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公开(公告)号:JP2002226838A
公开(公告)日:2002-08-14
申请号:JP2001025910
申请日:2001-02-01
Applicant: ASAHI GLASS CO LTD
Inventor: YONEDA TAKASHIGE , FURUKAWA YUTAKA , TORIMOTO TOMOKO
IPC: B60S1/02 , C03C17/30 , C09D4/00 , C09D5/00 , C09D183/08 , C09D183/12 , C09K3/18
Abstract: PROBLEM TO BE SOLVED: To obtain a water-repellent composition capable of forming a surface- treated layer having excellent waterdrop removing properties and durability thereof (abrasion, chemical and weather resistances), a surface-treated substrate having the surface-treated layer formed of the water-repellent composition and to provide a method for producing the same and an article for transportation equipment. SOLUTION: This water-repellent composition comprises a compound 1 [Rf- Si(R)p(X)3-p], a compound 4 [RF-Si(R1)q(X)3-q] and/or a compound 5 [SiX24] (Rf is a fluorine-containing organic group having etheral oxygen atom; RF is a fluorine-containing organic group without having the etheral oxygen atom; R and R1 are each a 1-6C fluorine atom-free hydrocarbon group; p and q are each 0, 1 or 2; and X, X1 and X2 are each a halogen atom or a hydrolyzable group).
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公开(公告)号:JP2001135340A
公开(公告)日:2001-05-18
申请号:JP30996799
申请日:1999-10-29
Applicant: ASAHI GLASS CO LTD
Inventor: ENDO EIJI , YOSHITAKE MASARU , YONEDA TAKASHIGE , KUNIHAZA YASUHIRO
Abstract: PROBLEM TO BE SOLVED: To provide a solid high molecular fuel cell which can decrease deterioration in output properties over aging by imparting durable water repellency to an electrode. SOLUTION: An electrode containing a reaction product obtained by a reaction of a silane compound in which a isocyanate radical or a hydrolytic radical and fluorine containing organic radical are attached to the silicon atom in the presence of water and also containing catalyst powders and an ion exchange resin is used. Especially an electrode in which the catalyst powders are surface- treaded with the silane compound is used.
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公开(公告)号:JP2001081445A
公开(公告)日:2001-03-27
申请号:JP25627399
申请日:1999-09-09
Applicant: ASAHI GLASS CO LTD
Inventor: FURUKAWA YUTAKA , YONEDA TAKASHIGE , TORIMOTO TOMOKO , KODERA MASAMI
Abstract: PROBLEM TO BE SOLVED: To obtain a surface treatment composition excellent in water repellency, stainproofness and capability for rolling down water droplets by incorporating, into the same, (A) a silicone compound, (B) a silicon compound, and/or (C) a partial cohydrolyzate of a fluorine-containing silicone compound and a silicon compound. SOLUTION: This composition contains (A) a silicone compound, (B) a silicon compound, and/or (C) a partial cohydrolyzate of a fluorine-containing silicone compound and a silicon compound represented by formula III. Ingredient A is a compound selected from among fluorine-containing silicone compounds each consisting essentially of organosiloxane units each containing a monovalent fluorine-containing organic group represented by formula I and organosiloxane units each having a monovalent silicon- containing organic group represented by formula II and their partial hydrolyzates. Ingredient B is a compound selected from among silicon compounds represented by formula III and their partial hydrolyzates. In the formulas, Rf is a monovalent polyfluorohydrocarbon group or the like; X is a divalent hydrocarbon group or the like; R1 and R20 are each a monovalent organic group; Y1 and Y2 are each a monovalent hydrolyzable group or the like; a>=1; b is 1-3; and j is 1-4.
