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    글리세롤로부터의 아크롤레인의 제조방법
    1.
    发明公开
    글리세롤로부터의 아크롤레인의 제조방법 有权
    从甘油制备丙烯酸的方法

    公开(公告)号：KR1020110077007A

    公开(公告)日：2011-07-06

    申请号：KR1020117011722

    申请日：2009-10-05

    Applicant: 아르끄마 프랑스

    Inventor： 뒤부아쟝-뤽

    IPC: C07C45/52 ,  B01J23/68

    CPC classification number: C07C45/52 ,  B01J23/682 ,  B01J2219/00006 ,  Y10S585/906 ,  C07C47/22

    Abstract: 본 발명의 대상은 산소, 인, 및 바나듐, 붕소 또는 알루미늄으로부터 선택되는 하나 이상의 금속을 포함하는 촉매계의 존재 하에서 글리세롤의 탈수 반응에 의한 아크롤레인의 제조 방법이다. 상기 방법은 바람직하게는 글리세롤 수용액으로부터 출발하여 산소의 존재 하에 기상에서 수행된다. 본 발명에 따른 방법은 아크롤레인을 고선택율로 수득할 수 있게 한다.

    촉매용 개질된 지지체 물질
    2.
    发明公开
    촉매용 개질된 지지체 물질 失效
    改性的催化剂支持材料

    公开(公告)号：KR1020070093971A

    公开(公告)日：2007-09-19

    申请号：KR1020077012528

    申请日：2005-11-21

    Applicant: 셀라니즈 인터내셔날 코포레이션

    Inventor： 키미취바바라 ,  웨이드레슬리이 ,  왕타오 ,  무넨로엘란두스에이치더블유 ,  시즉크스안드레에이치

    IPC: B01J23/52 ,  B01J23/68 ,  C07C67/055 ,  C07C69/01

    CPC classification number: B01J23/682 ,  B01J21/063 ,  B01J21/066 ,  B01J21/08 ,  B01J23/44 ,  B01J23/52 ,  B01J23/58 ,  B01J23/63 ,  B01J23/648 ,  B01J37/0207 ,  B01J37/16 ,  B01J2219/00745 ,  B01J2219/00747 ,  C07C67/055 ,  C40B30/08 ,  C40B40/18 ,  C07C69/01 ,  C07C69/15 ,  C07C69/24

    Abstract: The present invention relates to a method of producing a catalyst or pre-catalyst suitable for assisting in the production of alkenyl alkanoates. The method includes contacting a modifier precursor to a support material to form a modified support material. One or more catalytic component precursors (palladium or gold) may be contacted to the modified support material. The atomic ratio of gold to palladium is preferably in the range of about 0.3 to about 0.90. The support materials with the catalytic component may then be reduced using a reducing environment. A composition for catalyzing the production of an alkenyl alkanoates including a modified support material with palladium and gold is also included within the invention. Catalysts of the present invention may be used to produce alkenyl alkanoates in general and vinyl acetate in particular and are useful to produce low EA/VA ratios while maintaining or improving CO2 selectivity.

    Abstract translation: 本发明涉及一种制备适于辅助生产链烷酸链烯酯的催化剂或预催化剂的方法。 该方法包括使改性剂前体与载体材料接触以形成改性的载体材料。 一种或多种催化组分前体（钯或金）可以与改性的载体材料接触。 金与钯的原子比优选在约0.3至约0.90的范围内。 然后可以使用还原环境来减少具有催化组分的载体材料。 用于催化生产含钯和金的改性载体材料的链烷酸酯的组合物也包括在本发明内。 本发明的催化剂通常可用于制备烯基链烷酸酯，特别是乙酸乙烯酯，并且可用于在保持或提高CO 2选择性的同时产生低EA / VA比。

    은, 바나듐 및 인 계열 원소를 함유하는 다금속 산화물 및이의 용도
    3.
    发明公开
    은, 바나듐 및 인 계열 원소를 함유하는 다금속 산화물 및이의 용도 无效
    含钼，多晶和磷组合元素的多种氧化物及其用途

    公开(公告)号：KR1020070028413A

    公开(公告)日：2007-03-12

    申请号：KR1020067026208

    申请日：2005-06-14

    Applicant: 바스프 에스이

    Inventor： 네토사무엘 ,  힙스트하르트무트 ,  로소브스키프랑크 ,  스토르크세바스티안 ,  줄케유르겐

    IPC: C01G31/00 ,  C01G5/00 ,  B01J27/198 ,  B01J23/68

    CPC classification number: C01G31/00 ,  B01J23/002 ,  B01J23/682 ,  B01J27/198 ,  B01J2523/00 ,  C01P2002/72 ,  C01P2002/74 ,  C01P2006/12 ,  B01J2523/18 ,  B01J2523/51 ,  B01J2523/55

