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    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME
    4.
    发明公开
    TRANSITION METAL/CARBENE COMPLEX AND PROCESS FOR PRODUCING SAME 有权
    ÜBERGANGSMETALL-/ CARBENKOMPLEX UND VERFAHREN ZUR HERSTELLUNG DAVON

    公开(公告)号：EP3023430A1

    公开(公告)日：2016-05-25

    申请号：EP14827072.1

    申请日：2014-07-17

    申请人： Zeon Corporation

    发明人： HAYANO, Shigetaka

    IPC分类号： C07F11/00 ,  C07F19/00 ,  C08F4/78

    CPC分类号： C07F11/00 ,  C08F4/78

    摘要： Provided are a transition metal carbene complex represented by the following general formula (1) and a method of producing the same. (In general formula (1), M represents for example a molybdenum atom, R 1 represents for example a C 1 -C 20 alkyl group optionally having a substituent, L to L 3 each represent a ligand selected for example from a halogen group, R 2 and R 3 each represent for example a hydrogen atom or a C 1 -C 20 alkyl group optionally having a substituent, A represents for example a nitrogen atom, and R 4 to R 7 each represent for example a C 1 -C 20 alkyl group optionally having a substituent.)

    摘要翻译： 提供由以下通式（1）表示的过渡金属卡宾络合物及其制备方法。 （通式（1）中，M表示例如钼原子，R 1表示例如任选具有取代基的C 1 -C 20烷基，L〜L 3表示选自例如卤素基团的配体， R 2和R 3各自表示例如氢原子或任选具有取代基的C 1 -C 20烷基，A表示例如氮原子，R 4至R 7各自表示例如C 1 -C 20 任选具有取代基的烷基）

    POLYETHYLENE HAVING IMPROVED BRANCHING DEGREE DISTRIBUTION
    6.
    发明公开
    POLYETHYLENE HAVING IMPROVED BRANCHING DEGREE DISTRIBUTION 有权
    聚乙烯麻醉剂VERBESSERTER VERZWEIGUNGSGRADVERTEILUNG

    公开(公告)号：EP2657260A1

    公开(公告)日：2013-10-30

    申请号：EP11851416.5

    申请日：2011-12-22

    申请人： Japan Polyethylene Corporation

    发明人： KUZUBA, Yuuichi ,  MONOI, Takashi ,  KANAZAWA, Satoshi ,  OGAWA, Kouichi ,  HATTORI, Takaaki ,  YOSHIMOTO, Keiichi

    IPC分类号： C08F4/78 ,  C08F4/69 ,  C08F10/00

    CPC分类号： C08F210/16 ,  Y10T428/1397 ,  C08F4/69 ,  C08F210/14 ,  C08F2500/04 ,  C08F2500/12

    摘要： An object of the present invention is to provide polyethylene having excellent moldability and impact resistance and excellent balance between rigidity and durability, produced using a novel organoaluminum compound-supported chromium catalyst, a method for producing polyethylene, and a hollow plastic molding containing the polyethylene. The polyethylene of the invention is polymerized using a chromium catalyst, and has a weight average molecular weight (Mw) of 30,000 or more at the maximum value in a branching degree distribution curve that shows a molecular weight dependency of short chain branches having 4 or more carbon atoms.

    摘要翻译： 本发明的目的是提供使用新颖的有机铝化合物负载的铬催化剂制备的具有优异的模塑性和耐冲击性以及刚性和耐久性之间的优异平衡的聚乙烯，聚乙烯的制造方法和含有该聚乙烯的中空塑料模制品。 使用铬催化剂聚合本发明的聚乙烯，并且在显示具有4个或更多个的短链分支的分子量依赖性的支化度分布曲线中，其最大值的重均分子量（Mw）为30,000或更大 碳原子。

    Chromium-containing complex polymerisation catalyst
    10.
    发明公开
    Chromium-containing complex polymerisation catalyst 失效
    Chromkomplexe enthaltende Polymerisationskatalysatoren。

    公开(公告)号：EP0416786A2

    公开(公告)日：1991-03-13

    申请号：EP90309282.3

    申请日：1990-08-23

    申请人： BP Chemicals Limited

    发明人： Dawkins, Gordon Michael

    IPC分类号： C08F10/00 ,  C08F4/78

    CPC分类号： C08F10/00 ,  C08F4/78

    摘要： The present invention relates to an olefin polymerisation catalyst obtainable by depositing on a dry inorganic oxide support a mononuclear chromium complex which is a mixture of (A) a first mononuclear chromium complex represented by the general formula:
    wherein
    - three of R₁ to R₅ are H and the other two are H, or C₁-3 hydrocarbyl group, and
    - L is one or more hydrocarbyl ligands which are sufficiently reactive to enable the complex to react with the inorganic oxide without thermal activation, and
    (B) a second mononuclear chromium complex representable by the general formula:
    wherein
    - the cyclopentadienyl ligand is substituted with 4 or 5 hydrocarbyl groups (R1-R5) containing 1 to 3 carbon atoms, and
    - L has the same definition as above, being identical or different.
    The catalyst can be used for polymerising olefins, particularly ethylene optionally with C₃-8 alpha-olefins. It can be thermally activated before use in olefin polymerisation. It produces polyolefins having a relatively broad molecular weight distribution, the breadth and shape of which being easily controlled.

    摘要翻译： 本发明涉及通过在干燥的无机氧化物载体上沉积作为（A）由以下通式表示的第一单核铬络合物的混合物的单核铬络合物获得的烯烃聚合催化剂：其中 - R5是H，另外两个是H或C 1-3烃基，而-L是一个或多个烃基配位体，它们具有足够的反应活性，使复合物能够与无机氧化物反应而不需要热激活，和（B）第二个 由以下通式表示的单核铬络合物：其中 - 环戊二烯基配体被4或5个含有1至3个碳原子的烃基（R 1 -R 5）取代，并且-L具有与上述相同的定义，相同或相同 不同。 该催化剂可用于使烯烃，特别是任选与C 3-8α-烯烃的乙烯聚合。 在烯烃聚合中使用之前，它可以被热活化。 它产生具有相对宽的分子量分布的聚烯烃，其宽度和形状容易控制。