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公开(公告)号:JPH1179789A
公开(公告)日:1999-03-23
申请号:JP20935997
申请日:1997-08-04
Applicant: ASAHI GLASS CO LTD
Inventor: SUZUKI YOSHITADA , YONEDA TAKASHIGE
Abstract: PROBLEM TO BE SOLVED: To stably obtain a high quality water-repellent thin film in a large amt. by applying an excessive amt. of a coating liquid for the formation of a water-repellent thin film on the surface of a substrate such as glass and removing the excess coating material. SOLUTION: The base body consists of glass, metal, ceramic material, resin, etc., and especially, glass is preferable because the a glass base body has hydroxyl groups on the surface and firmly bonds with a water-repellent liquid to form a transparent thin film. The water-repellent liquid contains a perfluoro group- contg. compd., preferably a perfluoro group-contg. silane compd. and its hydrolyzed condensed material. As for the coating means of the water-repellent liquid, squeegee coating method is preferably used. After the water-repellent liquid is dropped on the surface of the base body, an elastic, preferably a sponge squeegee is used to spread the liquid. After coating, the liquid is dried for 1 to 25 hours to bond to the substrate. The excess coating material is removed by wiping till color irregularity or haze disappears. Especially, it is preferable to spray a starch-contg. powder which can adsorp the excess coating material and then to remove by using a brush or the like.
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公开(公告)号:JPH1036975A
公开(公告)日:1998-02-10
申请号:JP19235696
申请日:1996-07-22
Applicant: ASAHI GLASS CO LTD
Inventor: ABE KEISUKE , ISHIZEKI KENJI , SANADA YASUHIRO , YONEDA TAKASHIGE , MORIMOTO TAKESHI
Abstract: PROBLEM TO BE SOLVED: To form a high performance low resistance film which is not colored, is transparent and is excellent in conductivity by a low temp. heat treatment by allowing a coating liquid to contain Ag particulates having a specified particle size and Ag salt. SOLUTION: The Ag particulates having a mean particle size above 10nm and Ag salt are at least contained in the coating liquid for the low resistance film formation. Silver nitrate, silver acetate, silver sulfate, silver cyanide, etc., are usable as the Ag salt. A coating liquid for the low refractive index film formation is formed by incorporating a silicon compound into this coating film, if necessary. Absorption in the region of approx. 400 to 500nm of the film caused by the optical plasma resonance absorption of Ag particulates themselves is suppressed by using the Ag salt for the coating liquid. Further, the Ag salt is diffused as Ag ions to promote the particle growth of Ag particulates which form the film in the heating or ultraviolet rays irradiation at the time of the formed film hardening process. The concentration of the Ag particulates in the coating liquid is preferably 0.01 to 5wt.% or thereabouts.
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公开(公告)号:JPH08151564A
公开(公告)日:1996-06-11
申请号:JP29652394
申请日:1994-11-30
Applicant: ASAHI GLASS CO LTD
Inventor: YONEDA TAKASHIGE , GUNJI FUMIAKI , MORIMOTO TAKESHI
IPC: B65D25/14 , B65D25/34 , C03C17/30 , C07F7/10 , C07F7/12 , C09D5/00 , C09D183/00 , C09D183/04 , C09K3/00
Abstract: PURPOSE: To provide a surface-treating agent for vessels which contains an isocyanate silane, permits easy and simple treatment at room temperature, thus is useful for vessels to be filled with a variety of commercial products such as beverage, food products, cosmetics and the like, because it gives vessels having good appearance, antifouling properties and antiscuffing resistance. CONSTITUTION: This treating agent contains an isocyanate silane having at least one of isocyanate-binding Si atom, preferably a polyfluoroorganic group (for example, a group having a 3-21C perfluoroalkyl-) or a long-chain alkyl (for example, a group having 3-30C alkyl moiety). This treating agent may contain the above-stated isocyanate group as well as a polyorgnosiloxane including methyl-organosiloxane units. The isocyanate silane compound is, for example, a compound of the formula (R -R are independently to each other, H, a 1-21C monovalent organic group; Y is a divalent organic group; a, b are independently 0, 1, 2 where 0
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公开(公告)号:JPH07126606A
公开(公告)日:1995-05-16
申请号:JP27463293
申请日:1993-11-02
Applicant: ASAHI GLASS CO LTD
Inventor: YONEDA TAKASHIGE , GUNJI FUMIAKI , TAKANO YUKIKO , MORIMOTO TAKESHI
IPC: G02F1/1335 , C03C17/30 , C07F7/10 , C09K3/00 , G09F9/00
Abstract: PURPOSE:To obtain a display indication material having excellent stain-resistant durability, wear resistance, chemical resistance and weather resistance, useful as a terepanel, having a coating film formed from a composition comprising an isocyanatosilane compound as an essential component on the surface. CONSTITUTION:This display indication material has a coating film formed from a composition comprising an isocyanatosilane compound of formula I and/or formula II (R to R are H or a 1-30C organic group; (a) to (d) are 0-2; (a)+(b) and (c)+(d) are 0-2; Y is a bifunctional organic group; (e), (g) and (h) are 0-2; (e)+(g)+(h) is 0-2) as an essential component on the surface.
