公开(公告)号：US3956389A

公开(公告)日：1976-05-11

申请号：US517130

申请日：1974-10-23

申请人： Orville Wayne Rigdon ,  Lawrence Frank Kuntschik ,  Robert Sammie Edwards

发明人： Orville Wayne Rigdon ,  Lawrence Frank Kuntschik ,  Robert Sammie Edwards

IPC分类号： C07B61/00 ,  B01J23/00 ,  B01J23/74 ,  C07C67/00 ,  C07C209/00 ,  C07C209/26 ,  C07C209/38 ,  C07C209/40 ,  C07C211/03 ,  C07C85/10

CPC分类号： B01J23/74

摘要： A process for producing secondary alkyl primary amines having from 10 to 50 or, from about 10 to about 13, or from about 14 to 50 carbon atoms from crude n-paraffin oximes derived by the photonitrosation of C.sub.10 to C.sub.50 or C.sub.10 to C.sub.13 or C.sub.14 to C.sub.50 n-paraffins, said process comprising hydrogenation in a polar solvent in the presence of ammonia and a metal catalyst. The crude n-paraffin oximes are contaminated with ketones and nitroso halides. By the process of this invention, these impurities are likewise converted into the corresponding secondary alkyl primary amines.

摘要翻译： 从通过C10至C50或C10至C13或C14的光子作用衍生的粗制正链烷烃肟制备具有10至50个或约10至约13个或约14至50个碳原子的仲烷基伯胺的方法 所述方法包括在极性溶剂中在氨和金属催化剂的存在下氢化。 粗的正链烷烃肟被酮和亚硝基卤化物污染。 通过本发明的方法，这些杂质同样转化为相应的仲烷基伯胺。