METHODS AND INSTRUMENTATION FOR DURING-SYNTHESIS MONITORING OF POLYMER FUNCTIONAL EVOLUTION
    5.
    发明公开
    METHODS AND INSTRUMENTATION FOR DURING-SYNTHESIS MONITORING OF POLYMER FUNCTIONAL EVOLUTION 审中-公开
    方法和装置聚合物功能开发过程中综合监控

    公开(公告)号:EP2294406A2

    公开(公告)日:2011-03-16

    申请号:EP09759486.5

    申请日:2009-06-05

    发明人: REED, Wayne, F.

    摘要: A method of monitoring the evolution of polymer and/or colloid stimuli responsiveness during synthesis of polymers and/or colloids, including postpolymerization modifications on natural and synthetic polymers, includes providing a reactor in which the polymers and/or colloids are synthesized; and providing a means of monitoring the stimuli responsiveness of the polymers and/or colloids during said synthesis. Preferably, the method also includes monitoring the evolution of the characteristics of the polymers and/or colloids during said synthesis. Preferably, evolution of polymer and/or colloid stimuli responsiveness is correlated to the evolution of the properties of the polymers and/or colloids themselves. Also, preferably the conditions of the fluid in the reactor in which the synthesis occurs is determined. The determination can be by detection, choice of materials and temperature conditions, for example, and combinations thereof. The method and instrumentation disclosed can lead to optimization and control of processes and synthetic and modification strategies leading to polymers and colloids with desired stimuli responsiveness.

    CELLULOSE ESTERS AND THEIR PRODUCTION IN HALOGENATED IONIC LIQUIDS
    6.
    发明公开
    CELLULOSE ESTERS AND THEIR PRODUCTION IN HALOGENATED IONIC LIQUIDS 审中-公开
    红细胞中的细胞因子在HALOGENIERTEN IONISCHENFLÜSSIGKEITEN

    公开(公告)号:EP2247622A1

    公开(公告)日:2010-11-10

    申请号:EP08795232.1

    申请日:2008-08-12

    IPC分类号: C08B3/00 C08B1/00

    摘要: Ionic liquids and cellulose ester compositions and processes for producing ionic liquids and cellulose esters. Cellulose esters can be produced by esterifying cellulose in a reaction medium comprising one or more halide ionic liquids and at least one binary component. Cellulose esters prepared via the methods of the present invention can have a degree of substitution ('DS') of at least 1.5 and can comprise a plurality of ester substituents, where at least 50 percent of the ester substituents comprise alkyl esters having a carbon chain length of at least 6 carbons.

    摘要翻译: 离子液体和纤维素酯组合物和用于生产离子液体和纤维素酯的方法。 纤维素酯可以通过在包含一种或多种卤离子液体和至少一种二元组分的反应介质中酯化纤维素来生产。 通过本发明的方法制备的纤维素酯可以具有至少1.5的取代度(“DS”),并且可以包含多个酯取代基,其中至少50%的酯取代基包括具有碳链的烷基酯 长度至少为6个碳。

    Fatty acid ester of cellulose, cellulose diacetate and processes for the preparation thereof
    8.
    发明公开
    Fatty acid ester of cellulose, cellulose diacetate and processes for the preparation thereof 失效
    纤维素脂肪酸酯,纤维素二糖及其制备方法

    公开(公告)号:EP0590401A3

    公开(公告)日:1994-07-27

    申请号:EP93114692.2

    申请日:1993-09-13

    IPC分类号: C08B3/00 C08B3/06 C08B3/22

    CPC分类号: C08B3/06

    摘要: A fatty acid ester of cellulose excellent in transparency, filterability and spinnability in spite of its high content of mannose and xylose, wherein the total molar content of mannose and xylose accounts for at least 7% of that of glucose, mannose and xylose, and the amount of filtration satisfies a specified requirement. Such a fatty acid ester of cellulose is prepared by using a pulp having a low α-cellulose content as a raw material and a fatty acid corresponding to the ester as a diluent and adding an organic solvent in an amount of at least 10% by weight based on the diluent in any step during the preparation. In the preparation of cellulose diacetate, which is excellent in filterability and transparency, by the acetic acid process, the cellulose diacetate obtained by aging is dissolved in a solvent which can dissolve it and the resulting cellulose diacetate is recovered.

    摘要翻译: 尽管甘露糖和木糖含量高,透明度,过滤性和可纺性优异的纤维素脂肪酸酯,其中甘露糖和木糖的总摩尔含量占葡萄糖,甘露糖和木糖的总摩尔含量至少为7% 过滤量满足规定要求。 这种纤维素的脂肪酸酯是通过使用具有低α-纤维素含量的纸浆作为原料和对应于酯作为稀释剂的脂肪酸并加入至少10重量%的有机溶剂来制备的 基于制备过程中任何步骤中的稀释剂。 在过滤性和透明性优异的纤维素二乙酸酯的制备中,通过乙酸法,将通过老化得到的纤维素二乙酸酯溶解在可溶解的溶剂中,并回收得到的纤维素二乙酸酯。