公开(公告)号：US06365746B1

公开(公告)日：2002-04-02

申请号：US09473249

申请日：1999-12-27

申请人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

发明人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

IPC分类号： C07D23384

CPC分类号： C07F1/005

摘要： This invention relates to an organomercapto Au(I) complex having the formula [(M—SOL)n—A—S—Au—S—A—(SOL—M)n]M wherein M is a cationic counterion; SOL is a solubilizing group: A is a substituted or unsubstituted divalent organic linking group; and n is 1 to 4 and wherein the compound is symmetrical. It further relates to a method of manufacturing an organomercapto Au(I) complex comprising reacting an Au (I) complex with an organomercapto ligand and isolating the resulting organomercapto Au(I) complex from the reaction mixture.

摘要翻译： 本发明涉及具有马来酰亚胺的有机巯基Au（I）络合物，M是阳离子抗衡离子; SOL是增溶基团：A是取代或未取代的二价有机连接基团; n是1〜4，其中化合物是对称的。 进一步涉及一种制造有机巯基Au（I）配合物的方法，包括使Au（I）配合物与有机巯基配体反应，并从反应混合物中分离得到的有机巯基Au（I）配合物。

公开(公告)号：US06686143B1

公开(公告)日：2004-02-03

申请号：US10213992

申请日：2002-08-07

申请人： Roger Lok ,  Brian P. Cleary ,  Alton L. Chitty ,  Weimar W. White

发明人： Roger Lok ,  Brian P. Cleary ,  Alton L. Chitty ,  Weimar W. White

IPC分类号： G03C109

CPC分类号： G03C1/09

摘要： This invention relates to a photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising a water soluble Au(I) complex having the formula [L—Au—L]n−M+n wherein the complex is symmetrical; L is an organothiosulfonato ligand which is an antifogging, stabilizing, or sensitizing compound, n is 1 to 4, and M is a cationic counterion. This invention further relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising an organothiosulfonato Au(I) complex having the formula [A—SO2S—Au—SSO2—A]n−M+n wherein M is a cationic counterion; A is a substituted or unsubstituted organic group; and n is 1 to 4; and wherein the compound is symmetrical. It further relates to a method of preparing a silver halide emulsion utilizing said organothiosulfonato Au(I) complexes.

摘要翻译： 本发明涉及一种包含载体和卤化银乳剂层的照相元件，所述乳液层包含具有所述络合物中的所述络合物的水溶性Au（I）络合物是对称的; L是有机硫磺酸盐配体，其是防雾，稳定或敏化化合物，n为1至4，M为阳离子抗衡离子。 本发明还涉及一种包含载体和卤化银乳剂层的卤化银照相元件，所述乳液层包含具有马来酰亚胺的有机硫代磺酰亚胺Au（I）络合物M是阳离子抗衡离子; A是取代或未取代的有机基团; n 是1到4; 并且其中化合物是对称的。还涉及使用所述有机硫代磺酰胺Au（I）络合物制备卤化银乳剂的方法。

公开(公告)号：US06696586B1

公开(公告)日：2004-02-24

申请号：US10214031

申请日：2002-08-07

申请人： Brian P. Cleary ,  Roger Lok ,  Weimar W. White

发明人： Brian P. Cleary ,  Roger Lok ,  Weimar W. White

IPC分类号： C07F112

CPC分类号： G03C1/09 ,  C07C381/04 ,  G03C2001/091

摘要： This invention relates to an organothiosulfonato Au(I) complex having the formula [A—SO2S—Au—SSO2—A]n−M+n wherein M is a cationic counter ion; A is a substituted or unsubstituted organic group; and n is 1 to 4; and wherein the compound is symmetrical. It further relates to the synthesis of said compounds.

摘要翻译： 本发明涉及具有马来酰亚胺的有机硫代磺酰胺Au（I）络合物，M是阳离子抗衡离子; A是取代或未取代的有机基团; n是1至4; 并且其中所述化合物是对称的。 它还涉及所述化合物的合成。

公开(公告)号：US06306283B1

公开(公告)日：2001-10-23

申请号：US09184200

申请日：1998-11-02

申请人： E. Steven Brandt ,  Brian P. Cleary ,  Roger Lok ,  Weimar W. White

发明人： E. Steven Brandt ,  Brian P. Cleary ,  Roger Lok ,  Weimar W. White

IPC分类号： G01N2726

CPC分类号： G01N27/4166 ,  G03C1/09 ,  G03C2001/091

摘要： A method of screening a water soluble gold complex for use as a sensitizer in a silver halide photographic element comprised of experimentally measuring the electrochemical potential of the gold complex and then determining if the electrochemical potential falls within a predetermined utility window.

