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公开(公告)号：EP1456427B1
公开(公告)日：2008-07-02
申请号：EP02779030.2
申请日：2002-11-28
IPC分类号： C22B23/06
CPC分类号： C22B23/0446 , C22B3/001 , C22B5/12 , C22B23/0453 , Y02P10/234
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2.发明公开Method for the recovery of metals from chloride solutions 失效Verfahren zur Gewinnung von Metallen aus chloridischenLösungen。
公开(公告)号：EP0301783A2
公开(公告)日：1989-02-01
申请号：EP88306804.1
申请日：1988-07-25
发明人： Kyuchoukov, Georgi Dimitrov 1336 Sofia , Mihaylov, Indje Ognyanov , Elenkov, Dimiter Georgiev , Boyadjiev, Lyubomir Antonov , Fletcher, Archibald W.
IPC分类号： C22B3/00
CPC分类号： C01G51/003 , C01G3/003 , C01G9/003 , C02F1/26 , C22B3/001 , C22B3/0017 , C22B3/0021 , C22B3/0043 , C22B3/0095 , C23F1/46 , Y02P10/234
摘要： A method for the recovery of metals, generally heavy metals or chelatable metals such as zinc or copper from chloride solutions such as acid chloride etching solutions comprises extracting the metal with a mixed extracting agent of anion exchange/chelating, solvating/cation exchange or anion exchange/cation exchange character, separating the organic phase washing it with water, aqueous ammonia or aqueous ammoniacal ammonium sulphate, stripping the metal from the organic phase thereby obtained by contacting it with sulphuric acid and returning the organic phase to the extraction stage for reuse after regenerating it.
摘要翻译： 从氯化物溶液如酰氯蚀刻溶液中回收金属（通常是重金属或可螯合金属如锌或铜）的方法包括用阴离子交换/螯合，溶剂化/阳离子交换或阴离子交换的混合萃取剂萃取金属 /阳离子交换特性，分离有机相用水，氨水或氨水硫酸铵洗涤，从有机相中汽提金属，由此将其与硫酸接触并将有机相返回萃取阶段再生后再利用 它。
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公开(公告)号：EP0061976A1
公开(公告)日：1982-10-06
申请号：EP82400575.5
申请日：1982-03-30
CPC分类号： C22B34/36 , C01G41/00 , C22B3/001 , Y02P10/234
摘要： Prior to evaporative crystallization of ammonium tungstate solutions to give ammonium paratungstate (APT), an aluminum compound, e.g. aluminum sulfate solution, is added to precipitate silicon and phosphorus impurities.
The yield of crystallized ammonium paratungstate is thereby increased.-
公开(公告)号：EP2712940B1
公开(公告)日：2016-02-17
申请号：EP13761717.1
申请日：2013-02-21
发明人： GOTO, Masahiro , KUBOTA, Fukiko , BABA, Yuzo
CPC分类号： C07C237/06 , C22B3/0005 , C22B3/001 , C22B3/0024 , C22B3/0032 , C22B59/00 , Y02P10/234
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公开(公告)号：EP1456427A1
公开(公告)日：2004-09-15
申请号：EP02779030.2
申请日：2002-11-28
IPC分类号： C22B23/06
CPC分类号： C22B23/0446 , C22B3/001 , C22B5/12 , C22B23/0453 , Y02P10/234
摘要： 1. A process for the recovery of a metallic nickel product in a solvent extraction process including the steps of:(a) forming a nickel ammine complex by stripping nickel from a nickel loaded organic phase with a high strength ammonia solution; and(b) reducing the nickel ammine complex with hydrogen from the high strength ammonia solution to produce a metallic nickel product.
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公开(公告)号：EP0445347A3
公开(公告)日：1992-05-13
申请号：EP90112344.8
申请日：1990-06-28
CPC分类号： C22B3/001 , B01J41/05 , C02F1/26 , C22B3/0032 , Y02P10/234
摘要： An improved extraction system employing a quaternary amine to extract anions from an aqueous solution, particularly precious metals such as gold or silver from an aqueous alkaline solution. The improvement comprises the use of a weak organic acid (a compound providing an acidic proton) along with the quaternary amine. The improvement is useful in both liquid-liquid and liquid-solid extraction systems.
摘要翻译： 一种改进的萃取系统，使用季胺从碱性水溶液中提取阴离子，特别是贵金属如金或银。 该改进包括使用弱有机酸（提供酸性质子的化合物）以及季胺。 该改进在液 - 液和液 - 固萃取系统中是有用的。
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公开(公告)号：EP0301783A3
公开(公告)日：1991-04-10
申请号：EP88306804.1
申请日：1988-07-25
发明人： Kyuchoukov, Georgi Dimitrov 1336 Sofia , Mihaylov, Indje Ognyanov , Elenkov, Dimiter Georgiev , Boyadjiev, Lyubomir Antonov , Fletcher, Archibald W.
IPC分类号： C22B3/00
CPC分类号： C01G51/003 , C01G3/003 , C01G9/003 , C02F1/26 , C22B3/001 , C22B3/0017 , C22B3/0021 , C22B3/0043 , C22B3/0095 , C23F1/46 , Y02P10/234
摘要： A method for the recovery of metals, generally heavy metals or chelatable metals such as zinc or copper from chloride solutions such as acid chloride etching solutions comprises extracting the metal with a mixed extracting agent of anion exchange/chelating, solvating/cation exchange or anion exchange/cation exchange character, separating the organic phase washing it with water, aqueous ammonia or aqueous ammoniacal ammonium sulphate, stripping the metal from the organic phase thereby obtained by contacting it with sulphuric acid and returning the organic phase to the extraction stage for reuse after regenerating it.
