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1.发明授权Block copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks 失效含有两个内锥形嵌段的单乙烯基芳烃和共轭二烯的嵌段共聚物
公开(公告)号：US5399628A
公开(公告)日：1995-03-21
申请号：US162735
申请日：1993-12-02
IPC分类号： C08F297/02 , C08F297/04
CPC分类号： C08F297/044
摘要： A method for preparing tapered block copolymers in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomer in the presence of a randomizer; (2) an initiator and monovinylaromatic monomer; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; (5) conjugated diene monomer; and (6) a coupling agent; and the polymodal tapered block copolymers prepared thereby. The copolymers are particularly useful neat or in blends for applications such as packaging and food or drink containers which require transparency and good environmental stress crack resistance.
摘要翻译： 在聚合过程中通过顺序加入来制备渐缩嵌段共聚物的方法：（1）引发剂和单乙烯基芳族单体在无规发生剂存在下进行; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和共轭二烯单体的混合物; （5）共轭二烯单体; 和（6）偶联剂; 和由此制备的多模式锥形嵌段共聚物。 共聚物特别适用于需要透明度和良好的耐环境应力开裂性的包装和食品或饮料容器等应用的混合物。
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2.发明授权Blends of copolymers of monovinylarenes and conjugated dienes containing two interior tapered blocks 失效含有两个内锥形嵌段的单乙烯基芳烃和共轭二烯共聚物的共混物
公开(公告)号：US5587425A
公开(公告)日：1996-12-24
申请号：US580227
申请日：1995-12-28
IPC分类号： C08F297/02 , C08F297/04 , C08L25/04 , C08L53/02
CPC分类号： C08F297/044
摘要： A method for preparing blends of a copolymer in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomer in the presence of a randomizer; (2) an initiator and monovinylaromatic monomer; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjuated diene monomers; (5) conjugated diene monomer; and (6) a coupling agent; and the polymodal tapered block copolymers prepared thereby. The copolymers are particularly useful neat or in blends for applications such as packaging and food or drink containers which require transparency and good environmental stress crack resistance.
摘要翻译： 一种在聚合过程中共聚物的共混物的制备方法，该方法是在无规化剂存在下，顺序加入：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和结合二烯单体的混合物; （5）共轭二烯单体; 和（6）偶联剂; 和由此制备的多模式锥形嵌段共聚物。 共聚物特别适用于需要透明度和良好的耐环境应力开裂性的包装和食品或饮料容器等应用的混合物。
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公开(公告)号：US5910546A
公开(公告)日：1999-06-08
申请号：US963964
申请日：1997-11-04
IPC分类号： C08F8/44 , C08F297/02 , C08F297/04 , C08G81/02 , C08L25/04 , C08L25/06 , C08L53/02
CPC分类号： C08L53/02 , C08F297/044 , C08G81/021 , C08G81/022 , C08L25/04 , C08L25/06
摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.
摘要翻译： 一种制备锥形嵌段共聚物的方法，其特别适用于与苯乙烯聚合物的共混物中的共混物组分。 在本发明的第一个实施方案中，共聚物在聚合过程中通过顺序加入来制备：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（4）偶联剂; 以制备多晶型锥形嵌段共聚物。 在本发明的第二个实施方案中，在聚合过程中通过顺序加入来制备渐缩嵌段共聚物：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（5）偶联剂; 以制备多晶型锥形嵌段共聚物。 本发明的共聚物和本发明共聚物与苯乙烯聚合物的共混物特别适用于需要透明度，低蓝，无色度，良好的冲击强度和延展性的包装和食品或饮料容器等应用。
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4.发明授权Conjugated diene/monovinylarene block copolymers with multiple tapered blocks 失效具有多个锥形嵌段的共轭二烯/单乙烯基芳烃嵌段共聚物
公开(公告)号：US5290875A
公开(公告)日：1994-03-01
申请号：US982938
申请日：1992-11-30
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： A method for preparing polymodal tapered block copolymers in a polymerization process by sequentially charging: (a) an initiator and monovinylaromatic monomers in the presence of a randomizer; (b) an initiator and monovinylaromatic monomers; (c) a mixture of monovinylaromatic and conjugated diene monomers; (d) a mixture of monovinylaromatic and conjugated diene monomers; (e) an initiator and monovinylaromatic monomers; (f) a mixture of monovinylaromatic and conjugated diene monomers; (g) a mixture of monovinylaromatic and conjugated diene monomers; (h) conjugated diene monomers; and (i) a coupling agent. The copolymers are particularly useful for packaging applications which require good environmental stress crack resistance.
