摘要:
Provided is a method for producing a petroleum resin using a tube-type reactor, the method producing a petroleum resin that exhibits good properties as an adhesive component for a hot-melt adhesive which has a narrow molecular weight distribution and a high softening point, and which exhibits good adhesive capability and also has little insoluble matter. A method of producing a petroleum resin by using a raw material containing at least a cyclopentadiene-based component (A) and a styrene-indene-based aromatic component (B) so as to carry out a thermal polymerization reaction of the raw material, the method comprising: a first polymerization reaction step of thermally polymerizing the raw material using a loop reactor; and a second polymerization reaction step of thermally polymerizing a polymerization reaction product obtained in the first polymerization reaction step using a plug flow reactor.
摘要:
The present invention relates to a preparation method of a highly aromatic hydrocarbon hydrogenated resin, comprising the processes of fraction cutting, pretreatment, catalytic polymerization, two-stage hydrogenation, etc. The highly aromatic hydrocarbon hydrogenated resin obtained by the present invention has excellent compatibility with elastomers such as SBS, SIS and the like, and is suitable for hot melt adhesives, coatings, rubber modification, etc.
摘要:
Provided is a new method that effectively reduces odor components that are present in a hydrogenated petroleum resin, and adjusts a softening point to an appropriate range for exhibiting an adhesive performance. A method for deodorizing a hydrogenated petroleum resin, includes stripping a hydrogenated petroleum resin at a gas flow rate of 1 to 45 WM.
摘要:
Provided is a method for producing a hydrogenated petroleum resin having good compatibility with a base polymer and a good hue under a hydrogen pressure of 4 MPaG or less. A method for producing a hydrogenated petroleum resin, includes a hydrogenation step of hydrogenating a polymerization product of dicyclopentadiene and a vinyl aromatic compound in the presence of a catalyst, in which the hydrogenation step is performed under conditions (A) to (C) below: (A) an amount of the catalyst used: 0.125 to 0.4 parts by mass relative to 100 parts by mass of a resin in the polymerization product; (B) a reaction pressure: 4 MPaG or less; and (C) a reaction temperature: 240°C or higher.
摘要:
The present invention relates to a curable petroleum resin, a preparation method therefor, and use thereof, wherein the curable petroleum resin comprises a repeating unit derived from a petroleum resin monomer, a repeating unit derived from a silane monomer and a repeating unit derived from a cyclic anhydride monomer, and wherein the curable petroleum resin is used as an additive for a reactive polyolefin-based adhesive composition to increase the adhesive strength to a polyolefin-based substrate used for various parts.
摘要:
This invention provides a method of manufacturing a curable petroleum resin and a curable petroleum resin obtained therefrom. The method includes (a) a process of thermally polymerizing a composition for polymerization which includes silanes and monomers, including cyclic olefins having at least one ethylenically unsaturated group selected from among C5 fractions, C9 fractions, and dicyclopentadiene of naphtha cracking, thereby enabling petroleum resins, which are thermoplastic resins, to be applied as reactive adhesives, and ultimately being capable of providing eco-friendly reactive adhesives.
摘要:
Petroleum resins are produced using a supported BF3 cocatalyst complex. Preferably the cocatalyst is organic such as an alcohol or a carboxylic acid. Use of the catalyst in supported form together with the cocatalyst enables control over both Bronsted and Lewis acidity leading to better control of resin properties. Waste disposal and catalyst handling problems are also overcome.