公开(公告)号：KR870002182B1

公开(公告)日：1987-12-28

申请号：KR820000133

申请日：1982-01-14

Applicant: UNION CARBIDE CORP

Inventor： HAMILTON JARRETTE ANTHONY

IPC: F27B1/10 ,  C21B7/00 ,  F27B1/00 ,  F27B1/16

Abstract: Molten metal is produced by (i) charging coke and metal to a cupola furnace; (ii) buring the coke with introduced O2-contg. gas (I); (iii) additionally injecting O2-contg. gas (II) having a higher O2 concn. than (I) into the furnace, at a rate of flow such that the O2 concn. of (I) is enriched by 0.5-10%. The improvement is that the gas (II) is injected into the furnace at a supersonic velocity. Metal melting is more efficient than in other methods in which oxygen is injected directy into the furnace, because the increased rate of flow of ozygen gives increased combusion reasction penetration. Thus, less coke or fuel is required.

公开(公告)号：KR870002127B1

公开(公告)日：1987-12-09

申请号：KR820000268

申请日：1982-01-22

Applicant: UNION CARBIDE CORP

Inventor： CLEVELAND THOMAS C ,  DEITZLER JAMES E ,  DOMAUX ARTHUR R ,  HENRY JOSEF P ,  HURT JOHN M ,  CAPIKET LOWIS A

IPC: C07C67/36 ,  A61K20060101 ,  B01J23/00 ,  B01J23/44 ,  C01B20060101 ,  C07B61/00 ,  C07C69/36

Abstract: Oxalate diesters are prepared by contacting a nitrogen oxide and a saturated C1-8 monohydric aliphatic alcohol in the vapor state in a nitrite forming reaction zone at 10-300≦̸C, followed by contacting of the nitrite free of H2O with CO in the vapor state in a oxalate forming reaction zone at 50-200≦̸C over a supported Pd catalyst. The process is continuous in recycling the final effluence containing nitrogen oxide to initial step.

公开(公告)号：KR870001853B1

公开(公告)日：1987-10-17

申请号：KR820004400

申请日：1982-09-29

Applicant: UNION CARBIDE CORP

Inventor： DOUMAX JR ARTHUR R ,  HENRY JOSEPH P ,  DOWNEY JAMES M ,  HURT JOHN M

IPC: C07C67/00 ,  C07C201/00 ,  C07C201/02 ,  C07C201/04 ,  C07C203/00 ,  F16L59/14 ,  C07C76/02 ,  C07C77/00

Abstract: A method for the prepg. nitrite esters comprises (i) reacting NOx composites (the mole ratio of NO to NO2 is 4:1, the mole ratio of aliphatic alcohols to NOx is up to 1) with aliphatic alcohols in the presence of inert diluent i.e. N2 for 0.01-50 secs at 10-300 deg.C and 14.7-100 psia; performed in the no quenching site tubular reactor: N2O3+ROH=RONO+HONO, (ii) reacting former mixt. by former conditions in the 2nd reacting zone contg. packing mateials: ROH+HONO=RONO+H2O, and (iii) recovering the nitrite ester from (ii). R is univalent hydrocarbon radical derived from aliphatic alcohols.

公开(公告)号：KR870000645B1

公开(公告)日：1987-04-03

申请号：KR820005802

申请日：1982-12-24

Applicant: UNION CARBIDE CORP

Inventor： JAMERSON JACKIE D ,  BILLIG ERNST ,  BRYANT DAVID R

IPC: B01J31/24 ,  B01J31/40 ,  C07C27/22 ,  C07C45/50 ,  C07F15/00

Abstract: Hydridocarbonyltris(triorganophosphorous)rhodium compd. is prepd. for use as hydroformylation agent. Condenced rhodium complex soln., hydrogen gas, alcohol diluent, carbon monoxide and triorganophosphorous ligand are mixed to give homogeneous organic reaction soln.. This nonaqueous reaction soln. is reacted at 20-120≦̸C to give hydridocarbonyltris(triorganophosphrous) rhodium compd.. The solvent of condensed rhodium complex soln. is perhydroformylation reaction medium. This process is simple and economical.

