摘要:
It is an object of the present invention to provide fine fibrous cellulose capable of enhancing transparency and suppressing coloring, when the fine fibrous cellulose are processed into a dispersed solution or a sheet. The present invention relates to fine fibrous cellulose, in which the amount of substituents introduced is less than 0.5 mmol/g and the fiber width is 1 to 10 nm. Moreover, the present invention relates to a dispersed solution and a sheet, each of which comprises fine fibrous cellulose. Furthermore, the present invention relates to a method for producing fine fibrous cellulose, comprising: (A) removing at least a part of substituents from fine fibrous cellulose with a fiber width of 1000 nm or less having the substituents, and (B) performing a uniform dispersion treatment on the resulting fine fibrous cellulose after completion of the (A).
摘要:
A composition according to the invention contains a cellulose derivative having a liquid crystalline functional group and a liquid crystalline solvent having a reactive functional group. The reactive functional group preferably contains a carbon-carbon double bond. The reactive functional group is preferably a (meth)acryloyl group.
摘要:
A method of monitoring the evolution of polymer and/or colloid stimuli responsiveness during synthesis of polymers and/or colloids, including postpolymerization modifications on natural and synthetic polymers, includes providing a reactor in which the polymers and/or colloids are synthesized; and providing a means of monitoring the stimuli responsiveness of the polymers and/or colloids during said synthesis. Preferably, the method also includes monitoring the evolution of the characteristics of the polymers and/or colloids during said synthesis. Preferably, evolution of polymer and/or colloid stimuli responsiveness is correlated to the evolution of the properties of the polymers and/or colloids themselves. Also, preferably the conditions of the fluid in the reactor in which the synthesis occurs is determined. The determination can be by detection, choice of materials and temperature conditions, for example, and combinations thereof. The method and instrumentation disclosed can lead to optimization and control of processes and synthetic and modification strategies leading to polymers and colloids with desired stimuli responsiveness.
摘要:
Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by esterifying cellulose in a reaction medium comprising one or more halide ionic liquids and at least one binary component. Cellulose esters prepared via the methods of the present invention can have a degree of substitution ('DS') of at least 1.5 and can comprise a plurality of ester substituents, where at least 50 percent of the ester substituents comprise alkyl esters having a carbon chain length of at least 6 carbons.
摘要:
The present invention refers to the use of screens comprising at least two layers of different mesh or pore size in a cellulose powder preparation method as well as to said method, wherein grinding the cellulose pulp and sieving the obtained particles can be carried out on-line.
摘要:
A fatty acid ester of cellulose excellent in transparency, filterability and spinnability in spite of its high content of mannose and xylose, wherein the total molar content of mannose and xylose accounts for at least 7% of that of glucose, mannose and xylose, and the amount of filtration satisfies a specified requirement. Such a fatty acid ester of cellulose is prepared by using a pulp having a low α-cellulose content as a raw material and a fatty acid corresponding to the ester as a diluent and adding an organic solvent in an amount of at least 10% by weight based on the diluent in any step during the preparation. In the preparation of cellulose diacetate, which is excellent in filterability and transparency, by the acetic acid process, the cellulose diacetate obtained by aging is dissolved in a solvent which can dissolve it and the resulting cellulose diacetate is recovered.