公开(公告)号：US09266308B2

公开(公告)日：2016-02-23

申请号：US13724005

申请日：2012-12-21

Applicant: BASF SE

Inventor： Stephan Weinkötz ,  Michael Schmidt ,  Michael Finkenauer ,  Ralph Lunkwitz

IPC: B32B21/02 ,  C08L97/02 ,  B32B3/26

CPC classification number: B32B21/02 ,  B32B3/26 ,  B32B2264/0214 ,  B32B2264/065 ,  B32B2264/12 ,  B32B2471/00 ,  B32B2479/00 ,  C08L97/02 ,  Y10T428/249972 ,  C08L25/04

Abstract: The invention is directed to lignocellulosic materials having a core and two outer layers, containing in the core A) lignocellulose particles; B) expanded plastics particles having a bulk density in the range from 10 to 150 kg/m3, C) one or more binders selected from the group consisting of aminoplast resin, phenoplast resin, and organic isocyanate having at least two isocyanate groups, and D) optionally additives and in the outer layers E) lignocellulose particles, F) one or more binders selected from the group consisting of aminoplast resin, phenol-formaldehyde resin, and organic isocyanate having at least two isocyanate groups, and where the lignocellulose particles of the outer layers E comprise at least 25% by weight of lignocellulosic chips and the expanded plastics particles B are present in nonuniform distribution in the core.

Abstract translation: 本发明涉及具有芯和两个外层的木质纤维素材料，其包含在芯A）木质纤维素颗粒中; B）膨胀密度在10至150kg / m 3范围内的膨胀塑料颗粒，C）一种或多种选自氨基塑料树脂，酚醛树脂和具有至少两个异氰酸酯基团的有机异氰酸酯的粘合剂，D ）任选的添加剂和外层E）木质纤维素颗粒，F）一种或多种选自氨基塑料树脂，酚醛树脂和具有至少两个异氰酸酯基团的有机异氰酸酯的粘合剂，其中木质纤维素颗粒 外层E包含至少25重量％的木质纤维素片，并且发泡塑料颗粒B以不均匀分布存在于芯中。

公开(公告)号：US10391669B2

公开(公告)日：2019-08-27

申请号：US15110528

申请日：2015-01-09

Applicant: BASF SE

Inventor： Stephan Weinkötz

IPC: B27N3/00 ,  B27N3/02 ,  B27N3/04 ,  B27N3/08 ,  B27N3/18

Abstract: The present invention relates to a process for the production of lignocellulose materials via mixing A) of lignocellulose-containing particles or fibers, B) with organic isocyanate having at least two isocyanate groups or a mixture of these, and optionally with C) binders selected from the group of the phenol-formaldehyde resins, the aminoplastic resins, the protein-based binders, and other polymer-based binders, and mixtures of these, D) additives or a mixture of these, and E) plastics particles or a mixture of these, with the steps of: i.) scattering of the resultant mixture to give a mat, ii.) precompaction and heating of the mat during or after the precompaction process, and iii.) then hot pressing, wherein, in the step ii.), operations are carried out at elevated temperature during and/or after the precompaction process, and a value of at least 4 cm is achieved for the resultant mat in the push-off test.

公开(公告)号：US10661472B2

公开(公告)日：2020-05-26

申请号：US15534223

申请日：2015-12-07

Applicant: BASF SE

Inventor： Stephan Weinkötz ,  Ingolf Hennig ,  Matthias Schade ,  Detlef Krug ,  Marco Mäbert

