公开(公告)号：US20140171590A1

公开(公告)日：2014-06-19

申请号：US13714150

申请日：2012-12-13

申请人： Wen-Chiung Su ,  Ru-Jong Jeng ,  Tzong-Yuan Juang ,  Shi-Min Shau ,  Guan-Liang Chen ,  Han-Sheng Lin

发明人： Wen-Chiung Su ,  Ru-Jong Jeng ,  Tzong-Yuan Juang ,  Shi-Min Shau ,  Guan-Liang Chen ,  Han-Sheng Lin

IPC分类号： C08G69/40 ,  C08K3/20

CPC分类号： C08G69/40 ,  C01B32/20 ,  C08G73/1032 ,  C08G73/1046 ,  C08G73/1075 ,  C08G73/1082 ,  C08K3/20 ,  C08K9/04 ,  C08K9/12

摘要： A facile synthesis of amphiphilic hyperbranched polymers consisting of poly(amic acid) and polyimide was developed via “A2+B3” approach from difunctional anhydride and trifunctional hydrophilic poly(oxyalkylene)triamine. Various amphiphilic hyperbranched poly(amic acid)s (HBPAAs) with terminal amine functionalities and amic acid structures were prepared through ring-opening polyaddition at room temperature, followed by thermal imidization process for the formation of hyperbranched polyimides (HBPIs), accordingly. The resulting HBPIs were analyzed by GPC, indicating the molecule weights of 5000˜7000 g/mol with a distribution of polydispersity between 2.0 and 3.8. The amine titration for HBPIs indicated the peripheral total-amine contents to be 8.32˜18.32 mequiv/g dependent on compositions.

摘要翻译： 通过“A2 + B3”方法从双官能酐和三官能亲水性聚（氧化烯）三胺开发了由聚（酰胺酸）和聚酰亚胺组成的两亲性超支化聚合物的容易合成。 通过在室温下开环加聚制备了具有末端胺官能团和酰胺酸结构的各种两亲性超支化聚（酰胺酸）（HBPAA），然后进行用于形成超支化聚酰亚胺（HBPI）的热酰亚胺化方法。 通过GPC分析所得到的HBPI，表明分子量为5000〜7000g / mol，多分散性分布在2.0〜3.8之间。 HBPI的胺滴定表明，根据成分，外周总胺含量为8.32〜18.32mequiv / g。