公开(公告)号：US20200087426A1

公开(公告)日：2020-03-19

申请号：US16494501

申请日：2018-03-16

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Martin Alexander ZUIDEVELD ,  Aurora Alexandra BATINAS-GEURTS ,  Dafne Lise STEINFORT

IPC: C08F4/654 ,  C08F4/651 ,  C08F10/00

Abstract: The present invention relates to a process for preparing a procatalyst for polymerization of olefins, said process comprising contacting a magnesium-containing support with a halogen-containing titanium compound, an internal electron donor being a substituted 1,2-phenylene aromatic diester compound.

公开(公告)号：US20180362674A1

公开(公告)日：2018-12-20

申请号：US15736878

申请日：2016-06-17

Applicant: SABIC Global Technologies B.V.

Inventor： Martin Alexander ZUIDEVELD ,  Sergei Andreevich SERGEEV ,  Vladimir Aleksandrovich ZAKHAROV ,  Dafne Lise STEINFORT

IPC: C08F10/06 ,  C07C233/69

CPC classification number: C08F10/06 ,  C07C233/69 ,  C08F110/06 ,  C08F10/00 ,  C08F4/6546 ,  C08F4/656 ,  C08F4/651 ,  C08F4/6465

Abstract: A process for preparing a procatalyst for polymerization of olefins, comprising contacting a magnesium-containing support with a halogen-containing titanium compound, a first internal electron donor represented by Formula A, a second internal electron donor represented by Formula B, and an activator; wherein the molar ratio of the first internal donor to the second internal donor is between 0.01 and 0.7; wherein in Formula A each R80 group is independently a substituted or unsubstituted aromatic group; and R81, R82, R83, R84, R85, R86 and R87 are each independently selected from a hydrogen or a hydrocarbyl group; wherein in Formula B R51 and R52 are each independently selected from a hydrogen or a hydrocarbyl group; and R53 and R54 are each independently selected from hydrogen, a halide or a hydrocarbyl group.

公开(公告)号：US20240067765A1

公开(公告)日：2024-02-29

申请号：US17766353

申请日：2020-09-29

Applicant: SABIC GLOBAL TECHNOLOGIES B.V.

Inventor： Martin Alexander ZUIDEVELD ,  Anika MEPPELDER ,  Dafne Lise STEINFORT ,  Kiran Arunkumar PUTHAMANE ,  Mudubagilu Udaya KUMAR

IPC: C08F4/649 ,  C08F4/02 ,  C08F4/659 ,  C08F110/06

CPC classification number: C08F4/6494 ,  C08F4/022 ,  C08F4/65912 ,  C08F4/65916 ,  C08F110/06

Abstract: A process for preparing a procatalyst for polymerization of olefins, comprising contacting a magnesium-containing support with a halogen-containing titanium compound, and an internal electron donor according to Formula (I), said process comprising the steps of: i) contacting a compound R4zMgX42-z with an alkoxy- or aryloxy-containing silane compound to give a first intermediate reaction product, being a solid Mg(OR1)xX12-x, ii) optionally contacting the solid Mg(OR1)xX12-x obtained in step ii) with at least one activating compound selected from the group formed by activating electron donors and metal alkoxide compounds of formula M1(OR2)v-w(OR3)w or M2(OR2)v-w(R3)w, to obtain a second intermediate product; iii) contacting the first or second intermediate reaction product, obtained respectively in step i) or ii), with a halogen-containing Ti-compound and said compound represented Formula (I), as the internal electron donor.