摘要翻译： 一种筛选在卤化银照相元件中用作敏化剂的水溶性金络合物的方法，其包括通过实验测量金络合物的电化学电位，然后确定电化学电位是否落入预定的实用窗口内。

公开(公告)号：US5945270A

公开(公告)日：1999-08-31

申请号：US965507

申请日：1997-11-06

申请人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

发明人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

IPC分类号： G03C1/09 ,  G03C1/06

CPC分类号： G03C1/09

摘要： This invention relates to a silver halide photographic element comprising a support and a silver halide emulsion layer, the emulsion layer comprising an organomercapto Au(I) complex having the formula�(M--SOL).sub.n --A--S--Au--S--A--(SOL--M).sub.n !Mwherein M is a cationic counterion;SOL is a solubilizing group:A is a substituted or unsubstituted divalent organic linking group;and n is 1 to 4 and wherein the compound is symmetrical.It further relates to a method of preparing a silver halide emulsion utilizing said organomercapto Au(I) complexes.

摘要翻译： 本发明涉及包含载体和卤化银乳剂层的卤化银照相元件，该乳剂层包含具有式[（M-SOL）nAS-Au-SA-（SOL-M）的有机巯基Au（I） n] M其中M是阳离子抗衡离子; SOL是增溶基团：A是取代或未取代的二价有机连接基团; 且n为1至4，并且其中所述化合物是对称的。 它还涉及使用所述有机巯基Au（I）配合物制备卤化银乳剂的方法。

公开(公告)号：US6034249A

公开(公告)日：2000-03-07

申请号：US964104

申请日：1997-11-06

申请人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

发明人： Roger Lok ,  Weimar W. White ,  Brian P. Cleary

IPC分类号： G03C1/09 ,  C07D233/84 ,  C07F1/00 ,  C07F1/12 ,  C07D257/04

CPC分类号： C07F1/005

摘要： This invention relates to an organomercapto Au(I) complex having the formula ##STR1## wherein M is a cationic counterion;SOL is a solubilizing group;A is a substituted or unsubstituted divalent organic linking group;and n is 1 to 4 and wherein the compound is symmetrical.It further relates to a method of manufacturing an organomercapto Au(I) complex comprising reacting an Au(I) complex with an organomercapto ligand and isolating the resulting organomercapto Au(I) complex from the reaction mixture.

摘要翻译： 本发明涉及具有下式的有机巯基Au（I）配合物，其中M是阳离子抗衡离子; SOL是增溶基团; A是取代或未取代的二价有机连接基团; 且n为1至4，并且其中该化合物是对称的。 本发明还涉及一种制备有机巯基Au（I）配合物的方法，包括使Au（I）配合物与有机巯基配体反应并从所述反应混合物中分离得到的有机巯基Au（I）配合物。

公开(公告)号：US06290749B1

公开(公告)日：2001-09-18

申请号：US09456643

申请日：1999-12-08

申请人： Weimar W. White ,  Gary G. Kiehl ,  Brian P. Cleary

发明人： Weimar W. White ,  Gary G. Kiehl ,  Brian P. Cleary

IPC分类号： C22B332

CPC分类号： C22B3/065 ,  B22F9/24 ,  C22B3/44 ,  C22B11/042 ,  Y02P10/214 ,  Y02P10/234

摘要： A method for preparing ultra-pure silver from a crude silver mixture containing metallic and/or non-metallic impurities, said method comprising; dissolving the crude silver mixture in nitric acid to form a crude silver nitrate solution; adding a first selective reducing agent to the crude silver nitrate solution to precipitate a silver/contaminant matrix and form a partially purified silver nitrate solution; separating the partially purified silver nitrate solution from the precipitated silver/contaminant matrix; adding a second selective reducing agent to the partially purified silver nitrate solution to precipitate silver powder; and isolating the silver powder.

摘要翻译： 一种由含有金属和/或非金属杂质的粗银混合物制备超纯银的方法，所述方法包括：将粗银混合物溶解在硝酸中以形成粗硝酸银溶液;将第一选择性还原剂加入到 粗硝酸银溶液沉淀银/污染物基体并形成部分纯化的硝酸银溶液;将部分纯化的硝酸银溶液与沉淀的银/污染物基质分离;向部分纯化的硝酸银溶液中加入第二选择性还原剂 沉淀银粉; 将银粉拆分。

公开(公告)号：US06290747B1

公开(公告)日：2001-09-18

申请号：US09457170

申请日：1999-12-08

申请人： Weimar W. White ,  Gary G. Kiehl ,  Brian P. Cleary

发明人： Weimar W. White ,  Gary G. Kiehl ,  Brian P. Cleary

IPC分类号： C22B332

CPC分类号： C22B7/008 ,  C22B3/0002 ,  C22B3/12 ,  C22B3/14 ,  C22B3/44 ,  C22B11/046 ,  Y02P10/214 ,  Y02P10/234

摘要： A method for preparing ultra-pure silver from a crude silver halide matrix containing metallic and/or non-metallic impurities, said method comprising; roasting the crude silver halide matrix to substantially remove carbonaceous material; treating the roasted crude silver halide matrix with ammonium hydroxide to dissolve the silver halides and form an ammonium hydroxide reaction mixture; adding an initial reducing agent to the ammonium hydroxide reaction mixture to precipitate a crude silver powder mixture; separating the crude silver powder mixture from the ammonium hydroxide reaction mixture dissolving the crude silver powder mixture in nitric acid to form a crude silver nitrate solution; adding a first selective reducing agent to the crude silver nitrate solution to precipitate a silver/contaminant matrix and form a partially purified silver nitrate solution; separating the partially purified silver nitrate solution from the precipitated silver/contaminant matrix; adding a second selective reducing agent to the partially purified silver nitrate solution to precipitate pure silver powder; and isolating the pure silver powder.

