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1.发明申请Process for the continuous transvinylation of carboxylic acids with vinyl acetate 有权羧酸与乙酸乙烯酯连续转乙烯化反应的方法公开(公告)号：US20110275853A1
公开(公告)日：2011-11-10
申请号：US13068130
申请日：2011-05-03
Applicant: Ilias S. Kotsianis , Barbara F.M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
Inventor： Ilias S. Kotsianis , Barbara F.M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
CPC classification number: C07C67/10 , C07C51/36 , C07C51/44 , C07C51/48 , Y02P20/127 , Y02P20/582 , C07C69/78 , C07C69/24 , C07C69/01 , C07C53/128 , C07C69/54
Abstract: A continuous process is provided for selective formation of a vinyl ester by reactive distillation from a corresponding carboxylic acid. Carboxylic acid, vinyl acetate, and a palladium acetate—bidentate ligand catalyst complex are provided and reacted in a typical embodiment. Acetic acid and vinyl acetate are continuously removed from the reaction mixture and vinyl acetate is recycled to the reaction mixture. The vinyl ester product is separated from the vinyl acetate, residual carboxylic acid, residual acetic acid, and catalyst.
Abstract translation: 提供了通过相应羧酸的反应蒸馏选择性形成乙烯基酯的连续方法。 提供羧酸，乙酸乙烯酯和乙酸钯 - 二齿配位体催化剂络合物并在典型的实施方案中进行反应。 从反应混合物中连续除去乙酸和乙酸乙烯酯，将乙酸乙烯酯再循环到反应混合物中。 将乙烯基酯产物与乙酸乙烯酯，残余羧酸，残余乙酸和催化剂分离。
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Patent Agency Ranking
2.发明申请Process for the semi-continuous transvinylation of carboxylic acids with vinyl acetate 有权羧酸与乙酸乙烯酯半连续转乙烯化反应的方法公开(公告)号：US20110275852A1
公开(公告)日：2011-11-10
申请号：US13068112
申请日：2011-05-03
Applicant: Ilias S. Kotsianis , Barbara F.M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
Inventor： Ilias S. Kotsianis , Barbara F.M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
CPC classification number: C07C67/10 , C07C51/36 , C07C51/44 , C07C51/48 , Y02P20/127 , Y02P20/582 , C07C69/78 , C07C69/24 , C07C69/01 , C07C53/128 , C07C69/54
Abstract: A semi-continuous process is provided for selective formation of a vinyl ester by reactive distillation from a corresponding carboxylic acid. Carboxylic acid, vinyl acetate, and a palladium acetate—bidentate ligand catalyst complex are provided and reacted in a typical embodiment. Acetic acid and vinyl acetate are continuously removed from the reaction mixture and vinyl acetate is recycled to the reaction mixture. The vinyl ester product is separated from the vinyl acetate, residual carboxylic acid, residual acetic acid, and catalyst.
Abstract translation: 提供半连续方法用于通过相应的羧酸的反应蒸馏选择性形成乙烯基酯。 提供羧酸，乙酸乙烯酯和乙酸钯 - 二齿配位体催化剂络合物并在典型的实施方案中进行反应。 从反应混合物中连续除去乙酸和乙酸乙烯酯，将乙酸乙烯酯再循环到反应混合物中。 将乙烯基酯产物与乙酸乙烯酯，残余羧酸，残余乙酸和催化剂分离。
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公开(公告)号：US5594137A
公开(公告)日：1997-01-14
申请号：US368647
申请日：1995-01-04
Applicant: Brajesh K. Jha , Ajay S. Chhatre , Bhaskar D. Kulkarni , Subramanian Sivasanker
Inventor： Brajesh K. Jha , Ajay S. Chhatre , Bhaskar D. Kulkarni , Subramanian Sivasanker
IPC: C07D201/04
CPC classification number: C07D201/04
Abstract: A process for the preparation of caprolactam by reacting cyclohexanone oxime with a cationic or nonionic surfactant and a cosurfactant in dilute sulfuric acid at a temperature in the range of 15.degree. C. to 40.degree. C., neutralizing excess acid present in the solution and recovering the caprolactam from the solution by filtration.
