摘要:
The invention relates to a process that results in a vinylidene fluoride polymer composition with a reduced level of residual impurities, notably total oxidizable carbon (TOC) and fluoride ions. Such improvements can be accomplished in a cost-effective manner through the combination of a polymer recipe that uses a low amount of or no surfactants and the isolation of the polymer, especially in a dewatering extruder. The invention also relates to the use of such a vinylidene fluoride polymer for conveying ultrapure water in high purity applications.
摘要:
The present invention provides a method for producing a purified fluoropolymer aqueous dispersion, comprising: (A) bringing a fluoropolymer aqueous dispersion obtained using a hydrocarbon surfactant into contact with an anion exchange resin A or a synthetic adsorbent, wherein the anion exchange resin A has: an ion-exchange group represented by the following general formula (A1):
-N + R 1 R 2 R 3 X -
wherein R 1 , R 2 , and R 3 are the same as or different from each other, and are each a hydrogen atom or an organic group, and at least one of R 1 , R 2 , and R 3 is an organic group having 3 or more carbon atoms; and X is a counter ion; or an ion-exchange group represented by the following general formula (A2):
-NR 4 R 5
wherein R 4 and R 5 are the same as or different from each other, and are each a hydrogen atom or an organic group, and at least one of R 4 and R 5 is an organic group having 2 or more carbon atoms.
摘要:
Provided are methods for removing a perfluorinated alkanoic acid from solutions containing the perfluorinated alkanoic acid and a fluorinated alkoxy acid. These methods include contacting the first solution with an anion-exchange resin to produce a second solution and a resultant anion-exchange resin having perfluorinated alkanoic acid adsorbed thereto, wherein the perfluorinated alkanoic acid is present in the first solution at a first concentration and is present in the second solution at a second concentration which is lower than the first concentration, and separating the second solution from the resultant anion-exchange resin.
摘要:
The present application relates to a method for removing an unreacted vinyl chloride monomer (VCM) in polyvinyl chloride (PVC). According to an illustrative stripping apparatus and a stripping method using the stripping apparatus of the present application, in a stripping process using steam, a temperature difference between a raw material including a target substance to be removed and steam is minimized to suppress foam generation in the stripping process, thereby increasing efficiency of removing the target substance to be removed, particularly, an unreacted VCM in PVC. In addition, a cleansing cycle to remove foams generated in the stripping apparatus can be reduced, thereby not only securing economic feasibility of the process, but also preventing degradation in quality of a final product that may occur when an antifoamer to remove the foams is used.
摘要:
Provided is a method of purifying polyolefin, the method including the step of contacting linear low-density polyethylene synthesized by a gas phase polymerization reaction with a purge gas containing an ethylene gas and an inert gas in a purge bin. According to this purification method, residual alkene monomers with high carbon numbers may be removed in a simpler and more efficient manner.
摘要:
An object of the present invention is to provide methods for preparing a fluoropolymer aqueous dispersion that allow efficient removal of iron ions from fluoropolymer aqueous dispersions, and purified fluoropolymer aqueous dispersions. The present invention relates to a method for preparing a fluoropolymer aqueous dispersion, including: step (A) of preparing a fluoropolymer aqueous dispersion comprising a fluoropolymer having at least one selected from the group consisting of - SO 2 Y and -COOR (wherein Y is a halogen, and R is a C1 to C4 alkyl) by emulsion polymerization; step (B) of heating the fluoropolymer aqueous dispersion to 50°C or higher; and step (C) of contacting the fluoropolymer aqueous dispersion with an ion exchange resin for cation exchange after step (B), thereby providing a purified fluoropolymer aqueous dispersion, the fluoropolymer aqueous dispersion being adjusted to pH 7 or lower from the end of the polymerization in step (A) to the end of step (C).