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1.发明申请COMPATIBILIZED POLYPROPYLENE HETEROPHASIC COPOLYMER AND POLYLACTIC ACID BLENDS FOR INJECTION MOLDING APPLICATIONS 审中-公开用于注射成型应用的兼容聚丙烯异构共聚物和聚乳酸公开(公告)号：US20150218356A1
公开(公告)日：2015-08-06
申请号：US14686930
申请日：2015-04-15
Applicant: FINA TECHNOLOGY, INC.
Inventor： Fengkui Li , John Ashbaugh , Gabriel Desille , Caroline Schils
IPC: C08L23/14
CPC classification number: C08L23/142 , B29C45/72 , C08K3/34 , C08L23/06 , C08L23/10 , C08L23/14 , C08L23/16 , C08L51/06 , C08L67/04 , C08L2201/06 , C08L2205/025 , C08L2205/03 , C08L2205/08 , C08L2207/02 , C08L2207/04
Abstract: A method of forming a compatibilized polymeric blend may include providing a polyolefin that includes a propylene heterophasic copolymer. The polyolefin may have an ethylene content of at least 10 weight percent based on a total weight of the polyolefin. The method may include melt blending the polyolefin with a polylactic acid and a reactive modifier to form the compatiblized polymeric blend. The reactive modifier may be a glycidyl methacrylate grafted polypropylene (PP-g-GMA). The reactive modified may be produced by contacting a polypropylene, a glycidyl methacrylate, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of PP-g-GMA having a grafting yield in a range from 1 wt. % to 15 wt. %.
Abstract translation: 形成相容的聚合物共混物的方法可以包括提供包含丙烯异相共聚物的聚烯烃。 基于聚烯烃的总重量，聚烯烃可以具有至少10重量％的乙烯含量。 该方法可以包括将聚烯烃与聚乳酸和反应性改性剂熔融共混以形成相容的聚合物共混物。 反应性改性剂可以是甲基丙烯酸缩水甘油酯接枝聚丙烯（PP-g-GMA）。 反应性改性可以通过在适于形成PP-g-GMA的条件下使聚丙烯，甲基丙烯酸缩水甘油酯，多官能丙烯酸酯共聚单体和引发剂接触而制备，所述PP-g-GMA的接枝收率在1wt。 ％至15wt。 ％。
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2.发明授权公开(公告)号：US09034990B2
公开(公告)日：2015-05-19
申请号：US13956514
申请日：2013-08-01
Applicant: FINA TECHNOLOGY, INC.
Inventor： Fengkui Li , John Ashbaugh , Gabriel Desille , Caroline Schils
CPC classification number: C08L23/142 , B29C45/72 , C08K3/34 , C08L23/06 , C08L23/10 , C08L23/14 , C08L23/16 , C08L51/06 , C08L67/04 , C08L2201/06 , C08L2205/025 , C08L2205/03 , C08L2205/08 , C08L2207/02 , C08L2207/04
Abstract: Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article.
Abstract translation: 本文描述了注塑制品及其制备方法。 该方法通常包括提供包含一种或多种丙烯异相共聚物的聚烯烃，所述聚烯烃的乙烯含量为至少10wt。 基于聚烯烃的总重量％; 使聚烯烃与聚乳酸和反应性改性剂接触以形成相容的聚合物共混物，其中反应性改性剂通过在适于形成甲基丙烯酸缩水甘油酯接枝聚丙烯的条件下使聚丙烯，多官能丙烯酸酯共聚单体和引发剂接触来制备 PP-g-GMA），其接枝收率在1wt。 ％至15wt。 ％; 并将相容的聚合物共混物注塑成制品。
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3.发明申请公开(公告)号：US20130317173A1
公开(公告)日：2013-11-28
申请号：US13956514
申请日：2013-08-01
Applicant: FINA TECHNOLOGY, INC.
Inventor： Fengkui Li , John Ashbaugh , Gabriel Desille , Caroline Schils
IPC: C08L23/14
CPC classification number: C08L23/142 , B29C45/72 , C08K3/34 , C08L23/06 , C08L23/10 , C08L23/14 , C08L23/16 , C08L51/06 , C08L67/04 , C08L2201/06 , C08L2205/025 , C08L2205/03 , C08L2205/08 , C08L2207/02 , C08L2207/04
Abstract: Injection molded articles and process of forming the same are described herein. The processes generally include providing a polyolefin including one or more propylene heterophasic copolymers, the polyolefin having an ethylene content of at least 10 wt. % based on the total weight of the polyolefin; contacting the polyolefin with a polylactic acid and a reactive modifier to form a compatiblized polymeric blend, wherein the reactive modifier is produced by contacting a polypropylene, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of a glycidyl methacrylate grafted polypropylene (PP-g-GMA) having a grafting yield in a range from 1 wt. % to 15 wt. %; and injection molding the compatibilized polymeric blend into an article.
Abstract translation: 本文描述了注塑制品及其制备方法。 该方法通常包括提供包含一种或多种丙烯异相共聚物的聚烯烃，所述聚烯烃的乙烯含量为至少10wt。 基于聚烯烃的总重量％; 使聚烯烃与聚乳酸和反应性改性剂接触以形成相容的聚合物共混物，其中反应性改性剂通过在适于形成甲基丙烯酸缩水甘油酯接枝聚丙烯的条件下使聚丙烯，多官能丙烯酸酯共聚单体和引发剂接触来制备 PP-g-GMA），其接枝收率在1wt。 ％至15wt。 ％; 并将相容的聚合物共混物注塑成制品。
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4.发明授权公开(公告)号：US09416264B2
公开(公告)日：2016-08-16
申请号：US14686930
申请日：2015-04-15
Applicant: FINA TECHNOLOGY, INC.
Inventor： Fengkui Li , John Ashbaugh , Gabriel Desille , Caroline Schils
CPC classification number: C08L23/142 , B29C45/72 , C08K3/34 , C08L23/06 , C08L23/10 , C08L23/14 , C08L23/16 , C08L51/06 , C08L67/04 , C08L2201/06 , C08L2205/025 , C08L2205/03 , C08L2205/08 , C08L2207/02 , C08L2207/04
Abstract: A method of forming a compatibilized polymeric blend may include providing a polyolefin that includes a propylene heterophasic copolymer. The polyolefin may have an ethylene content of at least 10 weight percent based on a total weight of the polyolefin. The method may include melt blending the polyolefin with a polylactic acid and a reactive modifier to form the compatiblized polymeric blend. The reactive modifier may be a glycidyl methacrylate grafted polypropylene (PP-g-GMA). The reactive modified may be produced by contacting a polypropylene, a glycidyl methacrylate, a multifunctional acrylate comonomer, and an initiator under conditions suitable for the formation of PP-g-GMA having a grafting yield in a range from 1 wt. % to 15 wt. %.
Abstract translation: 形成相容的聚合物共混物的方法可以包括提供包含丙烯异相共聚物的聚烯烃。 基于聚烯烃的总重量，聚烯烃可以具有至少10重量％的乙烯含量。 该方法可以包括将聚烯烃与聚乳酸和反应性改性剂熔融共混以形成相容的聚合物共混物。 反应性改性剂可以是甲基丙烯酸缩水甘油酯接枝聚丙烯（PP-g-GMA）。 反应性改性可以通过在适于形成PP-g-GMA的条件下使聚丙烯，甲基丙烯酸缩水甘油酯，多官能丙烯酸酯共聚单体和引发剂接触而制备，所述PP-g-GMA的接枝收率在1wt。 ％至15wt。 ％。
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