IPC: B27N3/02 ,  B27N3/00 ,  B27N3/24 ,  B27N3/18 ,  B27N3/06 ,  B32B5/14

Abstract: The invention relates to a method for producing multi-layered lignocellulose materials having a core and an upper and a lower cover layer, said method comprising the following steps a) mixing the components, b) spreading the mixtures in layers, c) pre-compressing, d) applying a high-frequency electric field e) hot pressing. According to the invention, a mixture of C) 1-15 wt.-% of a binding agent selected from the group consisting of aminoplastic resin and organic isocyanate having at least two isocyanate groups [components C)], F) 0.1-3% alkali-/akaline earth salts, for the cover layers of the lignocellulose particles G) with H) 1-15% of a binding agent selected from the group consisting of aminoplastic resin and an organic isocyanate is mixed. After step a) the mixture for the core contains, with respect to the total dry weight of the mixture of the components A)-F) 3-15% water, the mixture for the cover layers of the components G)-K) contains 5-20% water, and the following conditions are met: F)≥1,1•components K) and [components F)+components D)]≥1,1•[components K)+components I)].

公开(公告)号：US10399246B2

公开(公告)日：2019-09-03

申请号：US15562093

申请日：2016-03-24

Applicant: BASF SE

Inventor： Jean-Pierre Berkan Lindner ,  Lukas Janitzki ,  Stephan Weinkötz

IPC: B27N3/00 ,  B27N3/10 ,  C08L97/02

Abstract: The present invention relates to a batchwise or continuous process for producing single-layer one multilayer lignocellulosic materials, comprising the process steps of (I) mixing the components of the individual layers, (II) scattering the mixture(s) produced in process step (I) to give a mat, (III) optionally precompacting the scattered mat and (IV) hot-pressing the optionally precompacted mat, by using, in process step (I), for the core of multilayer lignocellulosic materials or for single-layer lignocellulosic materials, a mixture (component A) comprising a1) 50% to 99% by weight, preferably 70% to 97% by weight, more preferably 80% to 95% by weight and especially 85% to 92% by weight of organic isocyanate having at least two isocyanate groups or mixtures thereof and a2) 1% to 50% by weight, preferably 3% to 30% by weight, more preferably 5% to 20% by weight and especially 8% to 15% by weight of organic carboxylic acid, carboxylic anhydride, carbonyl chloride or mixtures thereof and a3) 0% to 49% by weight, preferably 0% to 10% by weight and more preferably 0% to 5% by weight of auxiliaries or mixtures thereof.

公开(公告)号：US09080086B2

公开(公告)日：2015-07-14

申请号：US13852427

申请日：2013-03-28

Applicant: BASF SE

Inventor： Michael Finkenauer ,  Konrad Roschmann ,  Ralph Lunkwitz ,  Stephan Weinkötz

IPC: C08G12/12 ,  C09J161/30 ,  C08G12/00

CPC classification number: C09J161/30 ,  B27N3/002 ,  C08G12/38 ,  C08L97/02 ,  C08L61/30

Abstract: The present invention relates to a process for producing melamine-urea-formaldehyde resins with up to 0.9% of melamine by reacting a) urea which comprises from 0 to 10% by weight of one or more compounds A, formaldehyde, and melamine in the presence of a base at a pH of from 7.5 to 11, at a temperature of from 20 to 120° C., and at a pressure of from 0.1 to 10 bar, b) and then carrying out reaction in the presence of an acid which optionally comprises urea with from 0 to 10% by weight of one or more compounds A, at a temperature of from 60 to 180° C., and at a pressure of from 0.1 to 10 bar, and c) and then adding urea which comprises from 0 to 10% by weight of one or more compounds A, which comprises carrying out b) at a pH of from 4 to 5.9.

Abstract translation: 本发明涉及一种通过使a）含有0-10重量％的一种或多种化合物A，甲醛和三聚氰胺的脲在存在下生成具有高达0.9％三聚氰胺的三聚氰胺 - 脲 - 甲醛树脂的方法 的碱为7.5至11，温度为20至120℃，压力为0.1至10巴，b）然后在酸的存在下进行反应，所述酸可任选地 包括含有0至10重量％的一种或多种化合物A的脲，在60至180℃的温度和0.1至10巴的压力下，和c）然后加入包含 0至10重量％的一种或多种化合物A，其包括在4至5.9的pH下进行b）。

