G45/1221 ,  C01G51/006 ,  C01G51/44 ,  C01G53/006 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/52 ,  C01P2002/60 ,  C01P2002/72 ,  C01P2004/03 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/11 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/505 ,  H01M4/525 ,  H01M10/052 ,  Y10T428/2982

摘要： The present invention relates to nickel-cobalt-manganese-based compound particles which have a volume-based average secondary particle diameter (D50) of 3.0 to 25.0 µm, wherein the volume-based average secondary particle diameter (D50) and a half value width (W) of the peak in volume-based particle size distribution of secondary particles thereof satisfy the relational formula: W ≤ 0.4 x D50, and can be produced by dropping a metal salt-containing solution and an alkali solution to an alkali solution at the same time, followed by subjecting the obtained reaction solution to neutralization and precipitation reaction. The nickel-cobalt-manganese-based compound particles according to the present invention have a uniform particle size, a less content of very fine particles, a high crystallinity and a large primary particle diameter, and therefore are useful as a precursor of a positive electrode active substance used in a non-aqueous electrolyte secondary battery.

公开(公告)号：EP0858677B1

公开(公告)日：2001-12-05

申请号：EP97932884.6

申请日：1997-07-10

申请人： SAFT

发明人： BIENSAN, Philippe ,  GALLET, Damien ,  SIMON, Bernard

IPC分类号： H01M4/48

CPC分类号： H01M4/485 ,  C01G45/1228 ,  C01G49/0027 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/52 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/505 ,  H01M4/525

公开(公告)号：EP1137598A1

公开(公告)日：2001-10-04

申请号：EP99960299.8

申请日：1999-11-12

申请人： FMC CORPORATION

发明人： GAO, Yuan ,  YAKOVLEVA, Marina ,  WANG, Hugh, H. ,  ENGEL, John, F.

IPC分类号： C01G51/00 ,  C01G1/00 ,  H01M4/52

CPC分类号： H01M4/525 ,  C01G1/02 ,  C01G45/1228 ,  C01G51/42 ,  C01G51/44 ,  C01G53/42 ,  C01G53/44 ,  C01P2002/32 ,  C01P2002/52 ,  C01P2002/54 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2002/86 ,  C01P2002/88 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/1391 ,  H01M4/485 ,  H01M10/052 ,  H01M10/0525 ,  H01M2004/028

摘要： The present invention includes substantially single-phase lithium metal oxide compounds having hexagonal layered crystal structures that are substantially free of localized cubic spinel-like structural phases. The lithium metal oxides of the invention have the formula LiαMβAηO2, wherein M is one or more transition metals, A is one or more dopants having an average oxidation state N such that +2.5 ≤ N ≤ +3.5, 0.90 ≤ α ≤ 1.10, and β + η = 1. The present invention also includes dilithiated forms of these compounds, lithium and lithium-ion secondary batteries using these compounds as positive electrode materials, and methods of preparing these compounds.

公开(公告)号：EP0929111A1

公开(公告)日：1999-07-14

申请号：EP98929778.3

申请日：1998-06-30

申请人： MATSUSHITA ELECTRIC INDUSTRIAL CO., LTD.

发明人： KAWANO, Tomoko ,  KOBAYASHI, Shigeo ,  WATANABE, Shoichiro ,  FUJIWARA, Takafumi ,  HASHIMOTO, Akira ,  SYOJI, Yasuhiko

IPC分类号： H01M4/58 ,  H01M4/04 ,  H01M4/02 ,  H01M10/40

CPC分类号： H01M4/485 ,  C01G51/42 ,  C01G51/44 ,  C01G53/00 ,  C01G53/42 ,  C01G53/44 ,  C01G55/002 ,  C01P2004/32 ,  C01P2004/51 ,  C01P2004/61 ,  C01P2006/40 ,  H01M4/131 ,  H01M4/133 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0587

摘要： Lithium composite metal oxides prepared by mixing at least one type of hydroxides, oxides, and carbonates of a metal selected from the group of transition metal, IIA metal, and IIIA metal, and a lithium compound of which the D50 value is in the range 5 to 50 µm, the D90 value is 90 µm or smaller, and in which particles 100 µm or greater do not exist, and calcinating in the temperature range 700 to 1000°C for 2 to 30 hours, and grinding, are used as the active material of a positive electrode which is laminated with a negative electrode with a separator interposed and spirally wound thereby forming an electrode group. By using the positive active materials prepared in this manner, discharge capacity and cycle characteristic of a non-aqueous electrolyte secondary cell can be improved.

