摘要:
The present invention relates to a process for the asymmetric oxidation of organic compounds, particularly metal-free, with peroxide compounds in the presence of a chiral Brønsted acid catalyst. In one detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral imidodiphosphate catalyst. In another detail, the present invention relates to a process for enantioselective sulfoxidation of thiocompounds with peroxide compounds in the presence of a chiral phosphoric acid catalyst.
摘要:
A compound of formula the following formula: (I). In this formula, moieties A, B, X, R1, R2, and R3 are defined herein. Also disclosed are a nanocomplex that is formed of such a compound and a pharmaceutical agent, and a nanocomplex that is formed of a protein and a bioreducible compound.
摘要:
A compound of formula the following formula: (I). In this formula, moieties A, B, X, R1, R2, and R3 are defined herein. Also disclosed are a nanocomplex that is formed of such a compound and a pharmaceutical agent, and a nanocomplex that is formed of a protein and a bioreducible compound.
摘要:
The composition of a (phosphonyl) aromatic compound represented by (I) is provided. In this composition, R 1 (a) and R 1 (b) are each independently H, C n H 2n+1 , phenyl or benzyl; R 2 (a) and R 2 (b) are each independently H, C n H 2n+1 , phenyl or benzyl with the proviso that no more than one R 2(a) and no more than one R 2(b) can be phenyl or benzyl; R 3 (a) and R 3 (b) are each independently C n H 2n+1 , phenyl or benzyl; and, n is an integer of 1 - 10; and p is an integer of 1 - 10. The disclosed composition can find utility in improving flame retardancy of polyesters, aramids and nylons.