公开(公告)号：EP0134157A3

公开(公告)日：1985-10-02

申请号：EP84305718

申请日：1984-08-22

申请人： EXXON RESEARCH AND ENGINEERING COMPANY

发明人： Johnson, Jack Wayne ,  Jacobson, Allan Joseph

IPC分类号： C07F09/38 ,  C07F09/09 ,  C07F09/70 ,  B01J31/02 ,  B01J20/22 ,  B01J20/28 ,  C07D307/60

CPC分类号： C07F9/703 ,  B01J23/002 ,  B01J27/198 ,  B01J31/1691 ,  B01J31/185 ,  B01J2523/00 ,  B01J2531/56 ,  C07C31/02 ,  C07C33/20 ,  C07F9/09 ,  C07F9/38 ,  B01J2523/51 ,  B01J2523/55

摘要： A layered oxide containing vanadium together with phosphorus or arsenic and an organic group may be prepared which has a unique layered structure of the formula VORAO 3 ·nS or VOROAO 3 · nS where A is phosphorus or arsenic, S is a solvent molecule, R is an unsubstituted or alkyl-, alkoxy- or aryl-substituted alkyl or aryl group, and n is zero or a positive number. These layered compounds are characterized in that the vanadium is substantially in a 4 oxidation state and is present in an amount such that the molar ratio of A:V ranges from 0.8 to 1.2 throughout the oxide. Also the R groups are covalently bound to an A atom in the vanadium oxide layer directly through either carbon or oxygen atoms.