摘要翻译： 通过混合至少一种类型的氢氧化物，氧化物，和选自过渡金属，ⅡA金属，和IIIA族金属中选出的金属的碳酸盐的制备锂复合金属氧化物，和其中的锂化合物的D50值是范围为5 到50微米，D90的值是90微米或更小，并且其中颗粒100微米或更大的不存在，和煅烧在温度范围700〜1000℃下进行2至30小时，和研磨，使用 作为正极的所有被层压带的隔膜的负极和螺旋卷绕从而以电极组形成的活性材料。 通过使用以这种方式，放电容量和非水电解质二次电池的循环特性中制备的正极活性材料可以被改善。

公开(公告)号：EP2895428B1

公开(公告)日：2018-11-14

申请号：EP13762460.7

申请日：2013-09-11

申请人： SAFT ,  Umicore

发明人： JORDY, Christian ,  CAILLON, Georges ,  HEZEQUE, Thierry ,  LEVASSEUR, Stéphane ,  KOSOVA, Nina V. ,  DEVYATKINA, Evgeniya T.

IPC分类号： C01G53/00 ,  C01G51/00 ,  C01G45/12 ,  H01M4/131 ,  H01M10/0525 ,  H01M4/1391 ,  H01B1/08 ,  H01M4/36 ,  H01M4/38 ,  H01M4/485 ,  H01M4/505 ,  H01M4/62 ,  H01M4/525 ,  H01M4/587

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1285 ,  C01G51/44 ,  C01G51/62 ,  C01G53/44 ,  C01G53/62 ,  C01P2002/72 ,  C01P2002/76 ,  H01B1/08 ,  H01M4/36 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/625 ,  H01M10/0525

公开(公告)号：EP1846331B1

公开(公告)日：2017-05-17

申请号：EP06709499.5

申请日：2006-02-10

申请人： Commissariat à l'Énergie Atomique et aux Énergies Alternatives

发明人： JOUANNEAU, Séverine ,  LE CRAS, Frédéric ,  BOURBON, Carole

IPC分类号： C01G45/12 ,  C01G51/00 ,  H01M4/48 ,  H01M4/50 ,  H01M4/52 ,  C01G53/00 ,  H01M4/525 ,  H01M4/505 ,  H01M10/0525

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G51/44 ,  C01G53/44 ,  C01P2002/52 ,  C01P2004/61 ,  C01P2006/12 ,  C01P2006/40 ,  H01M4/525 ,  H01M10/0525

公开(公告)号：EP2895428A1

公开(公告)日：2015-07-22

申请号：EP13762460.7

申请日：2013-09-11

申请人： SAFT ,  Umicore

发明人： JORDY, Christian ,  CAILLON, Georges ,  HEZEQUE, Thierry ,  LEVASSEUR, Stéphane ,  KOSOVA, Nina V. ,  DEVYATKINA, Evgeniya T.

IPC分类号： C01G45/12 ,  C01G53/00 ,  C01G51/00 ,  H01M4/131 ,  H01M10/0525 ,  H01M4/1391

CPC分类号： H01M4/505 ,  C01G45/1221 ,  C01G45/1285 ,  C01G51/44 ,  C01G51/62 ,  C01G53/44 ,  C01G53/62 ,  C01P2002/72 ,  C01P2002/76 ,  H01B1/08 ,  H01M4/36 ,  H01M4/386 ,  H01M4/387 ,  H01M4/485 ,  H01M4/525 ,  H01M4/587 ,  H01M4/625 ,  H01M10/0525

摘要： The invention relates to a compound, having the formula Li
4+x MnM
1
a M
2
b O
c , wherein: M
1 is selected from the group comprising Ni, Mn, Co, Fe, and a mixture thereof; M
2 is selected from the group comprising Si, Ti, Mo, B, Al, and a mixture thereof, where -1.2≤x≤3, 0 2 is selected from the group comprising Si, Ti, Mo, or a mixture thereof; and n = 1.5 when M
2 is selected from the group comprising B and Al, or a mixture thereof; and n = 0 if b = 0.

摘要翻译： 式Li4 + xMnM1aM2bOc的化合物，其中：M1选自Ni，Mn，Co，Fe及其混合物; M2选自Si，Ti，Mo，B，Al及其混合物; 与：-1.2＆nlE; x＆nlE; 3; 0 <＆NLE; 2.5; 0＆NLE; B＆NLE; 1.5; 4.3＆NLE; C＆NLE; 10; 和c = 4 + a + n·b + x / 2，其中当M2选自Si，Ti，Mo或其混合物时，n = 2; 当M2选自B，Al或其混合物时，n = 1.5; 如果b = 0，则n = 0。