公开(公告)号：EP3344728A1

公开(公告)日：2018-07-11

申请号：EP16759780.6

申请日：2016-09-01

申请人： Shell Internationale Research Maatschappij B.V.

发明人： DEN BREEJEN, Johan, Peter ,  VAN BAVEL, Alexander, Petrus ,  VAN DEN BRINK, Peter, John

IPC分类号： C10G2/00 ,  B01J37/18

CPC分类号： C10G2/332 ,  B01J21/063 ,  B01J23/75 ,  B01J37/18 ,  C10G2/341 ,  C10G2300/4031 ,  C10G2300/705

摘要： The invention relates to a method for start-up and operation of a Fischer-Tropsch reactor comprising the steps of: providing a reactor with a fixed bed of Fischer-Tropsch catalyst precursor that comprises cobalt as catalytically active metal; supplying an initial hydrogen containing gaseous feed stream to the reactor, at a reduction temperature and pressure; supplying a further gaseous feed stream comprising carbon monoxide and hydrogen to the reactor; converting carbon monoxide and hydrogen supplied with the second gaseous feed stream to the reactor into hydrocarbons at a reaction temperature, wherein the reaction temperature is set at a value of at least 200° C. and hydrocarbons are produced.

公开(公告)号：EP2918659A1

公开(公告)日：2015-09-16

申请号：EP13853485.4

申请日：2013-11-06

申请人： Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

发明人： ITO Takeo ,  MURATA Atsushi ,  YAMADA Eiichi ,  KATO Yuzuru ,  ONISHI Yasuhiro

IPC分类号： C10G2/00

CPC分类号： C10G2/32 ,  C10G2/342 ,  C10G2/344 ,  C10G2300/4031

摘要： A start-up method for a hydrocarbon synthesis reaction apparatus, comprising: an initial slurry-loading step in which the slurry is loaded into the reactor at the initial stage of the Fischer-Tropsch synthesis reaction at a lower loading rate than that applied to the reactor in a steady-state operation; and a CO conversion ratio-increasing step in which the liquid level of the slurry in the reactor is raised by adding to the slurry the hydrocarbons synthesized at the early stage of the Fischer-Tropsch synthesis reaction so that the CO conversion ratio is increased in proportion to a rise in the liquid level of the slurry in the reactor.

摘要翻译： 一种烃合成反应装置的启动方法，包括：初始浆料加载步骤，其中在费 - 托合成反应的初始阶段，浆料以比施加到 反应堆处于稳态运行; 以及CO转化率增加步骤，其中通过向所述浆料中添加在费 - 托合成反应的早期阶段合成的烃使得CO转化率按比例增加而升高反应器中的浆料的液面 以使反应器中浆液的液面升高。

公开(公告)号：EP2829513A1

公开(公告)日：2015-01-28

申请号：EP14075048.0

申请日：2014-07-16

申请人： Salzgitter Mannesmann Line Pipe Gmbh

发明人： Kocks, Hans-Jürgen, Dr. ,  Winkels, Jörn

IPC分类号： C01B3/36 ,  C10G2/00

CPC分类号： C01B3/36 ,  C01B2203/025 ,  C01B2203/062 ,  C01B2203/148 ,  C01B2203/1604 ,  C10G2/32 ,  C10G2300/1022 ,  C10G2300/4031 ,  C10G2300/4043 ,  Y02P20/133 ,  Y02P20/134 ,  Y02P30/446

摘要： Verfahren zur Erzeugung von Energie durch einen Verbrennungsprozess mit vermindertem CO 2 -Ausstoß, bei dem zum Start ein fossiler Brennstoff unterstöchiometrisch verbrannt wird, das dabei entstehende Kohlenmonoxid in einem katalytischen Syntheseverfahren mit unabhängig vom Verbrennungsprozess erzeugtem Wasserstoff in einen kohlenwasserhaltigen Brennstoff umgewandelt wird, und anschließend der Verbrennungsprozess mit optionaler Zuführung weiterer fossiler Brennstoffe durch Verbrennung des vorher erzeugten kohlenwasserstoffhaltigen Brennstoffs in einem Reaktionskreislauf weitergeführt wird.