摘要翻译： 一种在聚合过程中制备多嵌段渐缩嵌段共聚物的方法，该方法是通过在无规化剂的存在下依次装入：（a）引发剂和单乙烯基芳族单体; （b）引发剂和单乙烯基芳族单体; （c）单乙烯基芳族化合物和共轭二烯单体的混合物; （d）单乙烯基芳族化合物和共轭二烯单体的混合物; （e）引发剂和单乙烯基芳族单体; （f）单乙烯基芳族化合物和共轭二烯单体的混合物; （g）单乙烯基芳族化合物和共轭二烯单体的混合物; （h）共轭二烯单体; 和（i）偶联剂。 共聚物特别适用于需要良好的耐环境应力开裂性的包装应用。
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公开(公告)号：US06265485B1
公开(公告)日：2001-07-24
申请号：US08968001
申请日：1997-11-12
IPC分类号： C08F29704
CPC分类号： C08L53/02 , C08F297/044 , C08G81/021 , C08G81/022 , C08L25/04 , C08L25/06 , C08L2666/24 , C08L91/06 , C08L2666/04
摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.
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公开(公告)号：US06265484B1
公开(公告)日：2001-07-24
申请号：US08966458
申请日：1997-11-07
IPC分类号： C08F29704
CPC分类号： C08L53/02 , C08F297/044 , C08G81/021 , C08G81/022 , C08L25/04 , C08L25/06 , C08L2666/24 , C08L2666/04
摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.
摘要翻译： 一种制备锥形嵌段共聚物的方法，其特别适用于与苯乙烯聚合物的共混物中的共混物组分。 在本发明的第一个实施方案中，共聚物在聚合过程中通过顺序加入来制备：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（4）偶联剂; 以制备多晶型锥形嵌段共聚物。 在本发明的第二个实施方案中，在聚合过程中通过顺序加入来制备渐缩嵌段共聚物：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（5）偶联剂; 以制备多晶型锥形嵌段共聚物。 本发明的共聚物和本发明共聚物与苯乙烯聚合物的共混物特别适用于需要透明度，低蓝，无色度，良好的冲击强度和延展性的包装和食品或饮料容器等应用。
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7.发明授权Block copolymers of monovinylarenes and conjugated dienes and preparation thereof 失效单乙烯基芳烃和共轭二烯的嵌段共聚物及其制备
公开(公告)号：US5705569A
公开(公告)日：1998-01-06
申请号：US651082
申请日：1996-05-22
申请人： George A. Moczygemba , Larry L. Nash , William J. Trepka , Craig D. DePorter , Nathan E. Stacy , Ralph C. Farrar , Charles M. Selman
发明人： George A. Moczygemba , Larry L. Nash , William J. Trepka , Craig D. DePorter , Nathan E. Stacy , Ralph C. Farrar , Charles M. Selman
IPC分类号： C08F297/04 , C08L53/02
CPC分类号： C08F297/044
摘要： A method for preparing resinous polymodal monovinylarene-conjugated diene block copolymers and polymers produced thereby are provided. The method comprises sequentially contacting under polymerization conditions: (a) a monovinylarene monomer and initiator; (b) initiator and a monovinylarene monomer; (c) a sequence of at least two charges selected from the group consisting of (i) initiator and a monovtnylarene monomer, (ii) a mixture of monovtnylarene monomer and conjugated diene monomor, (iii) a conjugated diene monomer, (iv) a monovinylarene monomer; (d) a coupling agent; wherein the sequence of at least two charges in step (c) can be made in any order. In a preferred embodiment, at least three Initiator charges are provided. In another preferred embodiment, at least three monovinylarene charges precede the first charge containing conjugated diene. In another preferred embodiment, at least four monovinylarene charges precede the first charge containing conjugated diene.
摘要翻译： 提供了一种制备树脂多聚单乙烯基芳烃 - 共轭二烯嵌段共聚物和由此制备的聚合物的方法。 该方法包括在聚合条件下依次接触：（a）单乙烯基芳烃单体和引发剂; （b）引发剂和单乙烯基芳烃单体; （c）选自（i）引发剂和单甲苯基芳烃单体的至少两种电荷的序列，（ii）单甲苯基芳烃单体和共轭二烯单体的混合物，（iii）共轭二烯单体，（iv） 单乙烯基芳烃单体; （d）偶联剂; 其中步骤（c）中的至少两个电荷的顺序可以以任何顺序制成。 在优选实施方案中，提供至少三种引发剂电荷。 在另一个优选实施方案中，至少三种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。 在另一个优选的实施方案中，至少四种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。
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8.发明授权Block copolymers of monovinylarenes and conjugated dienes and preparation thereof 失效单乙烯基芳烃和共轭二烯的嵌段共聚物及其制备
公开(公告)号：US5436298A
公开(公告)日：1995-07-25
申请号：US308240
申请日：1994-09-19
申请人： George A. Moczygemba , Larry L. Nash , William J. Trepka , Craig D. DePorter , Nathan E. Stacy , Ralph C. Farrar , Charles M. Selman
发明人： George A. Moczygemba , Larry L. Nash , William J. Trepka , Craig D. DePorter , Nathan E. Stacy , Ralph C. Farrar , Charles M. Selman
IPC分类号： C08F297/04
CPC分类号： C08F297/044
摘要： A method for preparing resinous polymodal monovinylarene-conjugated diene block copolymers and polymers produced thereby are provided. The method comprises sequentially contacting under polymerization conditions:(a) a monovinylarene monomer and initiator;(b) initiator and a monovinylarene monomer;(c) a sequence of at least two charges selected from the group consisting of (i) initiator and a monovinylarene monomer, (ii) a mixture of monovinylarene monomer and conjugated diene monomer, (iii) a conjugated diene monomer, (iv) a monovinylarene monomer;(d) s coupling agent;wherein the sequence of at least two charges in step (c) can be made in any order. In a preferred embodiment, at least three initiator charges are provided. In another preferred embodiment, at east three monovinylarene charges precede the first charge containing conjugated diene. In another preferred embodiment, at least four monovinylarene charges precede the first charge containing conjugated diene.
