摘要:
A magnesium compound obtained by reacting the following components (i), (ii) and (iii): (i) metal magnesium (ii) an alcohol (iii)a metal dihalide compound represented by the general formula (I) containing at least 0.001 mole of M relative to one mole of magnesium of the metal magnesium (i)
MX 2 (I)
where X is a halogen atom and M is Mn, Fe, Co or Zn.
摘要:
The invention relates to a process for preparing indium alkoxides soluble in organic solvents. The preparation method consists in reacting an indium halide with a C3-C20 alcohol in the presence of a base having a pka > 10 and a low nucleophilicity, in anhydrous medium, under inert gas and in the presence of polar organic solvents. The invention allows to obtain with a high yield pure indium alkoxides.
摘要:
An ester interchange process, preferably for the formation of vinyl higher esters from methyl acrylate or methacrylate, is conducted in the presence of a novel alcoholate of the formula wherein M' is selected from Mg, Ca and Ba M 2 is selected from Ti, Zr and A1 n is 3 or 4 and is the valency of M 2 a is a number from 0 to 1.5 b is a number from 0 to 0.75n x+y = 1 and each is a number from 0.005 to 0.995 and is such that the compound is liquid at 30°C R 4 is selected from alkyl having at least 4 carbon atoms, cycloalkyl having at least 4 carbon atoms and aminoalkyl, and each group R 6 is individually selected from C, 3 alkoxy and blocking groups that are substantially less reactive in the ester interchange reaction than the groups OR 4 .
摘要:
Le procédé de l'invention est caractérisé par le fait qu'il consiste à faire réagir le nitrate céri-ammoniacal complexé avec et en solution dans un solvant choisi dans le groupe constitué par les éthers glycoliques et les éthers de dérivés cycliques aliphatiques, avec un alcoolate de métal alcalin, dans des conditions anhydres, à une température comprise entre environ -30°C et environ 200°C, jusqu'à formation de l'alcoolate cérique et du sel nitrate du métal alcalin. Les alcoolates cériques peuvent être utilisés comme comme additifs pour peintures, agents hydrofuges, promoteurs d'adhérence, mordants, agents liants dans les compositions d'émaillage, catalyseurs et comme entermédiaires dans la synthèse d'autres composés organiques.
摘要:
In the augmenting or enhancing of aroma or taste of consumable materials, certain diisoamylene compounds or derivatives are used. Specific novel diisoamylene derivatives are also disclosed, having utility for organoleptic uses.
摘要:
The invention relates to a process for the synthesis of spheroidal magnesium alkoxide having improved mechanical strength and narrow particle size distribution, the process comprising reacting magnesium metal, in the presence of iodine, with a mixture of alcohols by step-wise heating first in the range of 40° C. to 65° C. for a period of 2 hours and then in the range of 65° C. to 80° C. for a period of 1 hour, further by maintaining reaction temperature at 80° C. for a period of 6-10 hours, the vapors of the mixture produced during the reaction being condensed in an overhead condenser, hydrogen gas produced during the reaction being vented off and the mixture of alcohols left after the reaction being filtered and reused. The invention also relates to spheroidal magnesium alkoxide particles synthesized by the method, to the Ziegler natta procatalyst synthesized by using the alkoxide and to the polymer resin synthesized using the procatalyst.