公开(公告)号：US20040127587A1

公开(公告)日：2004-07-01

申请号：US10688412

申请日：2003-10-16

Applicant: ConocoPhillips Company

Inventor： Rafael L. Espinoza ,  Kandaswamy Jothimurugesan ,  Yaming Jin

IPC: C07C027/06

CPC classification number: C10G2/332 ,  B01J21/04 ,  B01J23/74 ,  B01J23/75 ,  B01J23/8913 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207

Abstract: A method is provided for forming a highly active Fischer-Tropsch catalyst using boehmite having a particular crystallite size. In this method, a support material comprising boehmite is contacted with a catalytic metal-containing compound to form a catalyst precursor. The boehmite is selected to have an average crystallite size in the range of from about 6 nanometers (nm) to about 30 nm. An alternate embodiment uses a mixture of boehmites with various average crystallite sizes in the range of from about 4 nm to about 30 nm, differing by at least by 1 nm. Subsequently, the catalyst precursor is calcined to convert the boehmite to a stabilized aluminum oxide structure, thereby forming a catalyst support having a good attrition resistance and a relatively high hydrothermal stability.

Abstract translation: 提供了使用具有特定微晶尺寸的勃姆石形成高活性费 - 托催化剂的方法。 在该方法中，将包含勃姆石的载体材料与含催化金属的化合物接触以形成催化剂前体。 勃姆石被选择为具有在约6纳米（nm）至约30nm范围内的平均微晶尺寸。 替代实施例使用具有在约4nm至约30nm范围内的各种平均微晶尺寸的勃氏混合物，至少不同于1nm。 随后，将催化剂前体煅烧以将勃姆石转化为稳定的氧化铝结构，从而形成具有良好耐磨性和较高水热稳定性的催化剂载体。

公开(公告)号：US20040127586A1

公开(公告)日：2004-07-01

申请号：US10687140

申请日：2003-10-16

Applicant: ConocoPhillips Company

Inventor： Yaming Jin ,  Rafael L. Espinoza ,  Nithya Srinivasan ,  Olga P. Ionkina

IPC: B01J023/08 ,  C07C027/06

CPC classification number: C10G2/332 ,  B01J21/04 ,  B01J21/06 ,  B01J21/066 ,  B01J23/02 ,  B01J23/06 ,  B01J23/08 ,  B01J23/10 ,  B01J23/26 ,  B01J23/34 ,  B01J23/462 ,  B01J23/70 ,  B01J23/74 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/1014 ,  B01J35/1019 ,  B01J35/1038 ,  B01J35/1061 ,  B01J37/0207 ,  B01J37/10 ,  C01F7/021 ,  C01F7/448 ,  C01P2002/72 ,  C01P2004/04 ,  C01P2006/13 ,  C01P2006/14 ,  C01P2006/16 ,  C01P2006/37 ,  C10G2/333

Abstract: This invention relates to methods for making a stabilized transition alumina of enhanced hydrothermal stability, which include the introduction of at least one structural stabilizer; a steaming step before or after the introduction step, wherein steaming is effective in transforming a transition alumina at least partially to boehmite and/or pseudoboehmite; and a calcining step to create a stabilized transition alumina. The combination of the structural stabilizer and the steaming step is believed to impart high hydrothermal stability to the alumina crystal lattice. Particularly preferred structural stabilizers include boron, cobalt, and zirconium. The stabilized transition alumina is useful as a catalyst support for high water partial pressure environments, and is particularly useful for making a catalyst having improved hydrothermal stability. The invention more specifically discloses Fischer-Tropsch catalysts and processes for the production of hydrocarbons from synthesis gas.

Abstract translation: 本发明涉及制备具有增强的水热稳定性的稳定的转变氧化铝的方法，其包括引入至少一种结构稳定剂; 在引入步骤之前或之后的蒸汽步骤，其中蒸汽有效地将过渡氧化铝至少部分转化为勃姆石和/或假勃姆石; 和煅烧步骤以产生稳定的过渡氧化铝。 认为结构稳定剂和蒸汽步骤的组合被赋予氧化铝晶格高的水热稳定性。 特别优选的结构稳定剂包括硼，钴和锆。 稳定的过渡氧化铝可用作高水分分压环境的催化剂载体，并且特别可用于制备具有改善的水热稳定性的催化剂。 本发明更具体地公开了费 - 托催化剂和从合成气生产烃的方法。

公开(公告)号：US20040127352A1

公开(公告)日：2004-07-01

申请号：US10687017

申请日：2003-10-16

Applicant: ConocoPhillips Company

Inventor： Yaming Jin ,  Rafael L. Espinoza

IPC: B01J023/56

CPC classification number: B01J37/03 ,  B01J21/04 ,  B01J23/462 ,  B01J23/74 ,  B01J23/75 ,  B01J37/0207 ,  B01J37/036 ,  C10G2/33 ,  C10G2/331 ,  C10G2/332 ,  C10G2/333

Abstract: Methods are disclosed for preparing hydrothermally-stable structurally-promoted refractory-oxide catalyst supports, which includes mixing precursors of the refractory oxide and of at least one structural promoter and calcining the mixture. The methods feature the incorporation of at least one structural promoter into the lattice of a refractory-oxide material such as alumina. The hydrothermally-stable structurally-promoted refractory-oxide catalyst supports are useful in hydrothermal catalytic processes such as Fischer-Tropsch reactions.

Abstract translation: 公开了用于制备水热稳定的结构促进的耐火氧化物催化剂载体的方法，其包括混合难熔氧化物的前体和至少一种结构促进剂并煅烧该混合物。 该方法的特征在于将至少一种结构促进剂掺入耐火氧化物材料如氧化铝的晶格中。 水热稳定的结构促进耐火氧化物催化剂载体可用于水热催化方法如费 - 托反应。

公开(公告)号：US20040132833A1

公开(公告)日：2004-07-08

申请号：US10686977

申请日：2003-10-16

Applicant: ConocoPhillips Company

Inventor： Rafael L. Espinoza ,  Yaming Jin ,  Kandaswamy Jothimurugesan ,  Nithya Srinivasan

IPC: C07C027/06

CPC classification number: C10G2/33 ,  B01J21/04 ,  B01J23/74 ,  B01J23/75 ,  B01J23/8913 ,  B01J35/023 ,  B01J37/0045 ,  B01J37/0201 ,  B01J37/0205 ,  B01J37/0207 ,  C10G2/331 ,  C10G2/332

Abstract: A hydrothermally-stable catalyst, method for making the same, and process for producing hydrocarbon, wherein the catalyst is used in synthesis gas conversion to hydrocarbons. In one embodiment, the method comprises depositing a compound of a catalytic metal selected from Groups 8, 9, and 10 of the Periodic Table on a support material comprising boehmite to form a composite material; and calcining the composite material to form the catalyst. In other embodiments, the support material comprises synthetic boehmite, natural boehmite, pseudo-boehmite, or combinations thereof.

Abstract translation: 水热稳定催化剂及其制造方法以及烃的制造方法，其中将催化剂用于合成气转化成烃类。 在一个实施方案中，该方法包括将选自周期表第8,9和10族的催化金属的化合物沉积在包含勃姆石的载体材料上以形成复合材料; 并煅烧复合材料以形成催化剂。 在其它实施方案中，载体材料包括合成勃姆石，天然勃姆石，假勃姆石或其组合。