公开(公告)号：US07161019B2

公开(公告)日：2007-01-09

申请号：US10862897

申请日：2004-06-08

申请人： Juha A. Rantala ,  Arto L. T. Maaninen ,  Tina J. Maaninen ,  Jarkko J. Pietikainen

发明人： Juha A. Rantala ,  Arto L. T. Maaninen ,  Tina J. Maaninen ,  Jarkko J. Pietikainen

IPC分类号： C07F7/04

CPC分类号： C07F7/123 ,  C07F7/0874 ,  C07F7/12 ,  C07F7/1804 ,  C07F7/1888

摘要： A compound of the general formula R1MR4R5R6 is provided where R1 is a partially or fully fluorinated aryl, alkyl, alkenyl or alkynyl group, wherein M is selected from group 14 of the periodic table, wherein R4, R5 and R6 are independently an alkoxy group OR3 or a halogen group X—except, a) where R4, R5 and R6 are each ethoxy, M is Si and R1 is perfluorinated phenyl or perfluorinated vinyl; b) where R4 is ethoxy, R5 and R6 are chlorine, M is Si, and R1 is perfluorinated phenyl; or c) where R4, R5 and R6 are chlorine, M is Si, and R1 is perfluorinated phenyl, perfluorinated methyl or perfluorinated vinyl. This compound formed can be further reacted to attach an additional organic R group, and/or hydrolyzed, alone or with one or more similar compounds, to form a material having a molecular weight of from 500 to 10,000, which material can be deposited on various substrates as a coating or deposited and patterned for a waveguide or other optical device components. Methods for making compounds of the general formula R1MR4R5R6 are also disclosed.

摘要翻译： 提供了通式R 1的化合物，其中R 1，R 2，R 4，R 6， 部分或完全氟化的芳基，烷基，烯基或炔基，其中M选自周期表的第14族，其中R 4，R 5， >和R 6独立地是烷氧基OR 3或卤素基团X，除了a）其中R 4，R 4， 5和R 6各自为乙氧基，M为Si，R 1为全氟化苯基或全氟化乙烯基; b）其中R 4为乙氧基，R 5和R 6为氯，M为Si，R 1为 >是全氟化苯基; 或c）其中R 4，R 5和R 6是氯，M是Si，R 1， 是全氟化苯基，全氟化甲基或全氟乙烯基。 形成的该化合物可以进一步反应以附加另外的有机R基团和/或单独或与一种或多种类似化合物水解形成分子量为500至10,000的材料，该材料可以沉积在各种 衬底作为涂层或沉积和图案化用于波导或其它光学器件部件。 还公开了制备通式为R 1，R 5，R 5，R 6和S 6的化合物的方法。