    Abstract: The invention relates to a novel multimetal oxide of general formula Aga-cQbMcV12Od * e H2O (I), wherein a is a value ranging from 3 to 10, Q is an element selected from P, As, Sb and/or Bi, b is a value from 0.2 to 3, M is a metal, c is a value from 0 to 3, provided that (a-c)> 0, 1, d is a number determined according to the valence and frequency of different oxygen elements in the formula (I) and e is a value ranging from 0 to 20, wherein said oxide is embodied in the form of a crystalline structure whose powder X-ray diffractogram is characterised in that the diffraction reflex thereof for selected lattice differences is at least equal to 5 for d=7.13; 5.52; 5.14; 3.57; 3.25; 2.83; 2.79; 2.73; 2.23 and 1.71Š(Œ0,04Š). The inventive multimetal oxides are used for producing precatalysts and catalysts for a gas phase partial oxidation of aromatic hydrocarbons and are transformable by heat-treating into silver-vanadium oxide bronzes which are catalytically active components of catalysts. ® KIPO & WIPO 2007

    Abstract translation: 本发明涉及通式为Aga-cQbMcV12Od * eH2O（I）的新型多金属氧化物，其中a为3至10的值，Q为选自P，As，Sb和/或Bi的元素，b为 如果（ac）> 0,1，d是根据式（3）中不同氧元素的化合价和频率确定的数，则为0.2〜3，M为金属，c为0〜3， I），e是0至20的值，其中所述氧化物以晶体结构的形式实施，其粉末X射线衍射图的特征在于其所选晶格差的衍射反射至少等于5，对于 D = 7.13; 5.52; 5.14; 3.57; 3.25; 2.83; 2.79; 2.73; 2.23和1.71Š（Œ0,04Š）。 本发明的多金属氧化物用于制备用于芳烃的气相部分氧化的预催化剂和催化剂，并且可以通过热处理成作为催化剂的催化活性组分的银 - 钒氧化物青铜来转化。 ®KIPO＆WIPO 2007

    니오브 또는 탄탈을 촉진제로 하는 은 촉매
    8.
    发明公开
    니오브 또는 탄탈을 촉진제로 하는 은 촉매 无效
    NIOBIUM或TANTALUM促销银催化剂

    公开(公告)号：KR1020000022355A

    公开(公告)日：2000-04-25

    申请号：KR1019980710783

    申请日：1997-10-21

    Applicant: 사이언티픽 디자인 컴파니 인코포레이티드

    Inventor： 리즈칼라네이빌

    IPC: B01J23/20 ,  B01J23/50 ,  B01J23/68

    CPC classification number: C07D301/10 ,  B01J23/682 ,  B01J27/04 ,  Y02P20/52

    Abstract: PURPOSE: A silver catalyst containing a promoter combination consisting of an alkali metal component, preferably cesium, together with a niobium or tantalum component, a sulfur component, and optionally a fluorine component is provided to produce ethylene oxide. CONSTITUTION: A niobium or tantalum promoted silver catalysts usually involve reaction temperatures of about 150°C. to 400°C, usually about 200°C to 300°C, and reaction pressures in the range of from 0.5 to 35 bar. Reactant feed mixtures contain 0.5 to 20% ethylene and 3 to 15% oxygen, with the balance comprising comparatively inert materials including such substances as nitrogen, carbon dioxide, methane, ethane, argon and the like. Only a portion of the ethylene usually is reacted per pass over the catalyst and after separation of the desired ethylene oxide product and the removal of appropriate purge streams and carbon dioxide to prevent uncontrolled build up of inerts and/or by-products, unreacted materials are returned to the oxidation reactor.

    Abstract translation: 目的：提供含有由碱金属组分（优选铯）与铌或钽组分，硫组分和任选的氟组分组成的助催化剂组合的银催化剂以产生环氧乙烷。 构成：铌或钽促进的银催化剂通常包括约150℃的反应温度。 通常为约200℃至300℃，反应压力为0.5至35巴。 反应物进料混合物含有0.5-20％乙烯和3-15％氧气，余量包括比较惰性的材料，包括氮，二氧化碳，甲烷，乙烷，氩等物质。 只有一部分乙烯通常在催化剂上反应，并且在分离出所需的环氧乙烷产物和除去合适的吹扫流和二氧化碳以防止惰性气体和/或副产物的不受控制的积聚之后，未反应的物质是 返回到氧化反应器。

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