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1.发明申请Cobalt-Catalyzed Oxidations in Volumetrically Expanded Liquids by Compressed Gases 有权通过压缩气体在体积膨胀液体中的钴催化氧化公开(公告)号：US20080139841A1
公开(公告)日：2008-06-12
申请号：US11934612
申请日：2007-11-02
CPC分类号： C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/235 , C07C51/265 , C07C51/313 , C07C67/05 , C07C205/57 , C07C2601/14 , C07C49/12 , C07C49/403 , C07C49/603 , C07C49/597 , C07C47/22 , C07C49/78 , C07C63/26 , C07C63/16 , C07C63/24 , C07C59/84 , C07C55/02 , C07C55/14 , C07C59/347 , C07C69/013 , C07C69/003 , C07C69/16 , C07C69/145
摘要： Oxidations of hydrocarbons, cycloalkanes and alkenes, arylalkanes, and a variety of other organic substrates are accomplished by cobalt-N-hydroxysuccinimide co-catalyzed reactions with dioxygen under unusually mild, near ambient conditions of temperature and pressure. The improved safety of the oxidation method and the high yields of product obtained make use of a unique combination of cobalt (II) complexes with N-hydroxysuccinimide. These autoxidation reactions do not have prolonged initiation times. Many of these reactions can be safely performed under normal chemical laboratory conditions and do not require specialized equipment or reagents.
摘要翻译： 碳氢化合物，环烷烃和烯烃，芳基烷烃和各种其他有机基质的氧化通过钴 - N-羟基琥珀酰亚胺与二氧化碳的共催化反应在异常温和的近环境温度和压力条件下完成。 获得的产物的氧化方法的改进的安全性和高产率使得钴（II）配合物与N-羟基琥珀酰亚胺的独特组合。 这些自氧化反应没有延长的引发时间。 许多这些反应可以在正常的化学实验室条件下安全地进行，并且不需要专门的设备或试剂。
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2.发明授权Cobalt-catalyzed oxidations in volumetrically expanded liquids by compressed gases 有权通过压缩气体在体积扩大的液体中的钴催化氧化公开(公告)号：US08115029B2
公开(公告)日：2012-02-14
申请号：US11934612
申请日：2007-11-02
IPC分类号： C07C51/16
CPC分类号： C07C45/33 , C07C45/34 , C07C45/35 , C07C45/36 , C07C51/235 , C07C51/265 , C07C51/313 , C07C67/05 , C07C205/57 , C07C2601/14 , C07C49/12 , C07C49/403 , C07C49/603 , C07C49/597 , C07C47/22 , C07C49/78 , C07C63/26 , C07C63/16 , C07C63/24 , C07C59/84 , C07C55/02 , C07C55/14 , C07C59/347 , C07C69/013 , C07C69/003 , C07C69/16 , C07C69/145
摘要： Oxidations of hydrocarbons, cycloalkanes and alkenes, arylalkanes, and a variety of other organic substrates are accomplished by cobalt-N-hydroxysuccinimide co-catalyzed reactions with dioxygen under unusually mild, near ambient conditions of temperature and pressure. The improved safety of the oxidation method and the high yields of product obtained make use of a unique combination of cobalt (II) complexes with N-hydroxysuccinimide. These autoxidation reactions do not have prolonged initiation times. Many of these reactions can be safely performed under normal chemical laboratory conditions and do not require specialized equipment or reagents.
摘要翻译： 碳氢化合物，环烷烃和烯烃，芳基烷烃和各种其他有机基质的氧化通过钴 - N-羟基琥珀酰亚胺与二氧化碳的共催化反应在异常温和的近环境温度和压力条件下完成。 获得的产物的氧化方法的改进的安全性和高产率使得钴（II）配合物与N-羟基琥珀酰亚胺的独特组合。 这些自氧化反应没有延长的引发时间。 许多这些反应可以在正常的化学实验室条件下安全地进行，并且不需要专门的设备或试剂。
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3.发明申请公开(公告)号：US20110152498A1
公开(公告)日：2011-06-23
申请号：US12971311
申请日：2010-12-17
CPC分类号： C08G65/34 , Y02P20/582
摘要： Processes for producing polytrimethylene ether glycol and copolymers thereof are provided wherein, by condensing and recycling at least a portion of the vapor phase produced as the reaction progresses, the yield loss and polymer color are reduced.
摘要翻译： 提供聚三亚甲基醚二醇的制备方法及其共聚物，其中通过冷凝和再循环反应产生的气相的至少一部分进行，产率损失和聚合物颜色降低。
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4.发明授权公开(公告)号：US08344098B2
公开(公告)日：2013-01-01
申请号：US12971311
申请日：2010-12-17
IPC分类号： C08G65/34
CPC分类号： C08G65/34 , Y02P20/582
摘要： Processes for producing polytrimethylene ether glycol and copolymers thereof are provided wherein, by condensing and recycling at least a portion of the vapor phase produced as the reaction progresses, the yield loss and polymer color are reduced.
摘要翻译： 提供聚三亚甲基醚二醇的制备方法及其共聚物，其中通过冷凝和再循环反应产生的至少一部分气相，降低了收率损失和聚合物颜色。
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