摘要翻译： 提供了一种制备树脂多聚单乙烯基芳烃 - 共轭二烯嵌段共聚物和由此制备的聚合物的方法。 该方法包括在聚合条件下依次接触：（a）单乙烯基芳烃单体和引发剂; （b）引发剂和单乙烯基芳烃单体; （c）选自（i）引发剂和单乙烯基芳烃单体的至少两种电荷的序列，（ii）单乙烯基芳烃单体和共轭二烯单体的混合物，（iii）共轭二烯单体，（iv） 单乙烯基芳烃单体; （d）偶联剂; 其中步骤（c）中的至少两个电荷的顺序可以以任何顺序制成。 在优选的实施方案中，提供至少三种引发剂电荷。 在另一个优选的实施方案中，在东部三乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。 在另一个优选的实施方案中，至少四种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。
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9.发明授权Method for stabilizing monovinylarene/conjugated diene copolymers and a method for preparing a stabilizing mixture 失效用于稳定单乙烯基芳烃/共轭二烯共聚物的方法和制备稳定化混合物的方法
公开(公告)号：US5422389A
公开(公告)日：1995-06-06
申请号：US192000
申请日：1994-02-04
申请人： William J. Trepka , Larry L. Nash , John R. Bohannan , Nathan E. Stacy , George A. Moczygemba , Craig D. DePorter , Luis E. Reyes , Tad L. Olson
发明人： William J. Trepka , Larry L. Nash , John R. Bohannan , Nathan E. Stacy , George A. Moczygemba , Craig D. DePorter , Luis E. Reyes , Tad L. Olson
CPC分类号： C08K5/005 , C07F9/025 , C08J3/22 , C08J2309/06
摘要： A process for stabilizing polymers is provided comprising:(1) contacting at least one hindered phenolic compound and an organic phosphite to form a stabilizing mixture,wherein said contacting is at a temperature sufficient to at least partially dissolve said hindered phenolic compound,wherein said stabilizing mixture is essentially free of organic solvent; and(2) contacting said stabilizing mixture and a polymeric composition comprising a monovinylarene/conjugated diene copolymer;wherein said organic phosphite and said at least one hindered phenolic compound are present in step (2) in an effective amount sufficient to stabilize said polymeric composition. In accordance with another aspect of this invention a method for preparing a stabilizing mixture essentially free of organic solvent is provided.
摘要翻译： 提供了一种用于稳定聚合物的方法，包括：（1）使至少一种受阻酚化合物和有机亚磷酸酯接触以形成稳定化混合物，其中所述接触处于足以至少部分溶解所述受阻酚类化合物的温度，其中所述稳定化 混合物基本上不含有机溶剂; 和（2）使所述稳定化混合物和包含单乙烯基芳烃/共轭二烯共聚物的聚合物组合物接触; 其中所述有机亚磷酸酯和所述至少一种受阻酚化合物以足以稳定所述聚合物组合物的有效量存在于步骤（2）中。 根据本发明的另一方面，提供了一种制备基本上不含有机溶剂的稳定混合物的方法。
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公开(公告)号：US5545690A
公开(公告)日：1996-08-13
申请号：US478306
申请日：1995-06-07
IPC分类号： C08F8/44 , C08F297/02 , C08F297/04 , C08G81/02 , C08L25/04 , C08L25/06 , C08L53/02
CPC分类号： C08L53/02 , C08F297/044 , C08G81/021 , C08G81/022 , C08L25/04 , C08L25/06
摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the Invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.
摘要翻译： 一种制备锥形嵌段共聚物的方法，其特别适用于与苯乙烯聚合物的共混物中的共混物组分。 在本发明的第一个实施方案中，共聚物在聚合过程中通过顺序加入来制备：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（4）偶联剂; 以制备多晶型锥形嵌段共聚物。 在本发明的第二个实施方案中，在聚合过程中通过顺序加入来制备渐缩嵌段共聚物：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（5）偶联剂; 以制备多晶型锥形嵌段共聚物。 本发明的共聚物和本发明共聚物与苯乙烯聚合物的共混物特别适用于需要透明度，低蓝，无色度，良好的冲击强度和延展性的包装和食品或饮料容器等应用。
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