公开(公告)号：US11742520B2

公开(公告)日：2023-08-29

申请号：US17246861

申请日：2021-05-03

Applicant: Greatbatch Ltd.

Inventor： Robert S. Rubino ,  Joseph M. Lehnes ,  Marcus J. Palazzo ,  David M. Spillman ,  Ho-Chul Yun

IPC: H01M10/0567 ,  H01M10/0569 ,  H01M10/0568 ,  H01M4/134 ,  H01M4/62 ,  H01M10/0525 ,  H01M4/54 ,  H01M4/02

CPC classification number: H01M10/0567 ,  H01M4/134 ,  H01M4/54 ,  H01M4/625 ,  H01M10/0525 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2004/027 ,  H01M2004/028 ,  H01M2300/0034

Abstract: An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, dibenzyl carbonate (DBC), lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably DBC is present in an amount ranging from about 0.005 moles (M) to about 0.25M, LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFx mixture cells, and Li-SVO/CFx sandwich cathode primary electrochemical cells.

公开(公告)号：US11735773B1

公开(公告)日：2023-08-22

申请号：US17200975

申请日：2021-03-15

Applicant: Greatbatch Ltd.

Inventor： Robert S. Rubino ,  Joseph M. Lehnes ,  Marcus J. Palazzo ,  David M. Spillman ,  Ho-Chul Yun

IPC: H01M10/0567 ,  H01M4/38 ,  H01M4/54 ,  H01M10/052 ,  H01M4/583 ,  H01M4/36 ,  H01M4/136 ,  H01M4/134 ,  H01M10/0568 ,  H01M10/0569 ,  H01M4/587 ,  H01M4/131

CPC classification number: H01M10/0567 ,  H01M4/131 ,  H01M4/134 ,  H01M4/136 ,  H01M4/364 ,  H01M4/382 ,  H01M4/54 ,  H01M4/587 ,  H01M4/5835 ,  H01M10/052 ,  H01M10/0568 ,  H01M10/0569 ,  H01M2300/0037

Abstract: An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFx mixture cells, and Li-SVO/CFx sandwich cathode primary electrochemical cells.

公开(公告)号：US20210359343A1

公开(公告)日：2021-11-18

申请号：US17246861

申请日：2021-05-03

Applicant: Greatbatch Ltd.

Inventor： Robert S. Rubino ,  Joseph M. Lehnes ,  Marcus J. Palazzo ,  David M. Spillman ,  Ho-Chul Yun

IPC: H01M10/0567 ,  H01M10/0569 ,  H01M10/0568 ,  H01M4/134 ,  H01M4/54 ,  H01M4/62 ,  H01M10/0525

Abstract: An electrochemical cell having a casing housing an electrode assembly of a separator residing between a lithium anode and a cathode comprising silver vanadium oxide and fluorinated carbon is described. The electrode assembly is activated with a nonaqueous electrolyte comprising a lithium salt dissolved in a solvent system of propylene carbonate mixed with 1,2-dimethoxyethane, dibenzyl carbonate (DBC), lithium bis(oxalato)borate (LiBOB), and fluoroethylene carbonate (FEC). Preferably DBC is present in an amount ranging from about 0.005 moles (M) to about 0.25M, LiBOB is present in an amount ranging from about 0.005 wt. 5 to about 5 wt. %, and FEC is present in an amount ranging from about 0.01 wt. % to about 10 wt. %. This electrolyte formulation is more conductive than the conventional or prior art binary and ternary solvent system electrolytes while being chemically and electrochemically stable toward Li/SVO cells, Li-SVO/CFx mixture cells, and Li-SVO/CFx sandwich cathode primary electrochemical cells.