公开(公告)号：US3892906A

公开(公告)日：1975-07-01

申请号：US37543873

申请日：1973-07-02

申请人： COTTON INC

发明人： SWIDLER RONALD ,  SANDERSON WILLIAM A ,  MUELLER WILLIAM A

IPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  C09K3/28

CPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  Y10S428/921 ,  Y10T442/2689 ,  Y10T442/2762 ,  Y10T442/277

摘要： Fibrous material such as cotton cloth is simultaneously rendered flame retardant and imparted improved dimensional stability by treating the material with cyanamide and at least one phosphonic acid represented by the structural formula:

wherein R1 represents a divalent organic radical such as methylene or ethylene, X represents a covalent bond, -POOR3- or CO-; and R2 and R3 represent a monovalent radical such as hydrogen or methyl. Mixtures of these phosphonic acids with other phosphonic acids such as methyl phosphonic acid can give particularly advantageous results. Durability of the flame retardancy to repeated hard water washing may be improved through a subsequent treatment with additional cyanamide, with N-methylol compounds, or by methylation with diazomethane. Durable press properties of cellulosic textiles are also improved by the subsequent treatment with additional cyanamide. A particularly high degree of flame retardancy is imparted to mercerized cotton cloth.

摘要翻译： 纤维材料如棉布同时呈阻燃性，并通过用氨基氰和至少一种由结构式表示的膦酸处理该材料而赋予改善的尺寸稳定性：其中R 1表示二价 有机基团如亚甲基或亚乙基，X表示共价键，-POOR 3 - 或-CO-; 并且R 2和R 3表示一价基团如氢或甲基。 这些膦酸与其它膦酸如甲基膦酸的混合物可以得到特别有利的结果。 通过随后用另外的氰胺，与N-羟甲基化合物进行处理，或通过用重氮甲烷甲基化，可以改善阻燃性对重复硬水洗涤的耐久性。 纤维素纺织品的耐久压榨性能也通过随后用另外的氰胺处理而改善。 特别高度的阻燃性赋予丝光棉布。

公开(公告)号：US3874912A

公开(公告)日：1975-04-01

申请号：US37543973

申请日：1973-07-02

申请人： COTTON INC

发明人： SWIDLER RONALD ,  SANDERSON WILLIAM A ,  MUELLER WILLIAM A

IPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  C09K3/28

CPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  Y10S428/921 ,  Y10T442/2689 ,  Y10T442/2762 ,  Y10T442/277

摘要： WHEREIN R1 represents a monovalent radical such as hydrogen or methoxy and R2 represents a monovalent radical such as hydrogen or methyl. Durability of the flame retardancy to repeated hard water washing may be improved through a subsequent treatment with N-methylol compounds or with additional cyanamide or by methylation with diazomethane. Dimensional stability and durable press properties of cellulosic textiles are also improved by the subsequent treatment with additional cyanamide. A particularly high degree of flame retardancy is imparted to mercerized cotton cloth.

Fibrous material such as cotton cloth is rendered flame retardant by treating the material with cyanamide and at least one phosphonic acid represented by the structural formula:

摘要翻译： 纤维材料如棉布通过用氨基氰和至少一种由结构式表示的膦酸处理该材料而被阻燃：

公开(公告)号：US3897584A

公开(公告)日：1975-07-29

申请号：US37544073

申请日：1973-07-02

申请人： COTTON INC

发明人： SWIDLER RONALD ,  SANDERSON WILLIAM A ,  MUELLER WILLIAM A

IPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  D06M15/64 ,  C09B5/18

CPC分类号： D06M13/288 ,  D06M15/433 ,  D06M15/673 ,  Y10S428/921 ,  Y10T442/2689 ,  Y10T442/2762 ,  Y10T442/277

摘要： Fibrous material such as cotton cloth is rendered flame retardant by treating the material with cyanamide and at least one halomethyl phosphonic acid represented by the structural formula:

wherein R1 represents a monovalent radical such as chloro or bromo and R2 represents a monovalent radical such as hydrogen or methyl. Durability of the flame retardancy to repeated hard water washing may be improved through a subsequent treatment with Nmethylol compounds such as methylolated melamine precondensate. A particularly high degree of flame retardancy is imparted to mercerized cotton cloth.

摘要翻译： 纤维材料如棉布通过用氨基氰处理该材料和至少一种由以下结构式表示的卤代甲基膦酸来形成阻燃剂：HOOH | PARALLEL R1-CP ANGLE | HOR2其中R1表示一价基团如氯或溴， R2表示一价基团，例如氢或甲基。 通过随后用N-羟甲基化合物如羟甲基化三聚氰胺预缩合物进行处理可以改善阻燃性对重复的硬水洗涤的耐久性。 特别高度的阻燃性赋予丝光棉布。