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公开(公告)号：US06875880B2
公开(公告)日：2005-04-05
申请号：US10347308
申请日：2003-01-21
申请人： Hiromi Nishiwaki , Ayumu Kiyomori , Tohru Kubota
发明人： Hiromi Nishiwaki , Ayumu Kiyomori , Tohru Kubota
CPC分类号： C07F7/1892 , C07F7/188
摘要： A compound having a non-silanol hydroxyl group and a compound having a silanol group are subjected to dehydrative condensation in the presence of a compound of formula (1), (2) or (3): MXn (1) ZaSiR1bR2cR3d (2) CmF2m+1SO3Y (3) wherein M is a metal, n is the valence of metal M, and X is halogen or CmF2m+1SO3; a=1 to 4, b, c and d=0 to 3, a+b+c+d=4, R1, R2 and R3 are monovalent hydrocarbon groups, Z is halogen or CmF2m+1SO3; Y is H or HW, W is an amine NR4R5R6 or a nitrogen-containing heterocyclic compound, R4, R5 and R6 are H or monovalent hydrocarbyl groups, and m=0 to 10. The method is effective in silylating the hydroxyl group without generating a substantial amount of harmful by-products such as hydrogen chloride or triethylamine hydrochloride.
摘要翻译： 具有非硅烷醇羟基的化合物和具有硅烷醇基的化合物在式（1），（2）或（3）的化合物存在下进行脱水缩合：其中M是金属，n是 金属M的价数，X是卤素或C m F 2m + 1 SO 3; a = 1至4，b，c和d = 0至3，a + b + c + d = 4，R 1，R 2和R 3为一价烃基，Z为卤素或C m F 2m + 1SO3; Y是H或HW，W是胺NR 4 R 5 R 6或含氮杂环化合物，R 4，R 5和R 6是H或一价烃基 ，并且m = 0至10.该方法在不产生大量有害副产物如氯化氢或三乙胺盐酸盐的情况下对羟基进行甲硅烷基化是有效的。
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公开(公告)号：US20050004383A1
公开(公告)日：2005-01-06
申请号：US10868980
申请日：2004-06-17
CPC分类号： C07F5/00
摘要： A contaminated Group III metal hydrocarbon is purified by providing an adduct of Group III metal hydrocarbon with a Lewis base in a solvent having a boiling point which is up to 200° C., but at least 30° C. higher than the boiling point of the Group III metal hydrocarbon, separating the solvent from the adduct, and heating the adduct for thermal dissociation, thereby releasing the Group III metal hydrocarbon in high purity form.
摘要翻译： 污染的第III族金属烃通过在沸点高达200℃但高至少30℃的溶剂中提供第III族金属烃与路易斯碱的加合物来纯化， 第III族金属烃，将溶剂与加合物分离，并加热加合物进行热解，从而释放出高纯度形式的III族金属烃。
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3.发明授权High-purity trimethylaluminum and purification method of crude trimethylaluminum 有权高纯度三甲基铝和粗三甲基铝的纯化方法公开(公告)号：US07179931B2
公开(公告)日：2007-02-20
申请号：US11154535
申请日：2005-06-17
IPC分类号： C07F5/06
CPC分类号： C07F5/062
摘要： High-purity trimethylaluminum has the following impurity contents: organosilicon components≦0.5 ppm, chlorine components≦20 ppm, hydrocarbon components≦1,000 ppm, Ca≦0.05 ppm, Fe≦0.05 ppm, Mg≦0.05 ppm, Na≦0.05 ppm, Si (Si components other than the organosilicon components)≦0.07 ppm, Zn≦0.05 ppm, and S≦0.05 ppm. The high-purity trimethylaluminum can be obtained by removing impurities from crude trimethylaluminum through distillation and evaporation.
摘要翻译： 高纯度三甲基铝具有以下杂质含量：有机硅组分<= 0.5ppm，氯组分<= 20ppm，烃组分<= 1,000ppm，Ca <= 0.05ppm，Fe <= 0.05ppm，Mg <= 0.05ppm，Na <= 0.05ppm，Si（除有机硅成分以外的Si成分）<= 0.07ppm，Zn <= 0.05ppm，S <0.05ppm。 高纯度三甲基铝可以通过蒸馏除去粗三甲基铝中的杂质而获得。
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4.发明授权Purification method for organometallic compounds and organometallic compounds obtained therefrom 有权由其获得的有机金属化合物和有机金属化合物的纯化方法公开(公告)号：US07112691B2
公开(公告)日：2006-09-26
申请号：US11154534
申请日：2005-06-17
CPC分类号： C07F5/062
摘要： A method of purifying an organometallic compound comprising distilling the organometallic compound for purification while blowing an inert gas through a vapor of the organopolysiloxane, thereby removing from the organometallic compound an impurity having a higher vapor pressure than the organometallic compound.
