公开(公告)号：US11777136B2

公开(公告)日：2023-10-03

申请号：US16725656

申请日：2019-12-23

Applicant: KOREA INSTITUTE OF SCIENCE AND TECHNOLOGY

Inventor： Kyung Yoon Chung ,  Dong Hyun Kim ,  Juhyeon Ahn ,  Jaeho Park ,  Ji-Young Kim ,  Min Kyung Cho ,  Byung Won Cho ,  Hun-Gi Jung ,  Minah Lee ,  Seungho Yu ,  Hyungseok Kim

IPC: H01M10/054 ,  H01M4/04 ,  H01M4/505 ,  H01M10/0525 ,  H01M4/525 ,  H01M10/0569

CPC classification number: H01M10/054 ,  H01M4/0445 ,  H01M4/0459 ,  H01M4/505 ,  H01M4/525 ,  H01M10/0525 ,  H01M10/0569

Abstract: Disclosed is a method of preparing a cathode active material useful in a sodium ion secondary battery having high reversible capacity and excellent cycle characteristics. The method for preparing a cathode active material composed of Zrw-doped NaxLiyMzOa includes the steps of (A) doping LiyMzOa with Zrw to provide Zrw-doped LiyMzOa; and (B) dissociating Li ion from the Zrw-doped LiyMzOa and inserting Na ion thereto to provide the Zrw-doped NaxLiyMzOa, wherein M is selected from Ti, V, Cr, Mn, Fe, Co, Ni, Mo, Ru, and combinations thereof, and wherein 0.005