摘要翻译： 一种用于生产能量的燃烧过程具有减少CO 2的排放量，其中化石燃料亚化学计量燃烧的启动过程中，所得到的一氧化碳被转化中的催化合成过程，只是用含烃燃料，无论燃烧过程氢的产生，然后将 燃烧过程继续通过预先在反应周期中生成的烃类燃料的燃烧的额外的化石燃料可选喂养。

公开(公告)号：EP2687578A1

公开(公告)日：2014-01-22

申请号：EP12756963.0

申请日：2012-03-13

申请人： Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

发明人： ARAI, Shinya

IPC分类号： C10G2/00

CPC分类号： B01J8/08 ,  B01J2208/00796 ,  C07C1/02 ,  C10G2/00 ,  C10G2300/1022 ,  C10G2300/304 ,  C10G2300/4031

摘要： The hydrocarbon production apparatus is provided with a gas-liquid separator for cooling gaseous state hydrocarbons drawn out from a gas phase portion of a reactor for the Fischer-Tropsch synthesis reaction and liquefying a portion of the hydrocarbons. A light liquid hydrocarbon supply line for supplying light hydrocarbons is disposed between a downstream side line which is downstream from the last stage of a gas-liquid separating unit of the gas-liquid separator, and an upstream side line which is upstream from the last stage of the gas-liquid separating unit of the gas-liquid separator, wherein the downstream side line is a liquid hydrocarbon line on the downstream side through which the light hydrocarbons having cloud points lower than the temperature at an outlet of a cooler in the last stage of the gas-liquid separating unit are flowed.

摘要翻译： 烃制造装置设置有用于冷却从费 - 托合成反应的反应器的气相部分抽出的气态烃并液化一部分烃的气液分离器。 用于供给轻质烃的轻液态碳氢化合物供给管路配置在气液分离器的气液分离装置的最后级的下游侧的下游侧管线和最后级的上游侧的上游侧管线 气液分离器的气液分离单元，其中下游侧线是下游侧的液体烃管线，其中浊点低于最后阶段的冷却器出口处的温度点 的气液分离装置。

公开(公告)号：EP2607459A1

公开(公告)日：2013-06-26

申请号：EP11818168.4

申请日：2011-08-12

申请人： Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  JX Nippon Oil & Energy Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

发明人： TAKAHASHI, Shinya ,  TASAKA, Kazuhiko ,  TANAKA, Yuichi ,  IWAMA, Marie

IPC分类号： C10G75/00 ,  B08B3/08 ,  B08B9/08 ,  C10G2/00 ,  C10G47/00

CPC分类号： B08B3/04 ,  B01J38/52 ,  B01J38/56 ,  B08B9/08 ,  C10G1/06 ,  C10G2/32 ,  C10G21/12 ,  C10G47/00 ,  C10G47/22 ,  C10G47/36 ,  C10G2300/1014 ,  C10G2300/1022 ,  C10G2300/4031 ,  C10G2300/44 ,  Y02P30/20

摘要： The method for cleaning a reactor of the present invention comprises passing a solvent through a wax-fraction hydrocracking apparatus which is charged with a catalyst and to which supply of a wax fraction is stopped, wherein the solvent comprising at least one oil selected from a group consisting of hydrocarbon and vegetable oils, and having a sulfur content of less than 5 ppm and being in a liquid state at 15°C.

