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公开(公告)号：US07803269B2
公开(公告)日：2010-09-28
申请号：US11872312
申请日：2007-10-15
CPC分类号： C10G45/58 , C10G2400/04
摘要： A process is provided for improving the cold flow properties of a hydrocarbon stream employing a substantially liquid-phase continuous hydroisomerization zone where the reaction zone has a substantially constant level of dissolved hydrogen throughout without the addition of additional hydrogen external to the reaction zone.
摘要翻译： 提供了一种使用基本上液相连续加氢异构化区改进烃流的冷流性质的方法，其中反应区具有基本恒定水平的溶解氢，而不需要在反应区外添加另外的氢。
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公开(公告)号：US20090095655A1
公开(公告)日：2009-04-16
申请号：US11872251
申请日：2007-10-15
IPC分类号： C10G69/02
CPC分类号： C10G65/12 , C10G2300/42
摘要： Methods of hydrocracking hydrocarbon streams are provided that employ substantially liquid-phase continuous hydroprocessing conditions. In one aspect, the method includes a separate hydrotreating and hydrocracking system where the hydrocracking zone is a substantially liquid-phase continuous system. In another aspect, the method includes a two-stage hydrocracking system where one or both of the hydrocracking zones is a substantially liquid-phase continuous reaction system.
摘要翻译： 提供加氢裂化烃流的方法，其基本上采用液相连续加氢处理条件。 在一个方面，该方法包括单独的加氢处理和加氢裂化系统，其中加氢裂化区是基本上液相连续的系统。 另一方面，该方法包括两级加氢裂化系统，其中一个或两个加氢裂化区是基本上液相连续的反应体系。
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公开(公告)号：US07790020B2
公开(公告)日：2010-09-07
申请号：US11872102
申请日：2007-10-15
CPC分类号： C10G45/02 , C10G2400/04
摘要： A process is provided for producing low sulfur diesel having a high cetane number where the temperature and pressure requirements for obtaining low levels of sulfur is separated from the temperature and pressure requirements for improving cetane. In one aspect, a low pressure hydrodesulfurization zone and a high pressure aromatic saturation zone are employed to sequentially achieve the desired sulfur and cetane levels. In another aspect, the process first converts a diesel boiling range hydrocarbonaceous stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of aromatics. Hydrogen is then admixed with the hydrotreating zone effluent, which is then reacted in a substantially liquid-phase continuous reaction zone substantially undiluted with other streams to effect saturation of aromatics to provide a liquid-phase continuous reaction zone effluent having an improved cetane number.
摘要翻译： 提供了一种生产具有高十六烷值的低硫柴油的方法，其中获得低水平硫的温度和压力要求与用于改善十六烷的温度和压力要求分离。 一方面，使用低压加氢脱硫区和高压芳族饱和区来顺序地获得所需的硫和十六烷值。 在另一方面，该方法首先在加氢处理区中转化柴油沸程烃流，其条件是有效地产生具有降低的硫浓度并且具有最小芳烃饱和度的加氢处理区流出物。 然后将氢气与加氢处理区流出物混合，然后将其在基本上液相连续的反应区中与基本上未稀释的其它流反应，以实现芳族化合物的饱和，以提供具有改进的十六烷值的液相连续反应区流出物。
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公开(公告)号：US07749375B2
公开(公告)日：2010-07-06
申请号：US11852174
申请日：2007-09-07
CPC分类号： B01J37/0221 , B01J23/85 , B01J23/882 , B01J35/008 , C10G2400/02
摘要： In one aspect, a hydrodesulfurization process is provided that selectively desulfurizes a hydrocarbon stream with minimal olefin saturation and minimal recombination of sulfur into mercaptans. In another aspect, the process includes a multi-stage reaction zone including at least first and second serial hydrodesulfurization reaction zones that sequentially remove sulfur from a hydrocarbon stream. In yet another aspect, the process is particularly suited to selectively desulfurize an olefinic naphtha hydrocarbon stream, such as FCC naphtha, steam cracked naphtha, coker naphtha, or other gasoline boiling hydrocarbon streams.
