摘要:
PROBLEM TO BE SOLVED: To provide a crack preventing agent for cardboard which is capable of improving crack resistance of cardboard represented by a ruled-line crack of liner base paper and a column crack of core base paper and imparting water resistance as well without a large reduction in strength.SOLUTION: The crack preventing agent for cardboard contains a dehydrated condensate obtained by dehydration and condensation of a trivalent or tetravalent carboxylic acid (a1) and at least one compound (a2) selected from the group consisting of 6-22C monovalent aliphatic alcohol (a2-1), and an aliphatic amine (a2-2) having a 6-22C alkyl group and/or an alkenyl group, and/or a salt thereof (A).
摘要:
PROBLEM TO BE SOLVED: To provide rosin-modified cellulose and rosin-modified cellulose microfibrils having excellent hydrophobic effects and high crystallinity.SOLUTION: A rosin-modified cellulose whose hydroxyl groups partly form ester linkages with acid anhydrides of rosin compounds, wherein a degree of modification of the cellulose is 1.0 to 20% and a degree of crystallinity is 40 or more according to X-ray crystal diffraction; rosin-modified cellulose microfibrils whose hydroxyl groups partly form ester linkages with acid anhydrides of rosin compounds, wherein a degree of modification of the cellulose is 1.0 to 20% and a degree of crystallinity is 40 or more according to X-ray crystal diffraction.
摘要:
PROBLEM TO BE SOLVED: To provide a size property expression accelerator aid accelerating a size effect expression of an alkyl ketene dimer, and to provide an AKD-based sizing agent for paper manufacturing, capable of shortening a time till the size effect expression which is regarded as a problem in conventional AKD-based sizing agents, and expressing size effects in wide paper-making conditions in neutral to acidic region.SOLUTION: A size property expression accelerator aid (A) containing at least one compound selected from a group consisting of (I) a carboxyl group-containing amide compound obtained by reacting (i) divalent or tetravalent polybasic carboxylic acid and (ii-1) primary and/or secondary aliphatic amine having 12 to 22 carbon atoms, (II) a carboxyl group-containing ester compound obtained by reacting (i) divalent or tetravalent polybasic carboxylic acid and (ii-2) aliphatic alcohol having 12 to 22 carbon atoms and (III) salts thereof is simultaneously used with an alkyl ketene dimer-based sizing agent for paper manufacturing.
摘要:
PROBLEM TO BE SOLVED: To provide a rosin emulsion sizing agent which is excellent in terms of an environmental aspect, a sanitation aspect and sizing performance without using epihalohydrin substantially.SOLUTION: A paper making rosin emulsion sizing agent is a resin emulsion obtained through phase inversion emulsification of rosin substances in the presence of polyamide polyamine (a1) and water soluble acids (a2). The sizing agent includes a resin emulsion (A) in which the amount of the water soluble acids (a2) used is 30 to 75% of protons in the equivalent ratio with respect to all amino groups included in the polyamide polyamine (a1).