摘要翻译： 用于清洗本发明的反应器的方法包括使溶剂通过装有催化剂的蜡馏分加氢裂化装置，并停止供应蜡馏分，其中所述溶剂包含至少一种选自下组的油： 由烃和植物油组成，硫含量小于5ppm，在15℃处于液态。

公开(公告)号：EP2351819A4

公开(公告)日：2013-01-02

申请号：EP09817437

申请日：2009-09-25

申请人： JX NIPPON OIL & ENERGY CORP ,  JAPAN OIL GAS & METALS JOGMEC ,  INPEX CORP ,  JAPAN PETROLEUM EXPLORATION CO ,  COSMO OIL CO LTD ,  NIPPON STEEL ENG CO LTD

发明人： TANAKA YUICHI ,  HONDA HIDEKATSU

IPC分类号： C10G45/02 ,  C10G2/00 ,  C10G59/02

CPC分类号： C10G45/02 ,  C10G45/00 ,  C10G59/02 ,  C10G2300/1022 ,  C10G2300/1044 ,  C10G2300/4031 ,  C10G2300/44 ,  C10G2400/02

公开(公告)号：EP2351819A1

公开(公告)日：2011-08-03

申请号：EP09817437.8

申请日：2009-09-25

申请人： JX Nippon Oil & Energy Corporation ,  Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel Engineering Co., Ltd

发明人： TANAKA, Yuichi ,  HONDA, Hidekatsu

IPC分类号： C10G45/02 ,  C10G2/00

CPC分类号： C10G45/02 ,  C10G45/00 ,  C10G59/02 ,  C10G2300/1022 ,  C10G2300/1044 ,  C10G2300/4031 ,  C10G2300/44 ,  C10G2400/02

摘要： A method for starting-up a naphtha fraction hydrotreating reactor which subjects a naphtha fraction obtained in a fractionator by fractional distillation of hydrocarbon compounds produced by a Fischer-Tropsch synthesis reaction to hydrotreating, the method comprising: charging in advance an inactive hydrocarbon compound corresponding to the naphtha fraction into a vapor-liquid separator to which hydrogenated naphtha, which has been subjected to hydrotreating in the naphtha fraction hydrotreating reactor, is transferred; mixing the inactive hydrocarbon compound drawn from the vapor-liquid separator and the naphtha fractions being transferred from the fractionator to the naphtha fraction hydrotreating reactor; and supplying a mixture of the naphtha fractions and the inactive hydrocarbon compound to the naphtha fraction hydrotreating reactor.

摘要翻译： 一种用于启动石脑油馏分加氢处理反应器的方法，其将通过分馏塔分馏塔中得到的石脑油馏分分馏通过费 - 托合成反应生成的烃化合物进行加氢处理，该方法包括：预先将对应于 石脑油馏分转移到在石脑油馏分加氢处理反应器中进行加氢处理的氢化石脑油的气液分离器中; 将从气液分离器抽出的惰性烃化合物和从分馏塔转移到石脑油馏分加氢处理反应器的石脑油馏分混合; 并将所述石脑油馏分和所述无活性烃化合物的混合物供给到所述石脑油馏分加氢处理反应器。

公开(公告)号：EP0231988A1

公开(公告)日：1987-08-12

申请号：EP87300015.2

申请日：1987-01-05

申请人： EXXON RESEARCH AND ENGINEERING COMPANY

发明人： Arcuri, Kym Brian

IPC分类号： C07C1/04

CPC分类号： C07C1/047 ,  C10G2300/4031

摘要： The start-up period of a Fisher-Tropsch process reactor is substantially reduced by introducing the feed at a rate from 30 to 100% of total flow-rate at the lined-out conditions, the hydrogen rate being from 15 to 90% of the hydrogen rate at lined-out operation and the mol ratio H 2 /CO not exceeding 90% of the mol ratio at lined-out conditions, raising the pressure or the pressure and temperature until either the space-time-yield of products corresponds with the lined-out yield or the pressure and temperature are those at lined-out conditions, and then increasing the mol ratio of H 2 /CO to that employed at lined-out conditions.

