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    Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
    2.
    发明授权
    Block copolymers of monovinylarenes and conjugated dienes and preparation thereof 失效
    单乙烯基芳烃和共轭二烯的嵌段共聚物及其制备

    公开(公告)号：US5705569A

    公开(公告)日：1998-01-06

    申请号：US651082

    申请日：1996-05-22

    申请人： George A. Moczygemba ,  Larry L. Nash ,  William J. Trepka ,  Craig D. DePorter ,  Nathan E. Stacy ,  Ralph C. Farrar ,  Charles M. Selman

    发明人： George A. Moczygemba ,  Larry L. Nash ,  William J. Trepka ,  Craig D. DePorter ,  Nathan E. Stacy ,  Ralph C. Farrar ,  Charles M. Selman

    IPC分类号： C08F297/04 ,  C08L53/02

    CPC分类号： C08F297/044

    摘要： A method for preparing resinous polymodal monovinylarene-conjugated diene block copolymers and polymers produced thereby are provided. The method comprises sequentially contacting under polymerization conditions: (a) a monovinylarene monomer and initiator; (b) initiator and a monovinylarene monomer; (c) a sequence of at least two charges selected from the group consisting of (i) initiator and a monovtnylarene monomer, (ii) a mixture of monovtnylarene monomer and conjugated diene monomor, (iii) a conjugated diene monomer, (iv) a monovinylarene monomer; (d) a coupling agent; wherein the sequence of at least two charges in step (c) can be made in any order. In a preferred embodiment, at least three Initiator charges are provided. In another preferred embodiment, at least three monovinylarene charges precede the first charge containing conjugated diene. In another preferred embodiment, at least four monovinylarene charges precede the first charge containing conjugated diene.

    摘要翻译： 提供了一种制备树脂多聚单乙烯基芳烃 - 共轭二烯嵌段共聚物和由此制备的聚合物的方法。 该方法包括在聚合条件下依次接触：（a）单乙烯基芳烃单体和引发剂; （b）引发剂和单乙烯基芳烃单体; （c）选自（i）引发剂和单甲苯基芳烃单体的至少两种电荷的序列，（ii）单甲苯基芳烃单体和共轭二烯单体的混合物，（iii）共轭二烯单体，（iv） 单乙烯基芳烃单体; （d）偶联剂; 其中步骤（c）中的至少两个电荷的顺序可以以任何顺序制成。 在优选实施方案中，提供至少三种引发剂电荷。 在另一个优选实施方案中，至少三种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。 在另一个优选的实施方案中，至少四种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。

    Block copolymers of monovinylarenes and conjugated dienes and preparation thereof
    3.
    发明授权
    Block copolymers of monovinylarenes and conjugated dienes and preparation thereof 失效
    单乙烯基芳烃和共轭二烯的嵌段共聚物及其制备

    公开(公告)号：US5436298A

    公开(公告)日：1995-07-25

    申请号：US308240

    申请日：1994-09-19

    申请人： George A. Moczygemba ,  Larry L. Nash ,  William J. Trepka ,  Craig D. DePorter ,  Nathan E. Stacy ,  Ralph C. Farrar ,  Charles M. Selman

    发明人： George A. Moczygemba ,  Larry L. Nash ,  William J. Trepka ,  Craig D. DePorter ,  Nathan E. Stacy ,  Ralph C. Farrar ,  Charles M. Selman

    IPC分类号： C08F297/04

    CPC分类号： C08F297/044

    摘要： A method for preparing resinous polymodal monovinylarene-conjugated diene block copolymers and polymers produced thereby are provided. The method comprises sequentially contacting under polymerization conditions:(a) a monovinylarene monomer and initiator;(b) initiator and a monovinylarene monomer;(c) a sequence of at least two charges selected from the group consisting of (i) initiator and a monovinylarene monomer, (ii) a mixture of monovinylarene monomer and conjugated diene monomer, (iii) a conjugated diene monomer, (iv) a monovinylarene monomer;(d) s coupling agent;wherein the sequence of at least two charges in step (c) can be made in any order. In a preferred embodiment, at least three initiator charges are provided. In another preferred embodiment, at east three monovinylarene charges precede the first charge containing conjugated diene. In another preferred embodiment, at least four monovinylarene charges precede the first charge containing conjugated diene.

