Process for preparing vanadium halides
    4.
    发明公开
    Process for preparing vanadium halides 失效
    Verfahren zur Herstellung von Vanadiumhaliden。

    公开(公告)号:EP0103940A1

    公开(公告)日:1984-03-28

    申请号:EP83302704.8

    申请日:1983-05-12

    IPC分类号: C01G31/04 F27B15/12

    CPC分类号: C22B1/10 B01J8/006 C01G31/04

    摘要: Vanadium halides or oxyhalides are prepared by reacting vanadium oxyhalides or pentoxide with a halogen in the presence of activated carbon at an elevated temperature in a fluidised bed reactor, and thereafter separating the vanadium halide or oxyhalide from the other reaction products, the reaction being conducted in a fluidised bed reactor equipped with internal filters to prevent carryover of entrained solids with the vanadium halide or oxyhalide.

    摘要翻译: 卤化钒或卤氧化物通过卤化钒或五氧化物与活性炭的存在下在高温下在流化床反应器中反应制备,然后将卤化钒或卤氧化物与其它反应产物分离,反应在 装有内部过滤器的流化床反应器,以防止与卤化钒或卤氧化物携带夹带的固体。

    Vanadium tetrachloride stabilization
    7.
    发明公开
    Vanadium tetrachloride stabilization 失效
    四氯化钒稳定

    公开(公告)号:EP0291359A3

    公开(公告)日:1990-03-14

    申请号:EP88304426.5

    申请日:1988-05-16

    IPC分类号: C08F4/68 C08F10/00 C01G31/04

    摘要: Solutions of VCl₄ in inert organic solvent are stabilized by incorporation of decomposition retardants being halogenated organic compounds having at least two halogen atoms attached to the same carbon atom and activated by adjacent electron donor groups or carbon-carbon double bonds. One of the especially preferred stabilizers is butyl perchlorocrotonate. The solutions are useful in polymerization processes.

    摘要翻译: VCl 4在惰性有机溶剂中的溶液通过引入分解阻滞剂而稳定化,所述分解阻滞剂是具有至少两个连接到相同碳原子并被相邻电子供体基团或碳 - 碳双键活化的卤素原子的卤化有机化合物。 特别优选的稳定剂之一是全氯丁烯酸丁酯。 该解决方案可用于聚合过程。

    Vanadium tetrachloride stabilization
    8.
    发明公开
    Vanadium tetrachloride stabilization 失效
    稳定四氯化钒。

    公开(公告)号:EP0291359A2

    公开(公告)日:1988-11-17

    申请号:EP88304426.5

    申请日:1988-05-16

    IPC分类号: C08F4/68 C08F10/00 C01G31/04

    摘要: Solutions of VCl₄ in inert organic solvent are stabilized by incorporation of decomposition retardants being halogenated organic compounds having at least two halogen atoms attached to the same carbon atom and activated by adjacent electron donor groups or carbon-carbon double bonds. One of the especially preferred stabilizers is butyl perchlorocrotonate. The solutions are useful in polymerization processes.

    摘要翻译: VCl 4在惰性有机溶剂中的溶液通过加入分解阻滞剂来稳定,其是具有至少两个卤素原子的卤代有机化合物,其连接到相同的碳原子上并被相邻的电子给体基团或碳 - 碳双键活化。 其中一种特别优选的稳定剂是全氯巴豆酸丁酯。 该溶液在聚合过程中是有用的。