摘要:
Refractories obtained by molding a refractory raw material composition containing a refractory raw material including graphite grains having an average grain size of 500 nm or less or a refractory raw material including graphite grains obtained by graphitizing carbon black and a refractory filler, Or refractories containing carbonaceous grains (A) selected from carbon black or graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of 80 ml/100 g or more, carbonaceous grains (B) selected from carbon black and graphite grains obtained by graphitizing carbon black and having a DBP absorption (x) of less than 80 ml/100 g, and a refractory filler. Refractories excellent in corrosion resistance, oxidation resistance and thermal shock resistance, especially carbon-contained refractories having a low carbon content are thereby provided.
摘要:
Vanadium tetrachloride is stabilized by the addition of minor but stabilizing amounts of an acyl halide, benzoyl chloride being especially preferred. The vanadium tetrachloride may be dissolved in an inert organic solvent; hydrocarbons such as hexane are preferred. The stabilized vanadium tetrachloride may be utilized subsequently in polymerization processes.
摘要:
Vanadium halides or oxyhalides are prepared by reacting vanadium oxyhalides or pentoxide with a halogen in the presence of activated carbon at an elevated temperature in a fluidised bed reactor, and thereafter separating the vanadium halide or oxyhalide from the other reaction products, the reaction being conducted in a fluidised bed reactor equipped with internal filters to prevent carryover of entrained solids with the vanadium halide or oxyhalide.
摘要:
The stability of vanadium tetrachloride is improved by the addition of phosphorus halides such as phosphorus trichloride. Preferably, the vanadium tetrachloride is prepared by the reductive chlorination of vanadium oxychloride in the presence of activated carbon having a sulphur content less than 1% by weight.
摘要:
Solutions of VCl₄ in inert organic solvent are stabilized by incorporation of decomposition retardants being halogenated organic compounds having at least two halogen atoms attached to the same carbon atom and activated by adjacent electron donor groups or carbon-carbon double bonds. One of the especially preferred stabilizers is butyl perchlorocrotonate. The solutions are useful in polymerization processes.
摘要:
Solutions of VCl₄ in inert organic solvent are stabilized by incorporation of decomposition retardants being halogenated organic compounds having at least two halogen atoms attached to the same carbon atom and activated by adjacent electron donor groups or carbon-carbon double bonds. One of the especially preferred stabilizers is butyl perchlorocrotonate. The solutions are useful in polymerization processes.
摘要:
A metal fluoride whose metal is Mo, W, Nb, Ta, V, Re, Ti, Zr, Hf, Co, Ni, Cr, Sb, Sn, Zn, Cd, Pb, Al or a rare earth element is produced by heating a fluorine-containing ammonium salt of the metal, to convert it into the metal fluoride.