摘要翻译： 通过以排出条件的总流速的30至100％的速率引入进料，费托合成反应器的启动时间大大降低，氢气的比例为15〜90％ 在排出运行时的氢气速率和摩尔比H2 / CO不超过排出条件下的摩尔比的90％，提高压力或压力和温度，直到产品的时空产量对应于排出的 产量或压力和温度是在排出条件下的压力和温度，然后增加H 2 / CO与在排出条件下使用的摩尔比。

公开(公告)号：EP2351818B1

公开(公告)日：2018-10-31

申请号：EP09817432.9

申请日：2009-09-25

申请人： JXTG Nippon Oil & Energy Corporation ,  Japan Oil, Gas and Metals National Corporation ,  INPEX Corporation ,  Japan Petroleum Exploration Co., Ltd. ,  Cosmo Oil Co., Ltd. ,  Nippon Steel & Sumikin Engineering Co., Ltd.

发明人： TANAKA, Yuichi ,  HONDA, Hidekatsu

IPC分类号： C10G7/12 ,  C10G2/00 ,  C10G7/00

CPC分类号： C10G7/00 ,  C10G2/32 ,  C10G7/12 ,  C10G2300/1022 ,  C10G2300/4031

摘要： A start-up method of a fractionator which fractionally distills FT synthesized hydrocarbons produced by the Fischer-Tropsch synthesis reaction, the method includes: discharging light FT synthesized hydrocarbons which exist in a gaseous state in an FT reactor performing the Fischer-Tropsch synthesis reaction from the FT reactor to the outside; cooling down the light FT synthesized hydrocarbons discharged from the FT reactor for liquefaction; supplying the liquefied light FT synthesized hydrocarbons to the fractionator; and heating the light FT synthesized hydrocarbons and circulating the light FT synthesized hydrocarbons to the fractionator.

公开(公告)号：EP3321345A1

公开(公告)日：2018-05-16

申请号：EP17205115.3

申请日：2013-08-29

申请人： Steeper Energy ApS

发明人： IVERSEN, Steen Brummerstedt

IPC分类号： C10G1/00 ,  C10G1/06 ,  C10G3/00

CPC分类号： C10G1/065 ,  B08B9/08 ,  C10G1/008 ,  C10G3/40 ,  C10G3/50 ,  C10G3/60 ,  C10G2300/4031 ,  C10G2300/42 ,  C10G2300/805 ,  Y02P30/20

摘要： The invention relates to a continous process for converting carbonaceous material contained in one or more feedstocks into a liquid hydrocarbon product, said feedstocks including the carbonaceous material being in a feed mixture including one or more fluids, said fluids including water, the process comprising:converting at least part of the carbonaceous material, and further in a state of cleaning the pressure and temperature is set to a predetermined desired level; where prior to the cleaning, the inflow of feed mixture is terminated and the system is filled with a fluid, where the temperature and the pressure are altered to the predetermined level at a predetermined rate and where the pressure is constantly kept at a level above the saturation pressure for the fluid at a given temparature, where the inflow of at least one cleaning fluid is initiated and the at least one cleaning fluid is circulated in the system for a predetermined time; where upon reaching the predetermined time for the cleaning fluid circulation, the temparature and pressure is altered to the operational pressure and temperature at a predetermined rate, where the pressure is constantly kept at a level above the saturation pressure for the fluid at a given temperature; and where upon reaching the operational conditions the inflow of the fluid/cleaning fluid is terminated and the inflow of feed mixture is initiated.

摘要翻译： 本发明涉及一种用于将包含在一种或多种原料中的含碳材料转化成液态烃产物的连续方法，所述原料包括含碳材料在包含一种或多种流体的进料混合物中，所述流体包括水，所述方法包括： 至少部分含碳材料，并且进一步处于清洁压力和温度的状态被设定为预定的期望水平; 在清洁之前，进料混合物的流入终止并且系统充满流体，其中温度和压力以预定速率改变到预定水平，并且压力始终保持在高于 在给定温度下流体的饱和压力，其中至少一种清洁流体的流入开始并且至少一种清洁流体在系统中在预定时间内循环; 在达到清洗流体循环的预定时间时，温度和压力以预定速率改变为操作压力和温度，其中压力恒定保持在高于给定温度下流体饱和压力的水平; 并且在达到操作条件时，流体/清洁流体的流入终止并且开始进料混合物的流入。