公开(公告)号：KR1019900003276B1

公开(公告)日：1990-05-12

申请号：KR1019850006549

申请日：1985-09-07

Applicant: 시오노기세이야쿠가부시키가이샤

Inventor： 하야세요시오 ,  이찌나리미쓰하로 ,  다구찌준지 ,  이시구로다께오 ,  다까하시도시오

IPC: C07D279/06

CPC classification number: C07D279/06 ,  A01N57/32 ,  C07F9/6544

Abstract: The method for preparing thiazine phosphonic acid derivatives (I) (R1 and R2=lower alkoxy, alkynyloxy, alkylthio or alkylamino; R3 and R4=hydrogen, lower alkyl; R5,R6 and R7=hydrogen, halogen or trifluoromethyl; X=oxygen or sulfur) used in a insecticide comprises: (a) dissolving 5.64g of 2-phenylimino-5,5-dimethyl-3,4,5,6tetrahydro- 2H-1,3-thiazine in the mixture containing 2.85g of triethylamine and 50ml of benzene and agitating; (b) adding 5.29g of S-s-butyl O-methyl monochlorothiolphosphonate to the above mixture and reacting at 10-20≦̸C for 6 hrs.; (c) filtrating the reaction mixture and concentrating benzene layer to obtain 9.91g of product.

Abstract translation: 制备噻嗪膦酸衍生物（I）的方法（R 1和R 2 =低级烷氧基，炔氧基，烷硫基或烷基氨基; R 3和R 4 =氢，低级烷基; R 5，R 6和R 7 =氢，卤素或三氟甲基; X =氧或 用于杀虫剂的组合物包括：（a）将5.64g 2-苯基亚氨基-5,5-二甲基-3,4,5,6四氢-2H- 1,3-噻嗪溶于含有2.85g三乙胺和50ml 的苯和搅拌; （b）向上述混合物中加入5.29g的O-甲基一氯硫代膦酸S-仲丁酯，并在10-20℃下反应6小时。 （c）过滤反应混合物并浓缩苯层得到9.91g产物。