公开(公告)号：KR870000200B1

公开(公告)日：1987-02-16

申请号：KR820003667

申请日：1982-08-16

Applicant: UNION CARBIDE CORP

Inventor： ABATJOGLOU ANTHONY G ,  BRYANT DAVID R

IPC: B01J31/00 ,  B01J31/24 ,  C07C45/00 ,  C07C45/50 ,  C07C47/02 ,  C07C67/00 ,  B01J31/28

Abstract: Aldehydes are produced by hydroformylating an olefinically unsatd. compd. with CO and H2 in a reaction medium contg. a rhodium complex catalyst, free triarylphosphine ligand and free organic tert. bisphosphine monoxide ligand of formula(I) with the mole ration of triarylphosphine ligand to (I) being (2-30):1 (Ar is an opt. substd. aryl; R1, R2 and R3 are opt. subst. monovalent hydrocarbyl; and Y is a divalent bridging gp.). Also clamined is a rhodium complex hydroformylating catalystic precursor compsn. comprising a solubilised rhodium carbonyl phosphorus acetylacetonate complex, an organic solvent and the ligands given above.

公开(公告)号：KR860001823B1

公开(公告)日：1986-10-24

申请号：KR810004966

申请日：1981-12-17

Applicant: UNION CARBIDE CORP

Inventor： JONES JR ALLEN P ,  GUNNINGHAM CHARLES J

IPC: D06B1/08 ,  D06B19/00

公开(公告)号：KR860001173B1

公开(公告)日：1986-08-20

申请号：KR820003841

申请日：1982-08-26

Applicant: UNION CARBIDE CORP

Inventor： ANCKER FRED HARPOTH ,  ASHCRAFT ARNOLD CLIFTON JR ,  LEUNG MARTIN SIU-MO

IPC: C08K5/00 ,  C08F255/00 ,  C08F291/00 ,  C08K9/00 ,  C08K9/04 ,  C08L1/00 ,  C08L7/00 ,  C08L21/00 ,  C08L23/00 ,  C08L23/02 ,  C08L27/00 ,  C08L67/00 ,  C08L77/00 ,  C08L101/00

Abstract: A polymer compsn. having strength and ductility comprises a thermoplastic polymer (I) and an inorganic filler having an average particle size below 100 microns. Esp. the compsn. involves 0.1 - 5 wt.% based on the total compsn. of a reinforcement promoter having at least two reactive olefinic double bonds. The promoter has the promoter index P above O, where P is defined by the formula P=n(n-1) Q(e+2)(1-2Rf)-2.5. In the formula, n is the number of olefinic double bonds and is at least 2; Q and e are the Alfrey-Price resonance and polarity parameters; and Rf is 0 - 0.5 and is the relative flow ratio of the promoter.

公开(公告)号：KR850000792B1

公开(公告)日：1985-05-31

申请号：KR810001887

申请日：1981-05-28

Applicant: UNION CARBIDE CORP

Inventor： BERGSTEN VICTOR E ,  EARDLEY EDWARD P ,  FISHER THEODORE F

IPC: F23G5/24 ,  B03B9/06 ,  B09B3/00 ,  C10J3/08 ,  F23G5/027 ,  F23G7/00

公开(公告)号：KR840001701B1

公开(公告)日：1984-10-16

申请号：KR830005800

申请日：1983-12-07

Applicant: UNION CARBIDE CORP

Inventor： JONES DAVID NUNN ,  KURTZ STUART JACOB

IPC: B29D7/02

公开(公告)号：KR840001664B1

公开(公告)日：1984-10-12

申请号：KR810002152

申请日：1981-06-15

Applicant: UNION CARBIDE CORP

Inventor： JENKINS III JOHN M ,  CARTER MAX E ,  GREEN MICHAL L ,  CAVENDER MARVINE

IPC: G01N23/06 ,  C08F2/00 ,  C08F2/34 ,  C08F10/00 ,  G01N23/00 ,  G01N23/02 ,  G01N23/10