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公开(公告)号：US20120142535A1
公开(公告)日：2012-06-07
申请号：US13251667
申请日：2011-10-03
申请人： MARK D. LEATHERMAN , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
发明人： MARK D. LEATHERMAN , George A. Policello , Wenqing N. Peng , Liping Zheng , Roland Wagner , Suresh K. Rajaraman , Zijun Xia
IPC分类号： A01N25/30 , A01N25/02 , A01P13/00 , A01P21/00 , A01P3/00 , C09K5/10 , C10L1/28 , D21H17/13 , C08K5/544 , C11D17/00 , C11D3/60 , C02F5/00 , A61K8/58 , A01P7/04
CPC分类号： A01N25/30 , B01F17/0071 , C07F7/0838 , C11D3/3738 , C11D3/3742
摘要： The present invention provides for a composition comprising a siloxane having the formula: M1DM2 wherein M1=(R1)(R2)(R3)SiO1/2; M2=(R4)(R5)(R6)SiO1/2 and D=(R7)(Z)SiO2/2 where R1, R2, R3, R4, R5, R6 and R7 are each independently selected from the group consisting of 1 to 4 carbon monovalent hydrocarbon radicals, aryl, and a hydrocarbon group of 4 to 9 carbons containing an aryl group; Z is a pendant hydrophilic ionic group selected from the group consisting of R8—RA, R9-RC, and R10—RZ; RA being an anionic substituent, RC a cationic substituent or RZ a zwitterionic substituent on the D group wherein said siloxane has an enhanced resistance to hydrolysis at a pH below 6 or a pH above 7.5.
摘要翻译： 本发明提供包含具有下式的硅氧烷的组合物：M1DM2其中M1 =（R1）（R2）（R3）SiO1 / 2; M2 =（R4）（R5）（R6）SiO1 / 2和D =（R7）（Z）SiO2 / 2其中R1，R2，R3，R4，R5，R6和R7各自独立地选自1 至4碳一价烃基，芳基和含有芳基的4至9个碳的烃基; Z是选自R8-RA，R9-RC和R10-RZ的侧链亲水离子基团; RA为阴离子取代基，RC为阳离子取代基或RZ为D基团上的两性离子取代基，其中所述硅氧烷在pH低于6或pH高于7.5时具有增强的水解抗性。
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2.发明申请COSMETIC COMPOSITIONS COMPRISING HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE SURFACTANTS 有权包含抗水性抗坏血酸甲醛表面活性剂的化妆品组合物公开(公告)号：US20100069329A1
公开(公告)日：2010-03-18
申请号：US12621726
申请日：2009-11-19
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms, R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1; R14 is selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译： 包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价 烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15） ）dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R 14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a，b和c为零或正，并且满足以下关系：2＆nlE; a + b + c＆nlE; 20与 a≥2，R5和R6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。
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3.发明申请COATING COMPOSITIONS COMPRISING HYDROLYSIS RESISTANT ORGANOMODIFIED DISILOXANE SURFACTANTS 失效包含水解抗性有机化的甲基表面活性剂的涂料组合物公开(公告)号：US20100069546A1
公开(公告)日：2010-03-18
申请号：US12621755
申请日：2009-11-19
IPC分类号： C09D175/00 , C09D167/00 , C09D163/00
CPC分类号： A61Q19/00 , A61K8/585 , C09D163/00 , C08L2666/44
摘要： Compositions comprising disiloxane surfactant compositions comprising a silicone composition comprising a silicone having the formula: MM′ where M=R1R2R3SiO1/2; M′=R4R5R6SiO1/2; with R1 selected from the group consisting of branched monovalent hydrocarbon radical of from 3 to 6 carbon atoms and R7, where R7 has the formula: R8R9R10SiR12 with R8, R9, and R10 each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms and monovalent aryl or alkaryl hydrocarbon radicals having from 6 to 13 carbon atoms and R12 is a divalent hydrocarbon radical having from 1 to 3 carbon atoms,R2 and R3 are each independently selected from the group of from 1 to 6 carbon atom monovalent hydrocarbon radicals or R1, with R4 an alkylpolyalkyleneoxide of the general formula: R13(C2H4O)a(C3H6O)b(C4H8O)cR14 where R13 is a divalent linear or branched hydrocarbon radical having the structure: —CH2—CH(R15)(R16)dO— where R15 is H or methyl; R16 is a divalent alkyl radical of 1 to 6 carbons where the subscript d may be 0 or 1;R14 selected from the group consisting of H, monovalent hydrocarbon radicals of from 1 to 6 carbon atoms and acetyl where the subscripts a, b and c are zero or positive and satisfy the following relationships: 2≦a+b+c≦20 with a≧2, and R5 and R6 are each independently selected from the group of monovalent hydrocarbon radicals having from 1 to 6 carbon atoms or R4 that exhibit resistance to hydrolysis over a wide pH range.
摘要翻译： 包含二硅氧烷表面活性剂组合物的组合物，其包含硅氧烷组合物，其包含具有式MM的其中M = R 1 R 2 R 3 SiO 1/2的硅氧烷; M'= R4R5R6SiO1 / 2; 其中R 1选自3至6个碳原子的支化一价烃基和R 7，其中R 7具有下式：R 8 R 9 R 10 SiR 12，其中R 8，R 9和R 10各自独立地选自具有1至 6个碳原子和具有6至13个碳原子的单价芳基或烷芳基烃基，R 12是具有1至3个碳原子的二价烃基，R 2和R 3各自独立地选自1至6个碳原子的单价 烃基或R 1，其中R 4是具有通式R 13（C 2 H 4 O）a（C 3 H 6 O）b（C 4 H 8 O）c R 14的烷基聚环氧烷，其中R 13是具有以下结构的二价直链或支链烃基：-CH 2 -CH（R 15） ）dO-，其中R 15是H或甲基; R16是1至6个碳的二价烷基，其中下标d可以是0或1; R14选自H，1至6个碳原子的一价烃基和乙酰基，其中下标a，b和c为零或正，并且满足以下关系：2＆nlE; a + b + c＆nlE; 20，其中a ≥2，R5和R6各自独立地选自具有1至6个碳原子的一价烃基或在宽pH范围内表现出抗水解性的R4。
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