摘要翻译： 在一个方面，提供加氢脱硫方法，其选择性地使烃流以最少的烯烃饱和度和硫的最小重组硫化为硫醇。 在另一方面，该方法包括多级反应区，其包括至少第一和第二连续加氢脱硫反应区，其顺序地从烃流中除去硫。 在另一方面，该方法特别适用于烯烃石脑油烃流选择性脱硫，例如FCC石脑油，蒸汽裂解石脑油，焦化石脑油或其他汽油沸腾烃流。
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公开(公告)号：US20090095656A1
公开(公告)日：2009-04-16
申请号：US11872102
申请日：2007-10-15
IPC分类号： C10G69/02
CPC分类号： C10G45/02 , C10G2400/04
摘要： A process is provided for producing low sulfur diesel having a high cetane number where the temperature and pressure requirements for obtaining low levels of sulfur is separated from the temperature and pressure requirements for improving cetane. In one aspect, a low pressure hydrodesulfurization zone and a high pressure aromatic saturation zone are employed to sequentially achieve the desired sulfur and cetane levels. In another aspect, the process first converts a diesel boiling range hydrocarbonaceous stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of aromatics. Hydrogen is then admixed with the hydrotreating zone effluent, which is then reacted in a substantially liquid-phase continuous reaction zone substantially undiluted with other streams to effect saturation of aromatics to provide a liquid-phase continuous reaction zone effluent having an improved cetane number.
摘要翻译： 提供了一种生产具有高十六烷值的低硫柴油的方法，其中获得低水平硫的温度和压力要求与用于改善十六烷的温度和压力要求分离。 一方面，使用低压加氢脱硫区和高压芳族饱和区来顺序地获得所需的硫和十六烷值。 在另一方面，该方法首先在加氢处理区中转化柴油沸程烃流，其条件是有效地产生具有降低的硫浓度并且具有最小芳烃饱和度的加氢处理区流出物。 然后将氢气与加氢处理区流出物混合，然后将其在基本上液相连续的反应区中与基本上未稀释的其它流反应，以实现芳族化合物的饱和，以提供具有改进的十六烷值的液相连续反应区流出物。
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公开(公告)号：US20090095653A1
公开(公告)日：2009-04-16
申请号：US11872312
申请日：2007-10-15
IPC分类号： C10G45/58
CPC分类号： C10G45/58 , C10G2400/04
摘要： A process is provided for improving the cold flow properties of a hydrocarbon stream employing a substantially liquid-phase continuous hydroisomerization zone where the reaction zone has a substantially constant level of dissolved hydrogen throughout without the addition of additional hydrogen external to the reaction zone.
摘要翻译： 提供了一种使用基本上液相连续加氢异构化区改进烃流的冷流性质的方法，其中反应区具有基本恒定水平的溶解氢，而不需要在反应区外添加另外的氢。
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公开(公告)号：US20090095651A1
公开(公告)日：2009-04-16
申请号：US11872084
申请日：2007-10-15
IPC分类号： C10G65/02
CPC分类号： C10G65/12
摘要： Methods of hydroprocessing hydrocarbon streams are provided that employ substantially liquid-phase hydroprocessing conditions. In one aspect, the method includes directing a hydrocarbonaceous feed stock to a first substantially liquid-phase hydroprocessing zone wherein an effluent from the first substantially liquid-phase hydroprocessing zone is directed to a second substantially liquid-phase hydroprocessing zone generally undiluted with other hydrocarbon streams. In another aspect, the method recycles a liquid portion of a liquid hydrocarbonaceous effluent from the second substantially liquid-phase hydroprocessing zone, which preferably includes an amount of hydrogen dissolved therein, to the hydrocarbonaceous feed stock so that the feed to the first substantially liquid-phase hydroprocessing zone has a relatively larger concentration of dissolved hydrogen relative to the hydrocarbonaceous feed stock.
