公开(公告)号：US11590481B2

公开(公告)日：2023-02-28

申请号：US17349989

申请日：2021-06-17

Applicant: ExxonMobil Technology and Engineering Company

Inventor： Takayuki Iida ,  Jihad M. Dakka ,  Brandon M. Carcuffe ,  Aaron Peters

IPC: B01J29/74 ,  C07C5/27 ,  C10G45/64 ,  B01J37/04 ,  B01J37/00 ,  B01J37/30 ,  B01J37/08

Abstract: Provided herein are methods for hydroisomerization of a hydrocarbon feedstock comprising contacting the hydrocarbon feedstock with hydrogen and a catalyst to yield a hydrocarbon product having an increase in branched hydrocarbons relative to the hydrocarbon feedstock. The present catalysts comprise a heteroatom-doped Beta zeolite having a trivalent cation as a framework metal oxide, an extra-framework species comprised of cerium and/or cobalt, and from 0.01 to 1.5 wt. % of a group VIII or VIB metal, or a combination thereof.

公开(公告)号：US20250033027A1

公开(公告)日：2025-01-30

申请号：US18784280

申请日：2024-07-25

Applicant: EXXONMOBIL TECHNOLOGY AND ENGINEERING COMPANY

Inventor： Scott WEIGEL ,  Wesley Sattler ,  Allen Burton ,  Keith Hajkowski ,  Ryan Dugan ,  Aaron Peters

IPC: B01J20/26 ,  B01J20/28

Abstract: Crystalline support materials are provided that can serve as supports for polyamines. The support materials have a combination of properties that unexpectedly allows supported polyamines to retain an increased or maximized amount of CO2 sorption capacity after incorporation of substantial amounts of the polyamine on the support material. This combination of properties can include having a high pore volume, a high ratio of mesopore volume to micropore volume, and a sufficiently high acidity. The ability to allow supported amine sorbents to retain additional CO2 sorption capacity is unexpected. Conventionally, even when high pore volume support materials are used to support an amine sorbent, only a limited amount of the amine sorbent can be supported on the support material before substantial losses of sorbent capacity occur relative to the amount of amine sorbent.