摘要翻译： 从氯化物溶液如酰氯蚀刻溶液中回收金属（通常是重金属或可螯合金属如锌或铜）的方法包括用阴离子交换/螯合，溶剂化/阳离子交换或阴离子交换的混合萃取剂萃取金属 /阳离子交换特性，分离有机相用水，氨水或氨水硫酸铵洗涤，从有机相中汽提金属，由此将其与硫酸接触并将有机相返回萃取阶段再生后再利用 它。
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8.发明公开ION EXCHANGE RESIN AND METHOD FOR ADSORBING AND SEPARATING METAL 审中-公开IONENAUSTAUSCHERHARZ UND VERFAHREN ZUR吸附和TRENNUNG VON METALL
公开(公告)号：EP3156128A4
公开(公告)日：2017-06-14
申请号：EP15810881
申请日：2015-06-26
发明人： GOTO MASAHIRO , KUBOTA FUKIKO
IPC分类号： B01J45/00 , B01J20/22 , C22B3/00 , C22B3/06 , C22B3/20 , C22B3/24 , C22B3/28 , C22B3/32 , C22B3/42 , C22B7/00 , C22B59/00
CPC分类号： C22B3/42 , B01J20/22 , B01J45/00 , B01J47/12 , C22B3/001 , C22B3/0024 , C22B3/0098 , C22B3/06 , C22B3/24 , C22B7/007 , C22B23/0415 , C22B59/00 , Y02P10/234
摘要： Provided is a system for efficiently recovering trace metal from a large amount of a raw material, such as when trace metal is recovered from nickel oxide ore. This ion exchange resin has, on a carrier, an amide derivative represented by the following general formula. In the formula, R1 and R2 represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or an arbitrary group, other than an amino group, bonded to ± carbon as an amino acid. The amide derivative is preferably a glycineamide derivative. The carrier preferably includes a primary amine and/or a secondary amine.
摘要翻译： 本发明提供一种从氧化镍矿石中回收微量金属时等从大量的原料中高效回收痕量金属的系统。 该离子交换树脂在载体上具有下述通式所示的酰胺衍生物。 式中，R 1和R 2表示相同或不同的烷基，R 3表示氢原子或烷基，R 4表示氢原子或除氨基以外的与±碳键合的任意基团作为氨基酸 。 酰胺衍生物优选为甘氨酰胺衍生物。 载体优选包含伯胺和/或仲胺。
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9.发明公开
公开(公告)号：EP3156128A1
公开(公告)日：2017-04-19
申请号：EP15810881.1
申请日：2015-06-26
发明人： GOTO, Masahiro , KUBOTA, Fukiko
CPC分类号： C22B3/42 , B01J20/22 , B01J45/00 , B01J47/12 , C22B3/001 , C22B3/0024 , C22B3/0098 , C22B3/06 , C22B3/24 , C22B7/007 , C22B23/0415 , C22B59/00 , Y02P10/234
摘要： Provided is a system for efficiently recovering trace metal from a large amount of a raw material, such as when trace metal is recovered from nickel oxide ore. This ion exchange resin has, on a carrier, an amide derivative represented by the following general formula. In the formula, R1 and R2 represent the same or different alkyl groups, R3 represents a hydrogen atom or an alkyl group, and R4 represents a hydrogen atom or an arbitrary group, other than an amino group, bonded to α carbon as an amino acid. The amide derivative is preferably a glycineamide derivative. The carrier preferably includes a primary amine and/or a secondary amine.
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公开(公告)号：EP2712940A1
公开(公告)日：2014-04-02
申请号：EP13761717.1
申请日：2013-02-21
发明人： GOTO, Masahiro , KUBOTA, Fukiko , BABA, Yuzo
CPC分类号： C07C237/06 , C22B3/0005 , C22B3/001 , C22B3/0024 , C22B3/0032 , C22B59/00 , Y02P10/234
摘要： Provided is a method for selectively extracting and inexpensively recovering scandium from an acidic solution containing calcium, magnesium, and scandium. The scandium extraction method according to the present invention involves subjecting an acidic solution containing calcium, magnesium, and scandium to solvent extraction using an extraction agent consisting of an amide derivative represented by the general formula below. In the formula, R 1 and R 2 represent the same or different alkyl groups, and R 3 is a hydrogen atom or alkyl group. The amide derivative preferably consisting of one or more derivatives selected from glycine amide derivatives, histidine amide derivatives, lysine amide derivatives, and aspartic acid amide derivatives. The pH of the acidic solution is preferably pre-adjusted to between 1 and 4.
摘要翻译： 本发明提供一种从含有钙，镁和钪的酸性溶液中选择性萃取并廉价回收钪的方法。 根据本发明的钪提取方法涉及使用由下列通式表示的酰胺衍生物组成的提取剂对含有钙，镁和钪的酸性溶液进行溶剂提取。 在该式中，R1和R2代表相同或不同的烷基，R3是氢原子或烷基。 酰胺衍生物优选由一种或多种选自甘氨酰胺衍生物，组氨酸酰胺衍生物，赖氨酸酰胺衍生物和天冬氨酸酰胺衍生物的衍生物组成。 酸性溶液的pH值优选预调至1至4。
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