公开(公告)号：US20150045500A1

公开(公告)日：2015-02-12

申请号：US14451948

申请日：2014-08-05

Applicant: BASF SE

Inventor： Michael FINKENAUER ,  Evelyn Fuchs ,  Ralph Lunkwitz ,  Oliver Reese ,  Konrad Roschmann ,  Michael Schmidt ,  Martin Reif ,  Stephan Weinkötz

IPC: C08G12/12 ,  C08J5/00 ,  C09J161/24

CPC classification number: C08G12/12 ,  C08G12/00 ,  C08J5/005 ,  C08J2361/24 ,  C09J161/24

Abstract: The present invention relates to processes for discontinuously or continuously preparing aminoplast solutions by condensation of aminoplast formers with formaldehyde in a serial cascade of at least three stirred tank apparatus A, B, and C, which involves a) in apparatus A, reacting a mixture comprising formaldehyde and urea in a molar ratio of 2.3:1 to 2.9:1 and water at a pH of 6 to 8, set by means of a base, at a temperature of 80 to 85° C., where apparatus A consists of one or more, i.e., one to ten, preferably one to five, more preferably one to three, more particularly one or two stirred tanks in parallel or in series, very preferably of one stirred tank, b) in apparatus B, reacting said mixture at a molar ratio of formaldehyde to urea of 1.9:1 to 2.6:1, where apparatus B consists of one or more stirred tanks, wherein the molar ratio of formaldehyde to urea is lowered, optionally by further addition of urea, in stages to not less than 1.9:1, at a pH of 3.5 to 5.5, which is kept virtually constant, at a temperature of 100 to 105° C., and with a mean residence time of 10 to 90 minutes in the entire apparatus B, c) in apparatus C, at a temperature of 90 to 100° C., raising the pH to at least 5.9 and lowering the molar ratio of formaldehyde to urea to 1.7:1 to 1.4:1, where apparatus C consists of one or more stirred tanks, and d) by adding urea, at temperatures of 15 to 100° C., setting a final molar ratio of formaldehyde to urea of 0.7:1 to 1.28:1 and a pH of at least 7.

Abstract translation: 本发明涉及通过在至少三个搅拌罐装置A，B和C的串联级联中将氨基塑料形成物与甲醛缩合而不连续或连续制备氨基塑料溶液的方法，其涉及a）在装置A中，使包含 甲醛和尿素的摩尔比为2.3:1至2.9:1，pH为6至8的水通过碱在80至85℃的温度下设定，其中装置A由一个或多个 更优选地，即一至十个，优选一至五个，更优选一至三个，更特别地一个或两个平行或串联的搅拌槽，非常优选一个搅拌槽，b）在设备B中，使所述混合物在 甲醛与尿素的摩尔比为1.9:1至2.6:1，其中装置B由一个或多个搅拌槽组成，其中甲醛与尿素的摩尔比降低，任选地通过进一步加入尿素分级至不小于 1.9：1，pH 3.5〜5.5，保持v 在100至105℃的温度下，在装置C中的整个装置B，c）中的平均停留时间为10至90分钟，温度为90至100℃，升温 pH至至少5.9，并将甲醛与尿素的摩尔比降低至1.7：1至1.4：1，其中装置C由一个或多个搅拌槽组成，d）在15至100℃的温度下加入尿素。 ，将甲醛与尿素的最终摩尔比设定为0.7:1至1.28:1，pH至少为7。

公开(公告)号：US20130177757A1

公开(公告)日：2013-07-11

申请号：US13724005

申请日：2012-12-21

Applicant: BASF SE

Inventor： Stephan Weinkötz ,  Michael Schmidt ,  Michael Finkenauer ,  Ralph Lunkwitz

IPC: C08L97/02 ,  B32B3/26

CPC classification number: B32B21/02 ,  B32B3/26 ,  B32B2264/0214 ,  B32B2264/065 ,  B32B2264/12 ,  B32B2471/00 ,  B32B2479/00 ,  C08L97/02 ,  Y10T428/249972 ,  C08L25/04