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公开(公告)号:JPH06148414A
公开(公告)日:1994-05-27
申请号:JP31622592
申请日:1992-10-30
Applicant: ASAHI GLASS CO LTD
Inventor: KANEKO ATSUKO , YONEDA TAKASHIGE
IPC: G02B5/20
Abstract: PURPOSE:To obtain a color filter provided with a protecting film having extremely high flattening ability. CONSTITUTION:As to the production of an electrode substrate provided with the color filter having a substrate 1, a coloring layer formed on the substrate 1, a protecting layer 3 formed on the coloring layer and photoset by performing photoirradiation on a photosensitive composition layer, and an electrode layer provided on the protecting layer 3; heating is simultaneously performed on the photosensitive composition layer in the case of performing the photoirradiation on the photosensitive composition layer.
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公开(公告)号:JPH01275130A
公开(公告)日:1989-11-02
申请号:JP10425888
申请日:1988-04-28
Applicant: ASAHI GLASS CO LTD
Inventor: YONEDA TAKASHIGE , WAKABAYASHI TSUNEO
Abstract: PURPOSE:To suitably hold the balance of reflection preventing capacity and light ray transparency by forming a coating film of low reflection coating film composition made of specific compound or its hydrolyzed material on a transparent plastic base material having an uneven scattering surface. CONSTITUTION:A coating film of low reflection coating film composition made of a compound or its hydrolyzed material represented by formulae A and B is formed on a transparent plastic base material having an uneven scattering surface. The base material includes acrylic resin, polystyrene resin, etc., the roughness of the uneven scattering surface preferably has wavelength of 1/50-5times as long as that of a visible light ray, and a sandblasting, an etching with chemicals, etc., is employed. A forming method for the film includes a dipping coating, a rotary coating, a spray coating, etc., and it is heated, after coating, to form a cured coating film.
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公开(公告)号:JPS6445481A
公开(公告)日:1989-02-17
申请号:JP20186587
申请日:1987-08-14
Applicant: ASAHI GLASS CO LTD
Inventor: YONEDA TAKASHIGE , WAKABAYASHI TSUNEO
IPC: C09D183/04
Abstract: PURPOSE:To provide the titled composition outstanding in surface hardness, impact, chemical and scratch resistances, adhesivity, flexibility, dyeability and durability, applicable on various kinds of substrates, containing an imide group- contg. specific polyfunctional silicone compound (or cocondensate therefrom). CONSTITUTION:The objective composition containing either an imide group- contg. polyfunctional silicone compound of formula [R and R are each 1-6C alkyl; Q is (substituted)monovalent hydrocarbon; A is aromatic group; a and b are each 1-3] or a cocondensate therefrom. This composition is pref. further incorporated with a conventional alkoxysilane, chlorosilane etc.
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