摘要:
CO hydrogenation process for producing alcohols is described utilizing novel thallium-promoted iron catalysts (Fe : T1 100:1 to 1:100). Mixtures of CO/H 2 (1:4 to 4:1 volumes) are selectively converted to liquid C 6 -C 12 hydrocarbons containing C 6 -C 12 alcohols with attendant low methane and low CO 2 make.
摘要:
The surface area of a zinc oxide composition is increased, and stabilized to heating, by incorporation of a tri or tetravalent metal, especially aluminium or gallium, e.g. in the form of a spinel with the zinc oxide. The composition is preferably made by coprecipitation of zinc and a compound of said metal and then calcination. The zinc oxide composition may also incorporate a Group VIII metal and be used as a catalyst for a Fischer Tropsch process.
摘要:
Use a supported catalyst that includes a catalyst support and a combination of nickel, gallium, and, optionally, one or more of an alkali metal, an alkaline earth metal and a lanthanide to effect non-oxidative dehydrogenation of an oxygen-free gaseous stream that comprises an alkane such as ethane, propane or butane to a product stream that comprises a corresponding alkene such as propylene where the alkane is propane.
摘要:
Catalytic composition for producing an alpha - olefin and methods of making same. The catalytic composition includes a gamma - alumina substrate dopes with at least one element consisting of bismuth, copper, gallium, phosphorus, tin, and zinc, an amount of each element being within a range of from 150 parts per million to 1000 parts per million relative to a total doped weight of the gamma - alumina substrate. Additionally, at least one element is combined with at least one element consisting of cesium, lithium, and magnesium, an amount of each element being within the range of from 150 parts per million to 1000 parts per million relative to the total doped weight of the gamma-alumina substrate.
摘要:
Provided is a catalyst including a mixture of metal A selected from Fe, Co and Ni, and metal B selected from Zn and Ga, and a support material, where the two metals are present in an intermetallic composition; A method for the manufacture of the catalyst; and the use of the catalyst for the selective hydrogenation of acetylene to ethylene in a gas mixture including acetylenic impurities and hydrogen, and one or more of ethylene and carbon monoxide. The catalyst has a high selectivity and is based an easily available metal compounds.
摘要:
The surface area of a zinc oxide composition is increased, and stabilized to heating, by incorporation of a tri or tetravalent metal, especially aluminium or gallium, e.g. in the form of a spinel with the zinc oxide. The composition is preferably made by coprecipitation of zinc and a compound of said metal and then calcination. The zinc oxide composition may also incorporate a Group VIII metal and be used as a catalyst for a Fischer Tropsch process.