Abstract: The invention is directed to lignocellulosic materials having a core and two outer layers, containing in the core A) lignocellulose particles; B) expanded plastics particles having a bulk density in the range from 10 to 150 kg/m3, C) one or more binders selected from the group consisting of aminoplast resin, phenoplast resin, and organic isocyanate having at least two isocyanate groups, and D) optionally additives and in the outer layers E) lignocellulose particles, F) one or more binders selected from the group consisting of aminoplast resin, phenol-formaldehyde resin, and organic isocyanate having at least two isocyanate groups, and where the lignocellulose particles of the outer layers E comprise at least 25% by weight of lignocellulosic chips and the expanded plastics particles B are present in nonuniform distribution in the core.

Abstract translation: 本发明涉及具有芯和两个外层的木质纤维素材料，其包含在芯A）木质纤维素颗粒中; B）膨胀密度在10至150kg / m 3范围内的膨胀塑料颗粒，C）一种或多种选自氨基塑料树脂，酚醛树脂和具有至少两个异氰酸酯基团的有机异氰酸酯的粘合剂，D ）任选的添加剂和外层E）木质纤维素颗粒，F）一种或多种选自氨基塑料树脂，酚醛树脂和具有至少两个异氰酸酯基团的有机异氰酸酯的粘合剂，其中木质纤维素颗粒 外层E包含至少25重量％的木质纤维素片，并且发泡塑料颗粒B以不均匀分布存在于芯中。

公开(公告)号：US10421256B2

公开(公告)日：2019-09-24

申请号：US15534181

申请日：2015-12-09

Applicant: BASF SE

Inventor： Stephan Weinkötz ,  Detlef Krug ,  Marco Mäbert

IPC: B32B21/08 ,  C08F212/08 ,  C08L97/02 ,  B27N3/18 ,  B27N3/24 ,  B32B21/02 ,  B27N3/00

Abstract: The present invention relates to a process for the batchwise or continuous, preferably continuous production of single-layer lignocellulose-based boards or of multilayer lignocellulose-based boards with a core and with at least one upper and one lower outer layer,comprising the following steps: a) mixing of the components of the individual layer(s), b) layer-by-layer scattering of the mixtures to give a mat, c) compaction after the scattering of the individual layer(s), d) application of a high-frequency electrical field, during and/or after the compaction and thermal hardening of the binder(s), e) then optionally hot pressing, and f) cooling the lignocellulose material, where, in step a), for the core or the single layer, the lignocellulose particles A) [component A)] are mixed with B) from 0 to 25% by weight of expanded plastics particles with bulk density in the range from 10 to 150 kg/m3 [component B)], C) from 1 to 15% by weight of one or more binders selected from the group consisting of aminoplastic resin and organic isocyanate having at least two isocyanate groups [component C)], D) from 0 to 3% by weight of ammonium salts [component D)], E) from 0 to 5% by weight of additives [component E)] and F) from 0.1 to 3% by weight of alkali metal salts or alkaline earth metal salts from the group of the sulfates, nitrates, halides and mixtures of these [component F)], and optionally for the outer layers, the lignocellulose particles G) [component G)] are mixed with H) from 1 to 15% by weight of one or more binders selected from the group consisting of aminoplastic resin and organic isocyanate having at least two isocyanate groups [component H)], I) from 0 to 2% by weight of ammonium salts [component I)], J) from 0 to 5% by weight of additives [component J)] and K) from 0.1 to 3% by weight of alkali metal salts or alkaline earth metal salts from the group of the sulfates, nitrates, halides and mixtures of these [component K)], wherein at the juncture Z the temperature of the layer of the core or of the single layer is more than 90° C., and this temperature is reached in less than 40 s/mm·d after the application of the high-frequency electrical field, where d is the thickness of the sheet of lignocellulose material at the juncture Z.

