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    FORMATION OF A ZIEGLER-NATTA CATALYST
    5.
    发明公开
    FORMATION OF A ZIEGLER-NATTA CATALYST 审中-公开
    齐格勒 - 纳塔催化剂的形成

    公开(公告)号：EP3155022A1

    公开(公告)日：2017-04-19

    申请号：EP15806311.5

    申请日：2015-06-12

    申请人： Fina Technology, Inc.

    发明人： ZHANG, Lei ,  RAUSCHER, David

    IPC分类号： C08F4/42 ,  C08F4/50 ,  C08F4/642

    CPC分类号： C08F4/6555 ,  C08F10/00 ,  C08F4/6557

    摘要： The process includes reacting a reaction mixture comprising magnesium ethoxide (Mg(OEt)2), triethylaluminum (TEAl), and 2-ethylhexanol (2-EHOH) to form magnesium 2-ethyl hexyl alkoxide (Mg(2-EHO)2) and contacting Mg(2-EHO)2 in hexane with a first agent to form a reaction product “A.” The process further includes contacting the reaction product “A” with a second agent to form a reaction product “B”, wherein the second agent includes a transition metal and a halogen. The process further includes contacting the reaction product “B” with a third agent to form a reaction product “C”, wherein the third agent includes a first metal halide. In addition, the process includes contacting the reaction product “C” with a fourth agent to form a reaction product “D”, wherein the fourth agent includes a second metal halide. The process also includes contacting the reaction product “D” with a fifth agent to form a Ziegler-Natta catalyst, wherein the fifth agent includes an organoaluminum compound.

    摘要翻译： 该方法包括使包含乙醇镁（Mg（OEt）2），三乙基铝（TEAl）和2-乙基己醇（2-EHOH）的反应混合物反应以形成2-乙基己基醇镁（Mg（2-EHO）2）和 使Mg（2-EHO）2在己烷中与第一试剂接触以形成反应产物“A”。该方法进一步包括使反应产物“A”与第二试剂接触以形成反应产物“B”，其中第二 剂包括过渡金属和卤素。 该方法还包括使反应产物“B”与第三试剂接触以形成反应产物“C”，其中第三试剂包括第一金属卤化物。 此外，该方法包括使反应产物“C”与第四试剂接触以形成反应产物“D”，其中第四试剂包括第二金属卤化物。 该方法还包括使反应产物“D”与第五试剂接触以形成齐格勒 - 纳塔催化剂，其中第五试剂包括有机铝化合物。

    SELF-ASSEMBLED MULTI-NUCLEAR CATALYST FOR OLEFIN POLYMERIZATION
    9.
    发明公开
    SELF-ASSEMBLED MULTI-NUCLEAR CATALYST FOR OLEFIN POLYMERIZATION 审中-公开
    自组织更多的核的烯烃聚合催化剂

    公开(公告)号：EP2550308A1

    公开(公告)日：2013-01-30

    申请号：EP11759812.8

    申请日：2011-03-25

    申请人： Agency for Science, Technology and Research

    发明人： LUO, He Kuan

    IPC分类号： C08F4/42 ,  C08F4/642 ,  C08F10/00

    CPC分类号： C08F10/00 ,  C07F7/006 ,  C08F110/02 ,  C08F210/16 ,  C08F2410/03 ,  C08F2410/04 ,  C08F2500/01 ,  C08F210/14 ,  C08F4/7022 ,  C08F4/7021

    摘要： A self-assembled olefin polymerization catalyst comprising a transition metal complex according to formula (I) A-[(L
    2 (MX
    n )
    p (MX
    n -L
    1 (MX
    n )
    q -MX
    n -B)
    r -MX
    n )
    y -(L
    1 (MX
    n )
    t (MX
    n -L
    2 (MX
    n )
    u -MX
    n -A')
    v MX
    n )w]
    z -B (I) wherein each M is independently a transition metal selected from the group consisting of Group 3-11 of the periodic table; each X is independently selected from the group consisting of H, halogen, CN, optionally substituted N(R
    a )
    2 , OH, optionally substituted C
    1 -C
    20 alkyl, optionally substituted C
    1 -C
    20 alkoxy, wherein R
    a is independently selected from the group consisting of optionally substituted C
    1 -C
    20 alkyl, optionally substituted C
    6 -C
    20 aryl and halogen; A is nothing, L
    1 (MX
    n )
    g MX
    n -, or MX
    n L
    1 (MX
    n )
    g MX
    n ,-; A' is nothing, - L
    1 (MX
    n )
    g MX
    n , or - L
    1 (MX
    n )
    g ,; B is nothing, -L
    2 (MX
    n )h or -L
    2 (MX
    n )
    h MX
    n ; g is 0 or an integer of at least 1; h is 0 or an integer of at least 1; p is 0 or an integer of at least 1; q is 0 or an integer of at least 1; r is 0 or an integer of at least 1; t is 0 or an integer of at least 1; u is 0 or an integer of at least 1; v is 0 or an integer of at least 1; w is an integer of at least 1; y is an integer of at least 1; z is an integer of at least 1; n is an integer selected from 0-6, wherein n is selected depending on the valency of M such that the net charge of each M nucleus is zero or all ligand binding positions of M are occupied; L
    1 and L
    2 are independently selected ligands, wherein L
    1 and L
    2 are different, each of L
    1 and L
    2 having at least two linked coordination units, wherein each coordination unit binds to a different transition metal atom.