    摘要翻译： 提供了一种制备树脂多聚单乙烯基芳烃 - 共轭二烯嵌段共聚物和由此制备的聚合物的方法。 该方法包括在聚合条件下依次接触：（a）单乙烯基芳烃单体和引发剂; （b）引发剂和单乙烯基芳烃单体; （c）选自（i）引发剂和单乙烯基芳烃单体的至少两种电荷的序列，（ii）单乙烯基芳烃单体和共轭二烯单体的混合物，（iii）共轭二烯单体，（iv） 单乙烯基芳烃单体; （d）偶联剂; 其中步骤（c）中的至少两个电荷的顺序可以以任何顺序制成。 在优选的实施方案中，提供至少三种引发剂电荷。 在另一个优选的实施方案中，在东部三乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。 在另一个优选的实施方案中，至少四种单乙烯基芳烃电荷位于含有共轭二烯的第一电荷之前。

    Conjugated diene/monovinylarene block copolymers blends
    4.
    发明授权
    Conjugated diene/monovinylarene block copolymers blends 有权
    共轭二烯/单乙烯基芳烃嵌段共聚物共混物

    公开(公告)号：US06444755B1

    公开(公告)日：2002-09-03

    申请号：US09576879

    申请日：2000-05-22

    申请人： Craig D. DePorter ,  Nathan E. Stacy ,  George A. Moczygemba

    发明人： Craig D. DePorter ,  Nathan E. Stacy ,  George A. Moczygemba

    IPC分类号： C08F29707

    CPC分类号： C08F297/044 ,  C08L53/02 ,  C08L2666/04

    摘要： A block copolymer comprising at least three consecutive conjugated diene/monovinylarene tapered blocks is provided. Other aspects of this invention include a polymerization process for preparing the block copolymer and polymer blends comprising the block copolymer. The block copolymer and polymer blends exhibit excellent optical and mechanical properties.

    摘要翻译： 提供包含至少三个连续的共轭二烯/单乙烯基芳烃渐变嵌段的嵌段共聚物。 本发明的其它方面包括制备嵌段共聚物的聚合方法和包含嵌段共聚物的聚合物共混物。 嵌段共聚物和聚合物共混物表现出优异的光学和机械性能。

    Block copolymers of monovinylaromatic and conjugated diene monomers
    8.
    发明授权
    Block copolymers of monovinylaromatic and conjugated diene monomers 失效
    单乙烯基芳族和共轭二烯单体的嵌段共聚物

    公开(公告)号：US5438103A

    公开(公告)日：1995-08-01

    申请号：US216725

    申请日：1994-03-23

    申请人： Craig D. DePorter ,  Ralph C. Farrar, Jr. ,  Nathan E. Stacy ,  George A. Moczygemba

    发明人： Craig D. DePorter ,  Ralph C. Farrar, Jr. ,  Nathan E. Stacy ,  George A. Moczygemba

    IPC分类号： C08F297/04

    CPC分类号： C08F297/044

    摘要： A method for preparing block copolymers from which can be made transparent blue articles comprising sequentially charging under polymerization conditions at least one monovinylaromatic monomer and at least one conjugated diene monomer, wherein at least the first monomer charge is a monovinylaromatic monomer charge polymerized in the presence of an initiator; wherein at least one other charge polymerized in the presence of an initiator is a monomer selected from the group of conjugated diene monomers and mixtures of monovinylaromatic and conjugated diene monomers; wherein the final monomer charge is a conjugated diene charge; and thereafter charging the reaction mixture with at least one coupling agent. The invention copolymers are particularly useful for applications such as packaging, display devices, toys and decorative items in which transparent blue appearance is desired without significant compromise of other physical and mechanical properties.