公开(公告)号：US20150017425A1

公开(公告)日：2015-01-15

申请号：US14321557

申请日：2014-07-01

Applicant: BASF SE

Inventor： Matthias Schade ,  Stephan Weinkötz ,  Günter Scherr ,  Jens Aßmann ,  Dietrich Scherzer

IPC: C08L97/02 ,  B32B21/02 ,  C08L61/24 ,  B27N3/08

CPC classification number: C08L97/02 ,  B27N3/08 ,  B32B21/02 ,  B32B2264/0214 ,  C08J9/0085 ,  C08J9/236 ,  C08J2461/06 ,  C08J2461/32 ,  C08J2475/04 ,  C08L61/24 ,  Y10T428/254

Abstract: The present invention relates to lignocellulose materials which comprise A) 30 to 98 wt % of one or more lignocellulosic substances, B) 1 to 25 wt % of expanded plastics particles having a bulk density in the range from 10 to 150 kg/m3, C) 1 to 50 wt % of a binder selected from the group consisting of amino resin, phenol-formaldehyde resin, organic isocyanate having at least two isocyanate groups, or mixtures thereof, optionally with a curing agent, and D) 0 to 68 wt % of additives, wherein component B) or the original expandable plastics particles are coated with at least one coating material before, during, or after expansion.

Abstract translation: 本发明涉及木素纤维素材料，其包含A）30至98重量％的一种或多种木质纤维素物质，B）1至25重量％的堆积密度在10至150kg / m 3范围内的发泡塑料颗粒，C ）1至50重量％的选自氨基树脂，酚醛树脂，具有至少两个异氰酸酯基的有机异氰酸酯或其混合物，任选与固化剂的粘合剂的粘合剂，以及D）0至68重量％ 的添加剂，其中组分B）或原始可发泡塑料颗粒在膨胀之前，期间或之后用至少一种涂料涂覆。

公开(公告)号：US20140302288A1

公开(公告)日：2014-10-09

申请号：US14230295

申请日：2014-03-31

Applicant: BASF SE

Inventor： Stephan Weinkötz ,  Matthias Schade ,  Jens Assmann ,  Matus Joscäk ,  Tomas Joscäk ,  Clemens Schmidberger ,  Alejandro Lopez Martinez-conde

IPC: D21J1/08 ,  B29D7/01

CPC classification number: D21J1/08 ,  B27N1/02 ,  B27N1/0263 ,  B29B7/007 ,  B29B7/78 ,  B29C43/305 ,  B29D7/01 ,  Y10T428/24802 ,  Y10T428/2495

Abstract: The present invention relates to a method for the production of a particle based element, in particular a particle board or fiber board, wherein particles (2) are dispersed in a dispersing section (5) to form a particle mass (15), and a modification substance (13) is provided modifying the properties of the particle mass (15), such that particles (2) with accordingly modified properties are arranged in at least one predetermined region of the particle mass (15). The modification substance (13) is injected into the particles (2) before the particles (2) form the particle mass (15), wherein the modification substance (13) is injected into the particles (2) in an injection direction, which is inclined with respect to the flow direction (200) of the particle stream at the injection location. The invention further relates to an apparatus (1) for the production of a particle based element, a particle based element, and a further method for the production of a particle based element.

Abstract translation: 本发明涉及一种用于制造颗粒基元件，特别是颗粒板或纤维板的方法，其中颗粒（2）分散在分散部分（5）中以形成颗粒块（15），并且 提供修饰物质（13），其改变粒子质量（15）的性质，使得具有相应变化特性的颗粒（2）排列在颗粒物质（15）的至少一个预定区域中。 在颗粒（2）形成颗粒物质（15）之前，将改性物质（13）注射到颗粒（2）中，其中将改性物质（13）沿注射方向注入颗粒（2） 相对于喷射位置处的颗粒物流的流动方向（200）倾斜。 本发明还涉及一种用于生产基于颗粒的元件，基于粒子的元件的装置（1），以及用于生产颗粒基元素的另外的方法。