摘要:
The present invention pertains to the use of at least one Brønsted superacid or metal salt of said Brønsted superacid with a DeltaGacid value of 316 kcal/mol or less, as a heat and/or colour stabiliser for polyvinyl halide resin compositions. The superacid is not a perchlorate or a trifluoromethane sulphonate. The metal in the metal salt of the Brønsted superacid is preferably selected from the group consisting of alkali metals, alkali earth metals, transition metals, lanthanide metals, actinide metals, Al, Ga, In, TI, Ge, Sn, Pb, and Sb.
摘要:
Flexible, semi-rigid, and rigid vinyl chloride polymer compositions comprising a latent mercaptan-containing heat stabilizer are substantially free from the offensive odour typically associated with mercaptans and are protected during processing by the degradation products of the latent (i.e., blocked) mercaptan which include a free mercaptan. The free mercaptan thus released enhances the activity of metallic-based heat stabilizers such as zinc carboxylates and organotin carboxylates and mercaptides in the polymer composition. Other products of the degradation are believed to include carbocations of the blocking moiety which are stabilized by a molecular structure in which the electron deficiency is shared by several groups. The latent mercaptan is selected from a 2-S-(tetrahydropyranyl)-thioalkanol, a carboxylic acid ester thereof, a 2-S-(tetrahydropyranyl)-thioglycolic acid, and an ester thereof.
摘要:
The present invention pertains to the use of at least one Brønsted superacid or metal salt of said Brønsted superacid with a ΔGacid value of 316 kcal/mol or less, as a heat and/or colour stabiliser for polyvinyl halide resin compositions. The superacid is not a perchlorate or a trifluoromethane sulphonate. The metal in the metal salt of the Brønsted superacid is preferably selected from the group consisting of alkali metals, alkali earth metals, transition metals, lanthanide metals, actinide metals, Al, Ga, In, TI, Ge, Sn, Pb, and Sb.
A) 50-99.9% by weight of at least a copolymer (1) of ethylene (E) with chlorotrifluoroethylene (CTFE) wherein CTFE is comprised between 53 and 70% by moles, having a crystallinity in the range 5-45%; B) 0.1-50% by weight of a fine powder of a nucleating agent, having an average particle size lower than 50 micron and a melting temperature higher than 300°C.
摘要:
The invention relates to a process for preparing a stabilized suspen-sion/emulsion polymer of halogen-containing monomers with addition of a polymer stabilizer mixture compatible with the polymerization medium prior to, during or directly after the polymerization process, and to the polymers pre-pared by this process.
摘要:
This invention relates to a vinyl halide film comprising (A) at least one vinyl halide polymer, (B) at least one non-halogenated polymeric plasticizer and (C) at least one second plasticizer, wherein a major amount of the polymers of the film comprise the vinyl halide polymer (A) and wherein the film has an elongation of at least about 50%. The invention also relates to an adhesive article comprising a pressure sensitive adhesive layer having a first and second surface, and a vinyl halide film adhered to the first surface of the adhesive layer, wherein the vinyl halide film comprises (A) at least one vinyl halide polymer, (B) at least one non-halogenated polymeric plasticizer and (C) at least one second plasticizer, wherein the adhesive article has an elongation of at least about 50%. The invention also includes a plastisol, useful for preparing vinyl halide films, comprising (A) at least one vinyl halide polymer, (B) at least one non-halogenated polymeric plasticizer, (C) at least one second plasticizer, and (D) at least one solvent. The film and subsequent articles derived therefrom have improved conformability. Additionally, the film is a castable film. The films and articles are useful in exterior graphics applications, including graphics for vehicles, especially vehicles with corrugated side panels.
摘要:
Eine Polyolefinformmasse, welche eine hervorragende chemische Stabilität bei Dauerkontakt mit extrahierenden Medien besitzt, enthält als Stabilisatoren ein symmetrisches Triarylphosphit und einen Ester der 3,3-Bis-(3′-t-butyl-4′-hydroxyphenyl)-butansäure.