    摘要翻译： 一种制备嵌段共聚物的方法，可从其制备透明蓝色物品，其包括在聚合条件下至少一种单乙烯基芳族单体和至少一种共轭二烯单体依次充电，其中至少第一单体电荷是在存在下电荷聚合的单乙烯基芳族单体 发起者 其中在引发剂存在下聚合的至少一种其它电荷是选自共轭二烯单体和单乙烯基芳族和共轭二烯单体的混合物的单体; 其中最终的单体电荷是共轭二烯电荷; 然后用至少一种偶联剂装入反应混合物。 本发明共聚物特别适用于诸如包装，显示装置，玩具和装饰物品之类的应用，其中需要透明蓝色外观，而不会对其他物理和机械性能造成重大损害。

    Tapered block copolymers of monivinylarenes and conjugated dienes
    9.
    发明授权
    Tapered block copolymers of monivinylarenes and conjugated dienes 失效
    单乙烯基芳烃和共轭二烯的嵌段嵌段共聚物

    公开(公告)号：US5910546A

    公开(公告)日：1999-06-08

    申请号：US963964

    申请日：1997-11-04

    申请人： William J. Trepka ,  George A. Moczygemba ,  Nathan E. Stacy ,  Ralph C. Farrar, Jr.

    发明人： William J. Trepka ,  George A. Moczygemba ,  Nathan E. Stacy ,  Ralph C. Farrar, Jr.

    IPC分类号： C08F8/44 ,  C08F297/02 ,  C08F297/04 ,  C08G81/02 ,  C08L25/04 ,  C08L25/06 ,  C08L53/02

    CPC分类号： C08L53/02 ,  C08F297/044 ,  C08G81/021 ,  C08G81/022 ,  C08L25/04 ,  C08L25/06

    摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.

    摘要翻译： 一种制备锥形嵌段共聚物的方法，其特别适用于与苯乙烯聚合物的共混物中的共混物组分。 在本发明的第一个实施方案中，共聚物在聚合过程中通过顺序加入来制备：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（4）偶联剂; 以制备多晶型锥形嵌段共聚物。 在本发明的第二个实施方案中，在聚合过程中通过顺序加入来制备渐缩嵌段共聚物：（1）引发剂和单乙烯基芳族单体; （2）引发剂和单乙烯基芳族单体; （3）单乙烯基芳族化合物和共轭二烯单体的混合物; （4）单乙烯基芳族化合物和共轭二烯单体的混合物; 和（5）偶联剂; 以制备多晶型锥形嵌段共聚物。 本发明的共聚物和本发明共聚物与苯乙烯聚合物的共混物特别适用于需要透明度，低蓝，无色度，良好的冲击强度和延展性的包装和食品或饮料容器等应用。

    Tapered block copolymers of monovinylarenes and conjugated dienes
    10.
    发明授权
    Tapered block copolymers of monovinylarenes and conjugated dienes 失效

    公开(公告)号：US06265485B1

    公开(公告)日：2001-07-24

    申请号：US08968001

    申请日：1997-11-12

    申请人： William J. Trepka ,  George A. Moczygemba ,  Nathan E. Stacy ,  Ralph C. Farrar, Jr.

    发明人： William J. Trepka ,  George A. Moczygemba ,  Nathan E. Stacy ,  Ralph C. Farrar, Jr.

    IPC分类号： C08F29704

    CPC分类号： C08L53/02 ,  C08F297/044 ,  C08G81/021 ,  C08G81/022 ,  C08L25/04 ,  C08L25/06 ,  C08L2666/24 ,  C08L91/06 ,  C08L2666/04

    摘要： A method for preparing tapered block copolymers which are particularly useful for blend components in blends with polymers of styrene. In the first embodiment of this invention the copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; and (4) a coupling agent; to produce a polymodal tapered block copolymer. In a second embodiment of the invention tapered block copolymers are prepared in a polymerization process by sequentially charging: (1) an initiator and monovinylaromatic monomers in the presence of a randomizer; (2) an initiator and monovinylaromatic monomers; (3) a mixture of monovinylaromatic and conjugated diene monomers; (4) a mixture of monovinylaromatic and conjugated diene monomers; and (5) a coupling agent; to produce a polymodal tapered block copolymer. The invention copolymers and blends of the invention copolymers with polymers of styrene are particularly useful for applications such as packaging and food or drink containers which require transparency, low blueness, colorlessness, good impact strength and ductility.