摘要翻译： 一种纯化有机金属化合物的方法，其包括在通过有机聚硅氧烷的蒸气吹入惰性气体的同时蒸馏有机金属化合物，从而从有机金属化合物除去具有比有机金属化合物更高的蒸气压的杂质。
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5.发明申请High-purity trimethylaluminum and purification method of crude trimethylaluminum 有权高纯度三甲基铝和粗三甲基铝的纯化方法公开(公告)号：US20050283016A1
公开(公告)日：2005-12-22
申请号：US11154535
申请日：2005-06-17
IPC分类号： C07F5/06
CPC分类号： C07F5/062
摘要： High-purity trimethylaluminum has the following impurity contents: organosilicon components≦0.5 ppm, chlorine components≦20 ppm, hydrocarbon components≦1,000 ppm, Ca≦0.05 ppm, Fe≦0.05 ppm, Mg≦0.05 ppm, Na≦0.05 ppm, Si (Si components other than the organosilicon components)≦0.07 ppm, Zn≦0.05 ppm, and S≦0.05 ppm. The high-purity trimethylaluminum can be obtained by removing impurities from crude trimethylaluminum through distillation and evaporation.
摘要翻译： 高纯度三甲基铝具有以下杂质含量：有机硅组分<= 0.5ppm，氯组分<= 20ppm，烃组分<= 1,000ppm，Ca <= 0.05ppm，Fe <= 0.05ppm，Mg <= 0.05ppm，Na <= 0.05ppm，Si（除有机硅成分以外的Si成分）<= 0.07ppm，Zn <= 0.05ppm，S <0.05ppm。 高纯度三甲基铝可以通过蒸馏除去粗三甲基铝中的杂质而获得。
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公开(公告)号：US07005530B2
公开(公告)日：2006-02-28
申请号：US10868980
申请日：2004-06-17
IPC分类号： C07F5/00
CPC分类号： C07F5/00
摘要： A contaminated Group III metal hydrocarbon is purified by providing an adduct of Group III metal hydrocarbon with a Lewis base in a solvent having a boiling point which is up to 200° C., but at least 30° C. higher than the boiling point of the Group III metal hydrocarbon, separating the solvent from the adduct, and heating the adduct for thermal dissociation, thereby releasing the Group III metal hydrocarbon in high purity form.
摘要翻译： 污染的第III族金属烃通过在沸点高达200℃但高至少30℃的溶剂中提供第III族金属烃与路易斯碱的加合物来纯化， 第III族金属烃，将溶剂与加合物分离，并加热加合物进行热解，从而释放出高纯度形式的III族金属烃。
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7.发明申请Purification method for organometallic compounds and organometallic compounds obtained therefrom 有权由其获得的有机金属化合物和有机金属化合物的纯化方法公开(公告)号：US20050283015A1
公开(公告)日：2005-12-22
申请号：US11154534
申请日：2005-06-17
IPC分类号： C07F5/06
CPC分类号： C07F5/062
摘要： A method of purifying an organometallic compound comprising distilling the organometallic compound for purification while blowing an inert gas through a vapor of the organopolysiloxane, thereby removing from the organometallic compound an impurity having a higher vapor pressure than the organometallic compound.
摘要翻译： 一种纯化有机金属化合物的方法，其包括在通过有机聚硅氧烷的蒸气吹入惰性气体的同时蒸馏有机金属化合物，从而从有机金属化合物除去具有比有机金属化合物更高的蒸气压的杂质。
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公开(公告)号：US06867315B2
公开(公告)日：2005-03-15
申请号：US10868759
申请日：2004-06-17
IPC分类号： C07F5/00
CPC分类号： C07F5/00
摘要： Trialkylgallium is prepared by reacting a gallium halide or alkyl gallium with trialkylaluminum in a solvent having a boiling point which is at least 10° C. higher than the boiling point of the trialkylgallium, such as mesitylene or o-dichlorobenzene. High purity alkyl gallium is obtained in high yields.
摘要翻译： 三烷基镓通过卤化镓或烷基镓与三烷基铝在沸点比三烷基镓的沸点至少高10℃的溶剂中反应制备，例如均三甲苯或邻二氯苯。 以高产率获得高纯度烷基镓。
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