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    Solid titanium catalyst component and use thereof in the production of olefin polymers or copolymers
    4.
    发明公开
    Solid titanium catalyst component and use thereof in the production of olefin polymers or copolymers 失效
    固体钛催化剂组分，和在均聚物和烯烃的共聚物的制备中的用途。

    公开(公告)号：EP0018738A1

    公开(公告)日：1980-11-12

    申请号：EP80301160.0

    申请日：1980-04-10

    申请人： MITSUI PETROCHEMICAL INDUSTRIES, LTD.

    发明人： Toyota, Akinori ,  Kashiwa, Norio

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  Y10S526/903 ,  C08F4/651 ,  C08F4/6455 ,  C08F4/654

    摘要： A solid titanium catalyst component for use in the production of olefin polymers or copolymers comprises titanium, magnesium, halogen and an electron donor as essential ingredients, and further comprises an inert liquid hydrocarbon in an amount of, based on the weight of said component, of 1 to 10%when said component has a uniformity coefficient of at least4, and 1 to 25%when said component has a uniformity coefficient of less than 4.
    The solid titanium catalyst component finds use as one component of a polymerisation catalyst also comprising an organometallic compound of a metal of Groups I to III of the Periodic Table in the production of olefin polymers and copolymers The presence of the inert liquid hydrocarbon affords polymers and copolymers of high bulk density, high stereospecifity and reduced content of fines. By controlling the amount of the liquid hydrocarbon in the titanium catalyst component reproducible results can be achieved.

    Titanium halide material and production thereof
    6.
    发明公开
    Titanium halide material and production thereof 失效
    Titan-Halogenid-Material和Dessen Herstellung。

    公开(公告)号：EP0026655A1

    公开(公告)日：1981-04-08

    申请号：EP80303400.8

    申请日：1980-09-26

    申请人： IMPERIAL CHEMICAL INDUSTRIES PLC

    发明人： Parsons, Ian William ,  Licchelli, John Andrew ,  Caunt, Anthony David

    IPC分类号： C08F10/00 ,  C08F4/64

    CPC分类号： C08F10/00 ,  C08F4/6546 ,  C08F4/6455

    摘要： A titanium halide material has the composition TiCl y xMgCl 2 where y is 1.2to 2.9, typically 1.5 to 2.2, and x is at least 4, preferably between 6 and 10. The material may have a surface area in excess of 200 m 2 /g and a porosity in excess of 0.40 cm 3 /g. This material can be prepared by premixing titanium tetrachloride with a halocarbon compound which may contain hydrogen, for example carbon tetrachloride, reacting the mixture with an organo-magnesium compound, optionally separating and drying the solid product and thereafter treating this product with titanium tetrachloride. The transition metal composition can be used as a component of an olefin polymerisation catalyst to give a high yield of a polyolefin such as polyethylene or polypropylene.

    摘要翻译： 卤化钛材料具有TiClyxMgCl 2的组成，其中y为1.2至2.9，通常为1.5至2.2，x为至少4，优选为6至10。该材料可具有超过200m 2 / g的表面积 并且孔隙率超过0.40cm 3 / g。 该材料可以通过将四氯化钛与可能含有氢的卤化碳化合物（例如四氯化碳）预混合来制备，使混合物与有机镁化合物反应，任选地分离和干燥固体产物，然后用四氯化钛处理该产物。 过渡金属组合物可用作烯烃聚合催化剂的组分，以产生高产率的聚烯烃如聚乙烯或聚丙烯。