Abstract translation: 通过环己酮肟与阳离子或非离子表面活性剂和辅助表面活性剂在稀硫酸中在15℃至40℃的温度下反应制备己内酰胺的方法，中和溶液中存在的过量酸，并回收 己内酰胺从溶液中过滤。
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公开(公告)号：US5401843A
公开(公告)日：1995-03-28
申请号：US221180
申请日：1994-03-31
Applicant: Brajesh K. Jha , Ajay S. Chhatre , Bhaskar D. Kulkarni , Subramanian Sivasanker
Inventor： Brajesh K. Jha , Ajay S. Chhatre , Bhaskar D. Kulkarni , Subramanian Sivasanker
IPC: C07D201/04
CPC classification number: C07D201/04
Abstract: A process for the preparation of caprolactam by reacting cyclohexanone oxime with an anionic surfactant and a cosurfactant in dilute sulfuric acid at a temperature in the range of 15.degree. C. to 40.degree. C., neutralising excess acid present in the solution and from the solution by filtration.
Abstract translation: 通过环己酮肟与阴离子表面活性剂和辅助表面活性剂在15至40℃的温度下在稀硫酸中反应制备己内酰胺的方法，中和溶液中存在的过量酸和溶液 通过过滤。
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5.发明授权Process for the continuous transvinylation of carboxylic acids with vinyl acetate 有权羧酸与乙酸乙烯酯连续转乙烯化反应的方法公开(公告)号：US08975437B2
公开(公告)日：2015-03-10
申请号：US13068130
申请日：2011-05-03
Applicant: Ilias S. Kotsianis , Barbara F. M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
Inventor： Ilias S. Kotsianis , Barbara F. M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
CPC classification number: C07C67/10 , C07C51/36 , C07C51/44 , C07C51/48 , Y02P20/127 , Y02P20/582 , C07C69/78 , C07C69/24 , C07C69/01 , C07C53/128 , C07C69/54
Abstract: A continuous process is provided for selective formation of a vinyl ester by reactive distillation from a corresponding carboxylic acid. Carboxylic acid, vinyl acetate, and a palladium acetate—bidentate ligand catalyst complex are provided and reacted in a typical embodiment. Acetic acid and vinyl acetate are continuously removed from the reaction mixture and vinyl acetate is recycled to the reaction mixture. The vinyl ester product is separated from the vinyl acetate, residual carboxylic acid, residual acetic acid, and catalyst.
Abstract translation: 提供了通过相应羧酸的反应蒸馏选择性形成乙烯基酯的连续方法。 提供羧酸，乙酸乙烯酯和乙酸钯 - 二齿配位体催化剂络合物并在典型的实施方案中进行反应。 从反应混合物中连续除去乙酸和乙酸乙烯酯，将乙酸乙烯酯再循环到反应混合物中。 将乙烯基酯产物与乙酸乙烯酯，残余羧酸，残余乙酸和催化剂分离。
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6.发明授权Process for the semi-continuous transvinylation of carboxylic acids with vinyl acetate 有权羧酸与乙酸乙烯酯半连续转乙烯化反应的方法公开(公告)号：US08921593B2
公开(公告)日：2014-12-30
申请号：US13068112
申请日：2011-05-03
Applicant: Ilias S. Kotsianis , Barbara F. M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
Inventor： Ilias S. Kotsianis , Barbara F. M. Kimmich , Melchior A. Meilchen , Hang Wang , Prashant P. Barve , Bhaskar D. Kulkarni , Gopal M. Chaphekar , Ravindra W. Shinde , Milind Y. Gupte , Sanjay P. Kamble , Satish N. Shintre
CPC classification number: C07C67/10 , C07C51/36 , C07C51/44 , C07C51/48 , Y02P20/127 , Y02P20/582 , C07C69/78 , C07C69/24 , C07C69/01 , C07C53/128 , C07C69/54
Abstract: A semi-continuous process is provided for selective formation of a vinyl ester by reactive distillation from a corresponding carboxylic acid. Carboxylic acid, vinyl acetate, and a palladium acetate—bidentate ligand catalyst complex are provided and reacted in a typical embodiment. Acetic acid and vinyl acetate are continuously removed from the reaction mixture and vinyl acetate is recycled to the reaction mixture. The vinyl ester product is separated from the vinyl acetate, residual carboxylic acid, residual acetic acid, and catalyst.
Abstract translation: 提供半连续方法用于通过相应的羧酸的反应蒸馏选择性形成乙烯基酯。 提供羧酸，乙酸乙烯酯和乙酸钯 - 二齿配位体催化剂络合物并在典型的实施方案中进行反应。 从反应混合物中连续除去乙酸和乙酸乙烯酯，将乙酸乙烯酯再循环到反应混合物中。 将乙烯基酯产物与乙酸乙烯酯，残余羧酸，残余乙酸和催化剂分离。
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