摘要翻译： 一种从含有金属和/或非金属杂质的粗卤化银基质制备超纯银的方法，所述方法包括：焙烧粗卤化银基质以基本上除去含碳材料;用氢氧化铵处理焙烧的粗卤化银基质 溶解卤化银并形成氢氧化铵反应混合物;向氢氧化铵反应混合物中加入初始还原剂以沉淀粗银粉末混合物;将粗银粉末混合物与氢氧化铵反应混合物分离，将粗银粉末混合物溶解在 硝酸以形成粗硝酸银溶液;向粗硝酸银溶液中加入第一选择性还原剂以沉淀银/污染物基质并形成部分纯化的硝酸银溶液;将部分纯化的硝酸银溶液与沉淀的银/ 污染物基质;添加第二选择性r 培养剂将部分纯化的硝酸银溶液沉淀出纯银粉末; 将纯银粉末拆分。

公开(公告)号：US08623126B1

公开(公告)日：2014-01-07

申请号：US13537704

申请日：2012-06-29

申请人： Thomas B. Brust ,  Yongcai Wang ,  Brian P. Cleary ,  Dale E. DeCann

发明人： Thomas B. Brust ,  Yongcai Wang ,  Brian P. Cleary ,  Dale E. DeCann

IPC分类号： C09D11/02

CPC分类号： C09D11/38 ,  B82Y30/00 ,  C09D11/322

摘要： An inkjet ink composition comprising: (a) water; (b) dispersed pigment particles; and (c) at least one humectant; wherein the pigment particles are present from about 4.5% by mass to about 10% by mass, and the pigment particles have a mass weighted mean Stoke's diameter of from about 35 nm to about 70 nm wherein the Stoke's diameter is determined by differential centrifugal sedimentation of the particles through a fluid in a disc centrifuge. The present invention employs specified sedimentation particle sizing criteria for selection of appropriate pigment particle sizes at high pigment concentrations to obtain improved ink performance. Further embodiments of the invention also demonstrate that the criticality of humectant types and levels employed in an ink can also become much more important at high pigment loading in order to obtain desired performance.

摘要翻译： 一种喷墨油墨组合物，其包含：（a）水; （b）分散的颜料颗粒; 和（c）至少一种湿润剂; 其中所述颜料颗粒的存在量为约4.5质量％至约10质量％，并且所述颜料颗粒的质量加权平均斯托克斯直径为约35nm至约70nm，其中所述斯托克斯直径通过差异离心沉降 颗粒通过盘式离心机中的流体。 本发明采用规定的沉降颗粒施胶标准，以在高颜料浓度下选择合适的颜料颗粒尺寸以获得改进的油墨性能。 本发明的另外的实施方案还表明，为了获得所需的性能，在高颜料负载下，在油墨中使用的湿润剂类型和水平的关键性也可以变得更加重要。

公开(公告)号：US20140000477A1

公开(公告)日：2014-01-02

申请号：US13537704

申请日：2012-06-29

申请人： Thomas B. Brust ,  Yongcai Wang ,  Brian P. Cleary ,  Dale E. DeCann

发明人： Thomas B. Brust ,  Yongcai Wang ,  Brian P. Cleary ,  Dale E. DeCann

IPC分类号： C09D11/10 ,  C09D11/02 ,  B82Y30/00

CPC分类号： C09D11/38 ,  B82Y30/00 ,  C09D11/322

摘要： An inkjet ink composition comprising: (a) water; (b) dispersed pigment particles; and (c) at least one humectant; wherein the pigment particles are present from about 4.5% by mass to about 10% by mass, and the pigment particles have a mass weighted mean Stoke's diameter of from about 35 nm to about 70 nm wherein the Stoke's diameter is determined by differential centrifugal sedimentation of the particles through a fluid in a disc centrifuge. The present invention employs specified sedimentation particle sizing criteria for selection of appropriate pigment particle sizes at high pigment concentrations to obtain improved ink performance. Further embodiments of the invention also demonstrate that the criticality of humectant types and levels employed in an ink can also become much more important at high pigment loading in order to obtain desired performance.

摘要翻译： 一种喷墨油墨组合物，其包含：（a）水; （b）分散的颜料颗粒; 和（c）至少一种湿润剂; 其中所述颜料颗粒的存在量为约4.5质量％至约10质量％，并且所述颜料颗粒的质量加权平均斯托克斯直径为约35nm至约70nm，其中所述斯托克斯直径通过差异离心沉降 颗粒通过盘式离心机中的流体。 本发明采用规定的沉降颗粒施胶标准，以在高颜料浓度下选择合适的颜料颗粒尺寸以获得改进的油墨性能。 本发明的另外的实施方案还表明，为了获得所需的性能，在高颜料负载下，在油墨中使用的湿润剂类型和水平的关键性也可以变得更加重要。