摘要翻译： 提供加氢处理烃流的方法，其采用基本上液相加氢处理条件。 一方面，该方法包括将烃类原料引导至第一基本上液相加氢处理区，其中来自第一基本上液相加氢处理区的流出物被引导至通常未与其它烃流稀释的第二基本上液相加氢处理区 。 在另一方面，该方法将来自第二基本上液相加氢处理区的液体烃流出物的液体部分再循环到烃原料中，所述第二基本液相加氢处理区优选包含一定量的溶解在其中的氢， 相加氢处理区相对于含烃原料具有相对较大的溶解氢浓度。
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公开(公告)号：US20090065396A1
公开(公告)日：2009-03-12
申请号：US11852174
申请日：2007-09-07
IPC分类号： C10G45/02
CPC分类号： B01J37/0221 , B01J23/85 , B01J23/882 , B01J35/008 , C10G2400/02
摘要： In one aspect, a hydrodesulfurization process is provided that selectively desulfurizes a hydrocarbon stream with minimal olefin saturation and minimal recombination of sulfur into mercaptans. In another aspect, the process includes a multi-stage reaction zone including at least first and second serial hydrodesulfurization reaction zones that sequentially remove sulfur from a hydrocarbon stream. In yet another aspect, the process is particularly suited to selectively desulfurize an olefinic naphtha hydrocarbon stream, such as FCC naphtha, steam cracked naphtha, coker naphtha, or other gasoline boiling hydrocarbon streams.
摘要翻译： 在一个方面，提供加氢脱硫方法，其选择性地使烃流以最少的烯烃饱和度和硫的最小重组硫化为硫醇。 在另一方面，该方法包括多级反应区，其包括至少第一和第二连续加氢脱硫反应区，其顺序地从烃流中除去硫。 在另一方面，该方法特别适用于烯烃石脑油烃流选择性脱硫，例如FCC石脑油，蒸汽裂解石脑油，焦化石脑油或其他汽油沸腾烃流。
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公开(公告)号：US07799208B2
公开(公告)日：2010-09-21
申请号：US11872251
申请日：2007-10-15
IPC分类号： C10G65/02
CPC分类号： C10G65/12 , C10G2300/42
摘要： Methods of hydrocracking hydrocarbon streams are provided that employ substantially liquid-phase continuous hydroprocessing conditions. In one aspect, the method includes a separate hydrotreating and hydrocracking system where the hydrocracking zone is a substantially liquid-phase continuous system. In another aspect, the method includes a two-stage hydrocracking system where one or both of the hydrocracking zones is a substantially liquid-phase continuous reaction system.
摘要翻译： 提供加氢裂化烃流的方法，其基本上采用液相连续加氢处理条件。 在一个方面，该方法包括单独的加氢处理和加氢裂化系统，其中加氢裂化区是基本上液相连续的系统。 另一方面，该方法包括两级加氢裂化系统，其中一个或两个加氢裂化区是基本上液相连续的反应体系。
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公开(公告)号：US07794588B2
公开(公告)日：2010-09-14
申请号：US11872140
申请日：2007-10-15
CPC分类号： C10G65/12 , C10G2400/04
摘要： A process is provided for producing low sulfur diesel having a reduced poly-aromatic level where at least a portion of the poly-aromatics are converted to mono-aromatics. In one aspect, the process separates the temperature and pressure requirements for obtaining low levels of sulfur from the temperature and pressure requirements to saturate poly-aromatics to mono-aromatics. By one approach, the process first converts a diesel boiling range hydrocarbon stream in a hydrotreating zone at conditions effective to produce a hydrotreating zone effluent having a reduced concentration of sulfur with minimal saturation of poly-aromatics. Hydrogen is then admixed in the hydrotreating zone effluent or at least a portion thereof, which is then reacted in a substantially liquid-phase continuous reaction zone to effect saturation of poly-aromatics to provide a liquid-phase continuous reaction zone effluent having a reduced level of poly-aromatics relative to the diesel feed.
摘要翻译： 提供了一种制备具有降低的聚芳族水平的低硫柴油的方法，其中至少一部分多芳族化合物转化为单芳族化合物。 在一个方面，该方法将温度和压力要求从温度和压力要求中分离出来以获得低水平的硫，从而将多芳族化合物饱和至单芳族化合物。 通过一种方法，该方法首先将加氢处理区中的柴油沸程烃流转化成有效地产生具有降低的硫浓度并且具有最小的多芳族化合物饱和度的加氢处理区流出物的条件。 然后将氢混合在加氢处理区流出物或其至少一部分中，然后将其在基本上液相的连续反应区中反应以实现多芳族化合物的饱和，以提供具有降低水平的液相连续反应区流出物 的多芳烃相对于柴油进料。
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